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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Hou, Xingqi Hu; Wen Tan; Guolian;

    The pitch control system has a profound impact on the development of wind energy, and yet a delay or non-minimum phase can weaken its performance. Thus, there is a strong incentive to enhance pitch control technology in order to counteract the negative effects of unidentified delays and non-minimum phase characteristics. To reduce the complexity of the parameter-tuning process and improve the performance of the system, in this paper, we propose a novel control method for wind turbine pitch angle with time delays. Specifically, the proposed control method is state-space PIDD2, which is based on internal model control (IMC) and the open-loop system step response. Then, considering the tracking, disturbance rejection and measurement noise, the proposed controller is verified through simulations. The simulation results demonstrate that the state-space PIDD2 (SS-PIDD2) can provide a trade-off between robustness, time domain performance and measurement noise attenuation and effectively improve pitch control performance in contrast to series PID and PI control methods.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Ji-Won Kim; Chang-Ho Hong; Jin-Seop Kim; Song-Hun Chong;

    The estimation of hydraulic and mechanical properties of bedrock is important for the evaluation of energy-related structures, including high-level nuclear waste repositories, hydraulic fracturing wells, and gas-hydrate production wells. The hydraulic conductivity and stress–strain curves of rocks are conventionally measured through laboratory tests on cylindrical samples. Both ASTM standards for hydraulic conductivity and compressive strength involve the use of the planar bases of a cylindrical sample. Hence, an alternative test method is required for the simultaneous measurement of hydraulic conductivity and stress–strain curves. This study proposes a novel electrical resistivity estimation method using two perimeter electrodes for the estimation of hydraulic properties. The theoretical background for the perimeter electrode setup is derived and the COMSOL MultiPhysics® finite element numerical simulation tool is employed to verify the derived theoretical equation. The accuracy of the numerical simulation tool is first validated by simulating the ASTM standard testing method for electrical resistivity. The electrical resistance values derived from the theoretical equation and numerical simulation are compared for different electrical resistivity and electrode radius. The assumed equidistant, circular equipotential surface results in a theoretical lower bound for the measured electrical resistance in the cylindrical specimen. The introduction of a phenomenological distortion factor to correct for the theoretical equipotential surface results in a good fit with the numerical simulation results. The effects of electrode length and equivalent strap electrodes were investigated to assess the applicability of the suggested method for laboratory testing. Consequently, this study presents an effective alternative theoretical assessment method for the lower bound electrical resistivity of cylindrical rock core samples under confining conditions when the installation of base electrodes is infeasible.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2021 . Peer-reviewed
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2021
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2021 . Peer-reviewed
      License: CC BY
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
      Article . 2021
      Data sources: DOAJ
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Hongkai Han; Zhaoqi Shi; Weiqin Zuo; Shengjie Wu; +4 Authors

    Nano-clean fracturing fluids have broad application potential in coalbed methane reservoir fracturing owing to their high stability, good temperature resistance, low filtration loss, and strong frictional resistance reduction. However, the sand-carrying regularity of nano-clean fracturing fluids in coalbed methane reservoirs is unclear, especially for complex fractures with variable directions. This study established a sand transport model that considers proppant collision, wall friction blocking, fracture fluid filtration loss, and the fracture branching angle to study the sand-carrying law of nano-clean fracturing fluids and its influencing factors in complex fractures. The degrees of influence on equilibrium height and placement rate from high to low were the proppant particle size, proppant density, fracturing fluid properties, sand ratio, and pumping discharge volume, and the correlation degrees obtained by grey correlation analysis are 0.862, 0.861, 0.855, 0.854, and 0.832, respectively. As the complexity of the fractures deepens and the resistance increases, the flow rate of the fracturing fluid is reduced, making it difficult for the proppant to enter the branching joints. The sand-carrying performance of a nano-clean fracturing fluid is better than that of a common clear-water fracturing fluid. The fluid-structure coupling model of a nano-clean fracturing fluid can accurately characterize the sand-carrying law of nano-clean fracturing fluids, providing a research basis for optimizing high efficiency sand-carrying fracturing fluid parameters in coalbed methane reservoir fracturing construction.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2023 . Peer-reviewed
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    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Energies
    Article . 2023
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2023 . Peer-reviewed
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      Energies
      Article . 2023
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Donghyeon Kim; Youngjin Seo; Juhyun Kim; Jeongmin Han; +1 Authors

    Coalbed methane (CBM) content is generally estimated using the isotherm theory between pressure and adsorbed amounts of methane. It usually determines the maximum content of adsorbed methane or storage capacity. However, CBM content obtained via laboratory experiment is not consistent with that in the in-situ state because samples are usually ground, which changes the specific surface area. In this study, the effect of the specific surface area relative to CBM content was investigated, and diffusion coefficients were estimated using equilibrium time analysis. The differences in adsorbed content with sample particle size allowed the determination of a specific surface area where gases can adsorb. Also, there was an equilibrium time difference between fine and lump coal, because more time is needed for the gas to diffuse through the coal matrix and adsorb onto the surface in lump coal. Based on this, we constructed a laboratory-scale simulation model, which matched with experimental results. Consequently, the diffusion coefficient, which is usually calculated through canister testing, can be easily obtained. These results stress that lump coal experiments and associated simulations are necessary for more reliable CBM production analysis.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2019 . Peer-reviewed
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    Energies
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    Energies
    Article . 2019
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Article . 2019 . Peer-reviewed
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      Article . 2019
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    Authors: Max Buirma; Jaap Vleugel; Jeroen Pruyn; Vincent Doedée; +1 Authors

    The International Maritime Organisation (IMO) calls for the maritime industry to restrict its CO2 emissions by −40% (IMO2030) and −70% (IMO2050). This paper answered the following research question: “Which technical, economic and emissions-related conditions predominantly determine the feasibility of a conceptual supply chain of liquid CO2 that is captured from the exhaust gases of LNG powered offshore vessels?” The captured CO2 is transported to land where it is utilized by a final customer. The study followed a systems engineering approach. Problem definition was followed by a requirements analysis (technology, emissions, economy and operations), design with scenarios and a case study with realistic vessel deployment, modeling and evaluation. All designs have technical uncertainties and financial risks, but the sale of captured CO2 could be a crucial advantage of the proposed concept over other concepts. The main conclusion is that emission and financial targets (payback time) can be met by aligning the offshore transportation distance with the capacity to store CO2 on board and the available means of transport to the final user. Specialists from the vessel owner indicate that capturing, storage and off-loading is likely to have minor implications for the vessel availability and regular operations.

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    Energies
    Article . 2022 . Peer-reviewed
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    Energies
    Article . 2022
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    Authors: Ming Li; Bo Jiang; Qi Miao; Geoff Wang; +2 Authors

    Multi-phase tectonic movements and complex geological structures limit the exploration and hotspot prediction of coalbed methane (CBM) in structurally complex areas. This scientific problem is still not fully understood, particularly in the Bumu region, Southwest China. The present paper analyses the occurrence characteristics and distribution of CBM based on the comprehensive analysis of CBM data. In combination with the analysis of the regional tectonics setting, geological structure features and tectonic evolution. The control action of multi-phase tectonic movements on CBM occurrence are further discussed. Results show that the Indosinian local deformation, Yanshanian intense deformation, and Himalayan secondary derived deformation formed the current tectonic framework of Enhong synclinorium. The intense tectonic compression and dextral shear action in the Yanshanian and Himalayan movements caused the complex geological structures in Bumu region, composed of the Enhong syncline, associated reverse faults and late derived normal fault. The CBM distribution is complex, which has the central and western NNE-trending high gas content zones along the syncline hinge zone and the reverse faults. The geological structure controls on CBM enrichment are definite and important. Based on geological structure features and responses of gas content, methane concentration, and gas content gradient, the gas controlling patterns of geological structure are determined and can be classified into five types: the reverse fault sealing, syncline sealing, monoclinal enrichment, normal fault dispersion, and buried floor fault dispersion types. The structural compression above the neutral surface plays an important role in the syncline sealing process, which is indicated by an increase in gas content gradient. The EW-trending tectonic intense compression and dextral shear action in the Himalayan movement avoided the negative inversion of NNE-trending Yanshanian compressive structure and its destruction of CBM reservoir. However, the chronic uplift and derived normal fault during Himalayan period caused the constant dissipation of CBM.

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    Energies
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    Authors: Han Qing; Gao Tao; Cunbao Deng;

    CO2 sequestration in coal is mainly attributed to adsorption. The adsorption experiments of CO2 were conducted at injection pressures ranging from 1 to 3 MPa on coal samples with five kinds of particle sizes. The fitting degree of four classical adsorption models to experimental adsorption data was systematically compared. The adsorption properties of CO2 were comprehensively discussed. The temperature changes of coal samples at different positions during CO2 adsorption were measured by using the improved adsorption tank, and then the energy conversion law was obtained. The results showed increasing gas injection pressure can effectively increase the adsorption capacity of CO2 on coal samples. The BET equation had the best fitting accuracy for CO2 adsorption on various size coal samples. There was a significant exothermic effect during CO2 adsorption and storage. With the rise of injection pressure, the peak value of the rising temperature of coal samples increased, but the change rate decreased. The maximum temperature rise of coal samples was up to 13.6 °C at 3 MPa, which should be of great concern for the prevention of coal spontaneous combustion. During the sequestration process of CO2, the adsorption resulted in a decrease in coal surface free energy and then partial conversion to heat, leading to the rise of coal temperature. In addition, the CO2 adsorption on the pore surface caused the expansion and deformation of coal.

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    Authors: Qing Tian; Yudong Cui; Wanjing Luo; Pengcheng Liu; +1 Authors

    Horizontal wells with multi-stage fractures have been widely used to improve coalbed methane (CBM) production from coalbed methane reservoirs. The main focus of this work is to establish a new semi-analytical method in the Laplace domain and investigate the transient pressure behavior in coalbed methane reservoirs. With the new semi-analytical method, flow regimes of a multi-fractured horizontal well in coalbed methane reservoirs were identified. In addition, the sensitivities of fracture conductivity, diffusion model, storability ratio, inter-porosity flow coefficient, adsorption index, fracture spacing, fracture asymmetry, non-planar angle, and wellbore storage were studied. Results indicate that six characteristic flow regimes can be identified for multi-fractured horizontal wells in coalbed methane reservoirs, which are bilinear flow, first linear flow, desorption-diffusion flow, first pseudo-radial flow, second linear flow, and second pseudo-radial flow. Furthermore, the sensitivity analysis shows that the early flow is mainly determined by the fracture conductivity, the asymmetry factor, the non-planar angle, and the wellbore storage; while the desorption-diffusion flow regime is mainly influenced by the diffusion model, the storability ratio, the inter-porosity flow coefficient, the adsorption index, and the fracture spacing. Our work can provide a deep insight into the fluid flow mechanism of multi-fractured horizontal wells in coalbed methane reservoirs.

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    Energies
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    Authors: Bernd Gamisch; Lea Huber; Matthias Gaderer; Belal Dawoud;

    This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90% Fe2O3, 10% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions’ kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured kinetic results can be excellently described with the so-called shrinking core model. Using the geometrical contracting sphere reaction mechanism model, the concentration- and temperature-dependent reduction and oxidation rates can be reproduced with a maximum deviation of less than 5%. In contrast to the reduction process, the temperature has a smaller effect on the oxidation reaction kinetics, which is attributed to 71% less activation energy (Ea,Re=56.9 kJ/mol versus Ea,Ox=16.0 kJ/mol). The concentration of the reacting gas showed, however, an opposite trend: namely, to have an almost twofold impact on the oxidation reaction rate constant compared to the reduction rate constant.

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    Article . 2021
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      Energies
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    Authors: Marcello Pagliero; Marina Alloisio; Camilla Costa; Raffaella Firpo; +2 Authors

    Water reclamation is becoming a growing need, in particular in developing countries where harvesting the required energy can be a challenging problem. In this context, exploiting solar energy in a specifically tailored membrane distillation (MD) process can be a viable solution. Traditional MD guarantees a complete retention of non-volatile compounds and does not require high feed water temperatures. In this work, a suitable amount of carbon black (CB) was incorporated into the whole matrix of a polymeric porous membrane in order to absorb light and directly heat the feed. The mixed matrix membranes were prepared forming a uniform CB dispersion in the PVDF dope solution and then using a non-solvent induced phase separation process, which is a well-established technique for membrane manufacturing. CB addition was found to be beneficial on both the membrane structure, as it increased the pore size and porosity, and on the photothermal properties of the matrix. In fact, temperatures as high as 60 °C were reached on the irradiated membrane surface. These improvements led to satisfactory distillate flux (up to 2.3 L/m2h) during the direct solar membrane distillation tests performed with artificial light sources and make this membrane type a promising candidate for practical applications in the field of water purification.

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    Energies
    Article . 2022 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Hou, Xingqi Hu; Wen Tan; Guolian;

    The pitch control system has a profound impact on the development of wind energy, and yet a delay or non-minimum phase can weaken its performance. Thus, there is a strong incentive to enhance pitch control technology in order to counteract the negative effects of unidentified delays and non-minimum phase characteristics. To reduce the complexity of the parameter-tuning process and improve the performance of the system, in this paper, we propose a novel control method for wind turbine pitch angle with time delays. Specifically, the proposed control method is state-space PIDD2, which is based on internal model control (IMC) and the open-loop system step response. Then, considering the tracking, disturbance rejection and measurement noise, the proposed controller is verified through simulations. The simulation results demonstrate that the state-space PIDD2 (SS-PIDD2) can provide a trade-off between robustness, time domain performance and measurement noise attenuation and effectively improve pitch control performance in contrast to series PID and PI control methods.

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    Authors: Ji-Won Kim; Chang-Ho Hong; Jin-Seop Kim; Song-Hun Chong;

    The estimation of hydraulic and mechanical properties of bedrock is important for the evaluation of energy-related structures, including high-level nuclear waste repositories, hydraulic fracturing wells, and gas-hydrate production wells. The hydraulic conductivity and stress–strain curves of rocks are conventionally measured through laboratory tests on cylindrical samples. Both ASTM standards for hydraulic conductivity and compressive strength involve the use of the planar bases of a cylindrical sample. Hence, an alternative test method is required for the simultaneous measurement of hydraulic conductivity and stress–strain curves. This study proposes a novel electrical resistivity estimation method using two perimeter electrodes for the estimation of hydraulic properties. The theoretical background for the perimeter electrode setup is derived and the COMSOL MultiPhysics® finite element numerical simulation tool is employed to verify the derived theoretical equation. The accuracy of the numerical simulation tool is first validated by simulating the ASTM standard testing method for electrical resistivity. The electrical resistance values derived from the theoretical equation and numerical simulation are compared for different electrical resistivity and electrode radius. The assumed equidistant, circular equipotential surface results in a theoretical lower bound for the measured electrical resistance in the cylindrical specimen. The introduction of a phenomenological distortion factor to correct for the theoretical equipotential surface results in a good fit with the numerical simulation results. The effects of electrode length and equivalent strap electrodes were investigated to assess the applicability of the suggested method for laboratory testing. Consequently, this study presents an effective alternative theoretical assessment method for the lower bound electrical resistivity of cylindrical rock core samples under confining conditions when the installation of base electrodes is infeasible.

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    Energies
    Article . 2021 . Peer-reviewed
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    Article . 2021
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      Energies
      Article . 2021 . Peer-reviewed
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      Article . 2021
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Hongkai Han; Zhaoqi Shi; Weiqin Zuo; Shengjie Wu; +4 Authors

    Nano-clean fracturing fluids have broad application potential in coalbed methane reservoir fracturing owing to their high stability, good temperature resistance, low filtration loss, and strong frictional resistance reduction. However, the sand-carrying regularity of nano-clean fracturing fluids in coalbed methane reservoirs is unclear, especially for complex fractures with variable directions. This study established a sand transport model that considers proppant collision, wall friction blocking, fracture fluid filtration loss, and the fracture branching angle to study the sand-carrying law of nano-clean fracturing fluids and its influencing factors in complex fractures. The degrees of influence on equilibrium height and placement rate from high to low were the proppant particle size, proppant density, fracturing fluid properties, sand ratio, and pumping discharge volume, and the correlation degrees obtained by grey correlation analysis are 0.862, 0.861, 0.855, 0.854, and 0.832, respectively. As the complexity of the fractures deepens and the resistance increases, the flow rate of the fracturing fluid is reduced, making it difficult for the proppant to enter the branching joints. The sand-carrying performance of a nano-clean fracturing fluid is better than that of a common clear-water fracturing fluid. The fluid-structure coupling model of a nano-clean fracturing fluid can accurately characterize the sand-carrying law of nano-clean fracturing fluids, providing a research basis for optimizing high efficiency sand-carrying fracturing fluid parameters in coalbed methane reservoir fracturing construction.

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    Energies
    Article . 2023 . Peer-reviewed
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    Article . 2023
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    Authors: Donghyeon Kim; Youngjin Seo; Juhyun Kim; Jeongmin Han; +1 Authors

    Coalbed methane (CBM) content is generally estimated using the isotherm theory between pressure and adsorbed amounts of methane. It usually determines the maximum content of adsorbed methane or storage capacity. However, CBM content obtained via laboratory experiment is not consistent with that in the in-situ state because samples are usually ground, which changes the specific surface area. In this study, the effect of the specific surface area relative to CBM content was investigated, and diffusion coefficients were estimated using equilibrium time analysis. The differences in adsorbed content with sample particle size allowed the determination of a specific surface area where gases can adsorb. Also, there was an equilibrium time difference between fine and lump coal, because more time is needed for the gas to diffuse through the coal matrix and adsorb onto the surface in lump coal. Based on this, we constructed a laboratory-scale simulation model, which matched with experimental results. Consequently, the diffusion coefficient, which is usually calculated through canister testing, can be easily obtained. These results stress that lump coal experiments and associated simulations are necessary for more reliable CBM production analysis.

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    Authors: Max Buirma; Jaap Vleugel; Jeroen Pruyn; Vincent Doedée; +1 Authors

    The International Maritime Organisation (IMO) calls for the maritime industry to restrict its CO2 emissions by −40% (IMO2030) and −70% (IMO2050). This paper answered the following research question: “Which technical, economic and emissions-related conditions predominantly determine the feasibility of a conceptual supply chain of liquid CO2 that is captured from the exhaust gases of LNG powered offshore vessels?” The captured CO2 is transported to land where it is utilized by a final customer. The study followed a systems engineering approach. Problem definition was followed by a requirements analysis (technology, emissions, economy and operations), design with scenarios and a case study with realistic vessel deployment, modeling and evaluation. All designs have technical uncertainties and financial risks, but the sale of captured CO2 could be a crucial advantage of the proposed concept over other concepts. The main conclusion is that emission and financial targets (payback time) can be met by aligning the offshore transportation distance with the capacity to store CO2 on board and the available means of transport to the final user. Specialists from the vessel owner indicate that capturing, storage and off-loading is likely to have minor implications for the vessel availability and regular operations.

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    Authors: Ming Li; Bo Jiang; Qi Miao; Geoff Wang; +2 Authors

    Multi-phase tectonic movements and complex geological structures limit the exploration and hotspot prediction of coalbed methane (CBM) in structurally complex areas. This scientific problem is still not fully understood, particularly in the Bumu region, Southwest China. The present paper analyses the occurrence characteristics and distribution of CBM based on the comprehensive analysis of CBM data. In combination with the analysis of the regional tectonics setting, geological structure features and tectonic evolution. The control action of multi-phase tectonic movements on CBM occurrence are further discussed. Results show that the Indosinian local deformation, Yanshanian intense deformation, and Himalayan secondary derived deformation formed the current tectonic framework of Enhong synclinorium. The intense tectonic compression and dextral shear action in the Yanshanian and Himalayan movements caused the complex geological structures in Bumu region, composed of the Enhong syncline, associated reverse faults and late derived normal fault. The CBM distribution is complex, which has the central and western NNE-trending high gas content zones along the syncline hinge zone and the reverse faults. The geological structure controls on CBM enrichment are definite and important. Based on geological structure features and responses of gas content, methane concentration, and gas content gradient, the gas controlling patterns of geological structure are determined and can be classified into five types: the reverse fault sealing, syncline sealing, monoclinal enrichment, normal fault dispersion, and buried floor fault dispersion types. The structural compression above the neutral surface plays an important role in the syncline sealing process, which is indicated by an increase in gas content gradient. The EW-trending tectonic intense compression and dextral shear action in the Himalayan movement avoided the negative inversion of NNE-trending Yanshanian compressive structure and its destruction of CBM reservoir. However, the chronic uplift and derived normal fault during Himalayan period caused the constant dissipation of CBM.

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    Authors: Han Qing; Gao Tao; Cunbao Deng;

    CO2 sequestration in coal is mainly attributed to adsorption. The adsorption experiments of CO2 were conducted at injection pressures ranging from 1 to 3 MPa on coal samples with five kinds of particle sizes. The fitting degree of four classical adsorption models to experimental adsorption data was systematically compared. The adsorption properties of CO2 were comprehensively discussed. The temperature changes of coal samples at different positions during CO2 adsorption were measured by using the improved adsorption tank, and then the energy conversion law was obtained. The results showed increasing gas injection pressure can effectively increase the adsorption capacity of CO2 on coal samples. The BET equation had the best fitting accuracy for CO2 adsorption on various size coal samples. There was a significant exothermic effect during CO2 adsorption and storage. With the rise of injection pressure, the peak value of the rising temperature of coal samples increased, but the change rate decreased. The maximum temperature rise of coal samples was up to 13.6 °C at 3 MPa, which should be of great concern for the prevention of coal spontaneous combustion. During the sequestration process of CO2, the adsorption resulted in a decrease in coal surface free energy and then partial conversion to heat, leading to the rise of coal temperature. In addition, the CO2 adsorption on the pore surface caused the expansion and deformation of coal.

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    Authors: Qing Tian; Yudong Cui; Wanjing Luo; Pengcheng Liu; +1 Authors

    Horizontal wells with multi-stage fractures have been widely used to improve coalbed methane (CBM) production from coalbed methane reservoirs. The main focus of this work is to establish a new semi-analytical method in the Laplace domain and investigate the transient pressure behavior in coalbed methane reservoirs. With the new semi-analytical method, flow regimes of a multi-fractured horizontal well in coalbed methane reservoirs were identified. In addition, the sensitivities of fracture conductivity, diffusion model, storability ratio, inter-porosity flow coefficient, adsorption index, fracture spacing, fracture asymmetry, non-planar angle, and wellbore storage were studied. Results indicate that six characteristic flow regimes can be identified for multi-fractured horizontal wells in coalbed methane reservoirs, which are bilinear flow, first linear flow, desorption-diffusion flow, first pseudo-radial flow, second linear flow, and second pseudo-radial flow. Furthermore, the sensitivity analysis shows that the early flow is mainly determined by the fracture conductivity, the asymmetry factor, the non-planar angle, and the wellbore storage; while the desorption-diffusion flow regime is mainly influenced by the diffusion model, the storability ratio, the inter-porosity flow coefficient, the adsorption index, and the fracture spacing. Our work can provide a deep insight into the fluid flow mechanism of multi-fractured horizontal wells in coalbed methane reservoirs.

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    Energies
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    Authors: Bernd Gamisch; Lea Huber; Matthias Gaderer; Belal Dawoud;

    This work aims at investigating the kinetic mechanisms of the reduction/oxidation (redox) reactions of iron oxide/iron pellets under different operating conditions. The reaction principle is the basis of a thermochemical hydrogen storage system. To simulate the charging phase, a single pellet consisting of iron oxide (90% Fe2O3, 10% stabilising cement) is reduced with different hydrogen (H2) concentrations at temperatures between 600 and 800 °C. The discharge phase is initiated by the oxidation of the previously reduced pellet by water vapour (H2O) at different concentrations in the same temperature range. In both reactions, nitrogen (N2) is used as a carrier gas. The redox reactions have been experimentally measured in a thermogravimetric analyser (TGA) at a flow rate of 250 mL/min. An extensive literature review has been conducted on the existing reactions’ kinetic mechanisms along with their applicability to describe the obtained results. It turned out that the measured kinetic results can be excellently described with the so-called shrinking core model. Using the geometrical contracting sphere reaction mechanism model, the concentration- and temperature-dependent reduction and oxidation rates can be reproduced with a maximum deviation of less than 5%. In contrast to the reduction process, the temperature has a smaller effect on the oxidation reaction kinetics, which is attributed to 71% less activation energy (Ea,Re=56.9 kJ/mol versus Ea,Ox=16.0 kJ/mol). The concentration of the reacting gas showed, however, an opposite trend: namely, to have an almost twofold impact on the oxidation reaction rate constant compared to the reduction rate constant.

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    Energies
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    Authors: Marcello Pagliero; Marina Alloisio; Camilla Costa; Raffaella Firpo; +2 Authors

    Water reclamation is becoming a growing need, in particular in developing countries where harvesting the required energy can be a challenging problem. In this context, exploiting solar energy in a specifically tailored membrane distillation (MD) process can be a viable solution. Traditional MD guarantees a complete retention of non-volatile compounds and does not require high feed water temperatures. In this work, a suitable amount of carbon black (CB) was incorporated into the whole matrix of a polymeric porous membrane in order to absorb light and directly heat the feed. The mixed matrix membranes were prepared forming a uniform CB dispersion in the PVDF dope solution and then using a non-solvent induced phase separation process, which is a well-established technique for membrane manufacturing. CB addition was found to be beneficial on both the membrane structure, as it increased the pore size and porosity, and on the photothermal properties of the matrix. In fact, temperatures as high as 60 °C were reached on the irradiated membrane surface. These improvements led to satisfactory distillate flux (up to 2.3 L/m2h) during the direct solar membrane distillation tests performed with artificial light sources and make this membrane type a promising candidate for practical applications in the field of water purification.

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