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In ecological risk assessment, exposure is generally modelled assuming static conditions, herewith neglecting the potential role of emission, environmental and biomass dynamics in affecting bioavailable concentrations. In order to investigate the influence of such dynamics on predicted bioavailable concentrations, the spatially-resolved dynamic model "ChimERA fate" was developed, incorporating macrophyte and particulate/dissolved organic carbon (POC/DOC) dynamics into a water-sediment system. An evaluation against three case studies revealed a satisfying model performance. Illustrative simulations then highlighted the potential spatio-temporal variability of bioavailable concentrations after a pulsed emission of four chemicals in a system composed of a pond connected to its inflow and outflow streams. Changes in macrophyte biomass and POC/DOC levels caused exposure variations which were up to a factor of 4.5 in time and even more significant (several orders of magnitude) in space, especially for highly hydrophobic chemicals. ChimERA fate thus revealed to be a useful tool to investigate such variations and to identify those environmental and ecological conditions in which risk is expected to be highest.

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This paper aims at reviewing the life cycle assessment (LCA) literature on second generation bioethanol based on lignocellulosic biomass and at identifying issues to be resolved for good LCA practice. Reviews are carried out on respective LCA studies published over the last six years. We use the classification of lignocellulosic biomass to define system boundaries, so that the comparison among LCA results can be thoroughly assessed based on identified system components. A basis for attributing environmental burden for different biomass feedstocks is also suggested. Despite the non-homogeneous systems, we conclude that second generation bioethanol performs better than fossil fuel at least for the two most studied impact categories, net energy output and global warming. For the latter category, carbon sequestration at the biomass generation stage can even consistently offset the GHG emissions from all parts of the life cycle chains at high ethanol percentage (≥85%). The aspect of biogenic carbon and agrochemical input for energy crops and biomass residues, and the effect of removal of the latter from soil have not been treated consistently. In contrast, the exclusion of upstream chain of biomass waste feedstocks is observed in practice. The bioethanol conversion process is mostly based on simultaneous saccharification and co-fermentation, characterized by high yield and low energy input. In this regard, the LCA results tend to under estimate the real impacts of the current technology. The choice of allocation methods strongly influences the final results, particularly when economic value is used as a reference. Substitution of avoided burden seems to be the most popular allocation method in practice, followed by partition based on mass, energy, and economic values.

The Coast to Karoo Transect investigates the abundance and diversity of ants and beetles along an altitudinal gradient in the Cederberg mountains of the Western Cape, South Africa. It is a long term project, initiated in 2002 by Prof. S.L. Chown, Stellenbosch University. Data collection is carried out on a biannual (spring and autumn) basis. To monitor changes in invertebrate assemblages, focusing on ants and beetles.

The modern Common Rail Diesel engine are, normally, optimised for being fuelled with the commercial Diesel fuel. The ECU calibrations are, consequently, defined to obtain the correct compromise between performances and emissions. It is, so, clear that if the engine is fuelled with an alternative bio-fuel with different characteristics (net heating value, stoichiometric A/F ratio, density, viscosity, etc.) the calibration must be modify. Interest in fuels from renewable sources and their use in transport has grown over the last decade. This is because of their biodegradability, potential improvements in exhaust emissions and benefits on the virtuous CO2 cycle of the earth. This paper demonstrates that it is possible to optimise the emissions and the performances of a light duty diesel C.R. engine fuelled with a vegetable derived fuel (Rapeseed Methyl-Ester) pure or blended with commercial Diesel fuel. Particularly in this paper the experimental results and the ECU control solutions referring to different fuel compositions are shown.

Over half of the world's forests are disturbed, and the rate at which ecosystem processes recover after disturbance is important for the services these forests can provide. We analyze the drivers' underlying changes in rates of key ecosystem processes (biomass productivity, litter productivity, actual litter decomposition, and potential litter decomposition) during secondary succession after shifting cultivation in wet tropical forest of Mexico.We test the importance of three alternative drivers of ecosystem processes: vegetation biomass (vegetation quantity hypothesis), community‐weighted trait mean (mass ratio hypothesis), and functional diversity (niche complementarity hypothesis) using structural equation modeling. This allows us to infer the relative importance of different mechanisms underlying ecosystem process recovery.Ecosystem process rates changed during succession, and the strongest driver was aboveground biomass for each of the processes. Productivity of aboveground stem biomass and leaf litter as well as actual litter decomposition increased with initial standing vegetation biomass, whereas potential litter decomposition decreased with standing biomass. Additionally, biomass productivity was positively affected by community‐weighted mean of specific leaf area, and potential decomposition was positively affected by functional divergence, and negatively by community‐weighted mean of leaf dry matter content.Our empirical results show that functional diversity and community‐weighted means are of secondary importance for explaining changes in ecosystem process rates during tropical forest succession. Instead, simply, the amount of vegetation in a site is the major driver of changes, perhaps because there is a steep biomass buildup during succession that overrides more subtle effects of community functional properties on ecosystem processes. We recommend future studies in the field of biodiversity and ecosystem functioning to separate the effects of vegetation quality (community‐weighted mean trait values and functional diversity) from those of vegetation quantity (biomass) on ecosystem processes and services.

Renewable energy has been prioritized in Danish energy policy since the early 1980s. This has led to the current situation where Denmark is one of the leading countries in the world in the field of wind energy utilization. The background for this success is a story about how a society can manage the development and diffusion of sustainable technologies so that they are simultaneously socially acceptable and environmentally benign. Consequently, this article describes the relationship between the organization of wind power and the protection of nature. The aim is to analyse which kinds of public planning and policy can promote wind power and nature protection in a situation where a conflict exists between these two issues. The discussion acknowledges that it has been a serious problem to balance these contrasting considerations. However, it also suggests that the problems seem solvable if technology development, the social organization relating to the use of the technology and proper planning are brought together to work in a spirit of local involvement. © 1998 John Wiley & Sons, Ltd. and ERP Environment

AbstractEarthworms may promote the biodegradation of polycyclic aromatic hydrocarbons (PAHs) in soil, but the mechanism through which they exert such influence is still unknown. To determine if the stimulation of PAH degradation by earthworms is related to changes in microbial communities, a microcosm experiment was conducted consisting of columns with natural uncontaminated soil covered with PAH‐contaminated dredge sediment. Columns without and with low and high Eisenia andrei densities were prepared. Organic matter and PAH content, microbial biomass, and dehydrogenase activity (DHA) were measured in soil and sediment over time. Biolog Ecoplate™ and polymerase chain reaction using denaturing gradient gel electrophoresis were used to evaluate changes in metabolic and structural diversity of the microbial community, respectively. Earthworm activity promoted PAH degradation in soil, which was significant for biphenyl, benzo[a]pyrene, and benzo[e]pyrene. Microbial biomass and DHA activity generally did not change over the experiment. Earthworm activity did change microbial community structure, but this did not affect its functioning in terms of carbon substrate consumption. Results suggest no relationship between changes in the microbial community by earthworm activity and increased PAH disappearance. The role of shifts in soil microbial community structure induced by earthworms in PAH removal needs further investigation. Environ. Toxicol. Chem. 2012;31:794–803. © 2011 SETAC

The use of methane as supplement to liquid fuel is one of the solution proposed for the reduction of the internal combustion engine pollutant emissions. Its intrinsic properties as the high knocking resistance and the low carbon content makes methane the most promising clean fuel. The dual fuel combustion mode allows improving the methane combustion acting mainly on the methane slow burning velocity and allowing lean burn combustion mode. An experimental investigation was carried out to study the methane-gasoline dual fuel combustion. Methane was injected in combustion chamber (DI fuel) while gasoline was injected in the intake manifold (PFI fuel). The measurements were carried out in an optically accessible small single-cylinder four-stroke engine. It was equipped with the cylinder head of a commercial 250 cc motorcycles engine representative of the most popular two-wheel vehicles in Europe. UV-visible spectroscopy measurements were performed to analyze the combustion process with high spatial and temporal resolution. In particular, UV-visible spectroscopy allows detecting the chemical markers of combustion process such as the radicals OH* and CH*. The in-cylinder lambda spatial and temporal evolution was evaluated. The combustion evolution is characterized by means of a high speed cycle resolved camera. The exhaust emissions were characterized by means of gaseous analyzers. The measurements were performed under steady state conditions at different engine operating conditions.

A new concept of a system for Combined Heat and Power generation is presented. The concept is based on hybrid use of two renewable energy sources, direct solar (thermodynamic solar) and biomass (indirect solar energy). Biomass combustion is conducted using a fluidized bed combustor. A second source of energy, given by the direct irradiation of the bed with a concentrated solar radiation, is integrated in the same system, using the fluidized bed as solar receiver. A Stirling engine converts heat into mechanical power. A Scheffler type mirror is adopted to allow irradiation of the system in a fixed focal point. Advantages of the proposed solution are illustrated and some preliminary results on the performance of the system, obtained with a simple model, are presented. The principal improvements with respect to existing systems of similar size and primary energy source are illustrated. The most important are the enhanced heat transfer processes that are realized with the help of the fluidized bed, and the possibility of continuous cogeneration during the day. Different working conditions are considered to estimate the contribution given by the burning of fuel, in presence as well as in absence of sun irradiation (as during the night). The distribution of energy shares among the different flux contributes is reported versus the amount of biomass burned per unit time. The results clearly demonstrate the advantage of coupling, in the same system, two sources for heat generation, thus maintaining the option of producing electricity without the supply of biomass fuel.