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Abstract With drastic fossil fuel depletion and environmental deterioration concerns, a move towards a more sustainable bioenergy-based economy is essential. Lately, the application of microwave (MW) irradiation for waste processing has been attracting interest globally. MW-assisted heating possesses several advantages such as the provision of high microwave energy into dielectric materials with deeper penetration for internal heat generation, showing beneficial features in improving the heating rate and reducing the reaction time. Consequently, the most recent literature regarding the applications of MW-assisted heating for biomass pretreatment as well as biofuel and bioenergy production was reviewed and consolidated in this study. An impressive increase in the product yield and improvement of the product properties are reported, with the use of MW-assisted heating in several conversion routes to produce biofuels. Despite being a promising technology for biofuel production, some major fundamental data of MW-assisted heating have not been comprehensively identified. Therefore, the feasibility of this technology for large-scale implementation is still subpar. Understanding the interaction between the feedstock and the microwave electromagnetic field, and the optimization of several operational and mechanical parameters are the two main keystones that would propel the industrialization of MW heating in the near future. This provides key insights leading to increased feasibility and more advanced application of MW heating.

The production of charcoal for its many uses requires a careful selection of biomass and pyrolysis conditions, especially temperature, to ensure suitable quality. To do so, physical, chemical, and mechanical energy must be considered. This study aimed to analyze the yields and properties of charcoal produced at different pyrolysis temperatures. Eucalyptus saligna wood was pyrolyzed in a reactor with final temperatures of 450, 550, 650, 750, 850 and 950 °C. The yields of charcoal, pyroligneous liquid and non-condensable gases were determined. Mass loss was determined for each temperature. Charcoal analysis included the determination of the apparent density, proximate analysis, heating value, mechanical strength, X-ray images for the internal visualization of its structure and hygroscopicity test. Relevant charcoal properties for the steel industry and barbecue, such as density, mechanical strength, heating value and hygroscopicity, show variable trends from pyrolysis at 650 °C. The results show that pyrolysis temperature had a great impact on the properties of charcoal. The apparent density of charcoal rose from 500 °C and had no relation to the breaking strength. When the pyrolysis temperature was raised, an increase in both apparent and true densities, internal fissures and cracks and fixed carbon content of charcoal was observed.