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Mining and mineral processing industry adversely affects ecosystems and communities in nearby areas, including high freshwater consumption and scarcity. That is why the emerging global trend is to use sea water in flotation to recover valuable minerals from finely disseminated base metals ores. Recent studies investigate sea water flotation of copper, molybdenum, nickel sulphides and pyrite, while flotation of sphalerite, the main valuable mineral for zinc production, remains uncovered. This paper examines the feasibility of sphalerite flotation by conventional collectors in artificial sea water using a bubble-particles technique and frothless flotation tests. Potassium isopropyl xanthate (PIPX) and sodium isopropyl dithiophosphate (SIDTP) were used as collectors, and copper sulphate was introduced as the activator, while zinc sulphate and sodium sulphide were used as depressants. We examined the most common size fractions of sphalerite: medium (−74 + 44 μm) and fines (−44 μm). The findings showed the feasibility of sphalerite flotation in artificial sea water. We also established correlations between the rate of bubble-particle attachment and the sphalerite flotation recovery resulting in the growth of flotation recovery with the increase of the bubble-particle attachment rate. The results can be used as guidelines in choosing flotation reagents for sphalerite flotation in sea water. Another practical application of the results is the potential for sustainable development of the industrial sector, ecosystems and societies due to the replacement of fresh water by sea water, although further technological and environmental studies are required.

In the current study, we examine the Indonesian government's watershed management program, which was established in 2001. In 2005, the Coordination Team for Rescue of Water Resources (CTRWR) was established to execute the program on a national level. However, at the time, field implementation was a sectoral interest due to the lack of program integration. To this end, the Indonesian government promoted integrated watershed management in 2009, which since then has been implemented by all stakeholders (in Top–Down management form), with application limited to preparing and planning documents. This is mainly driven by the stakeholders’ lack of understanding with regard to watershed systems as integrated management units. Field implementation results have not yet been realized, including the promotion of community-based watershed management (through Bottom–Up management). The purpose of our research was to determine the index numbers by measuring the level of cooperation between watershed management workers based on the Village Watershed Model (VWM) specifically surface water which includes six variables: planning, participation, institutional, fund sharing, gender, and management systems. The method used was an ordinal measure with the Likert scale. Our data showed successful watershed management, in which five of the six VWM variables—planning, participation, institutional, fund sharing, and management systems—were in the “good” category with indices ranging from 73.08 to 78.27. The gender variable index (69.12) was in the “medium” category.

The production process of nitroaromatic hazardous compounds, with the generation of acidic wastewater, represents a significant danger for the health and safety of the workers and the environment. The present study is focused on the development of an efficient installation to treat acidic wastewater resulting from the synthesis process of nitroaromatic compound, considering workers safety and environmental criteria. In this research, a detailed study of the different alternatives that can be used for effective and safe treatment of acidic wastewater was performed. The analysis of several technological schemes for the acidic wastewaters neutralization and the selection of the most feasible alternative from a technical-economic point of view were carried out. The simulation and mathematical modeling developed in this research represent a significant advance in the knowledge of this process for working in a much more secure form. The technological scheme of the process was defined, and the design of the main and auxiliary equipment as well as the piping system was carried out using different computational programs. Finally, this paper proposes a technological design for the treatment of acidic wastewater generated by the production process of nitroaromatic compound, which represents the basic criteria for the further design, construction, and equipment installation of the plant.

AbstractPrincipal Component Analysis (PCA) was used to evaluate groundwater quality data acquired in the pre-injection and injection periods for the Illinois Basin – Decatur Project (IBDP), a large-scale carbon capture and storage (CCS) project located in Decatur, Illinois, USA. For the pre-injection and injection periods three principal components explained 76.6% and 80.0% of the total data variance, respectively. Analysis of the pre-injection data set determined that highly positive loadings for total dissolved solids, chloride, bromide, sodium, magnesium, potassium, and electrical conductance designated the first component (PC1) as the salinity factor. High loadings for calcium, iron, and sulfate in component two (PC2) represents an oxidation-reduction component. The third component (PC3) represents groundwater acidity because of highly positive loading of pH. For the injection data set the variables contributed to the first component are bromide, sodium, total dissolved solids, chloride, electrical conductance, potassium, sulfate, iron, and calcium. Sulfate, magnesium, and calcium contribute to the second component and pH to the third component and represent salinity, dissolution, and acidity of groundwater. The results of the PC analysis indicate that water-rock interactions are the primary mechanism governing groundwater quality during both periods. The results of this analysis indicate that CO2 injection activities have not impacted the quality of the shallow groundwater in the project area.

Daily rainfall is measured as the total (mm) over the 24-hour period 0900 to 0900 GMT. It includes all precipitation - snow, rain, mist and fog. Rainfall was first recorded at Rothamsted in March 1853, using a copper funnel rain gauge (5 inch / 12.7 cm diameter) and measured using a graduated cylinder. Since 2004 it has been measured using an electronic tipping bucket rain gauge (10 inch / 25.4cm diameter), ARG100, calibrated to tip at 0.2mm (which has since become the minimum amount of rain that can be recorded). The rain gauge is placed within a 30cm deep 1.5m radius turf wall, retained by brick, to reduce wind eddies that may potentially blow rain out of the gauges. Data were collected daily manually until 2004 and since then by Automatic Weather Station using a standard protocol. There are differences in the capture rate between the two gauges, see Rainfall for further information. The monthly summary data contained in this spreadsheet are derived from daily data measured at Rothamsted Meteorological Station, Harpenden. Total monthly data is determined from daily data using Genstat 19th Edition. Verification includes checks for instrument errors, for missing data and outliers. The original raw daily data is available, after registering, from the e-RA database. Please contact the e-RA Curators for an access password and further details. This dataset represents the mean monthly rainfall recorded at Rothamsted from October 1985 - September 2017 and is derived from continuous daily records measured at the site. Location: Rothamsted Meteorological Station, Harpenden, Hertfordshire, England 51.82 N 0.37 W 128 m asl.

Global warming and direct anthropogenic impacts, such as water extraction, are largely affecting water budgets in Mediterranean wetlands, thereby increasing wetland salinities and isolation, and decreasing water depths and hydroperiods (duration of the inundation period). These wetland features are key elements structuring waterbird communities. However, the ultimate and net consequences of these dynamic conditions on waterbird assemblages are largely unknown. We combined a regular sampling on waterbird presence through the 2008 annual cycle with in-situ data on these relevant environmental predictors of waterbird distribution to model habitat selection for 69 individual species in a typical Mediterranean wetland network in south-western Spain. Species association with environmental features were subsequently used to predict changes in habitat suitability for each species under three climate change scenarios (encompassing changes in environment that ranged from 10% to 50% change as predicted by climatic models). Waterbirds distributed themselves unevenly throughout environmental gradients and water salinity was the most important gradient structuring the distribution of the community. Environmental suitability for the guilds of diving birds and vegetation gleaners will be reduced according to future climate scenarios, while most small wading birds will benefit from changing conditions. Resident species and those that breed in this wetland network will be also more impacted than those using this area for wintering or stopover. We provide here a tool that can be used in a horizon-scanning framework to identify emerging issues on waterbird conservation and to anticipate suitable management actions : Datasets as supporting information to article “How will climate change affect endangered Mediterranean waterbirds?” to be published in PLOS ONE. Address questions to Francisco Ramírez: ramirez@ub.edu

This study aims to identify potential hydropower sites and calculate the theoretical potential hydropower capacity based on watershed modelling of the Mindanao River Basin (MRB) in the Philippines for the sustainable development of a previously unstudied region. The Soil and Water Assessment Tool (SWAT) was applied to delineate the watershed of the MRB and simulate the river discharges with inputs from observed precipitation and global gridded precipitation datasets. Observed weather data, such as temperature, humidity, and solar radiation, from four meteorological stations in the Philippines were also used as inputs for SWAT modelling. Simulated discharges were calibrated at three river gauges on the Nituan, Libungan and Pulangi Rivers. However, due to limited river discharge records, model validations were conducted in proxy basins: the calibrated model parameters in river A were used in the watershed modelling of proxy river B. Of the delineated 107 sub-basins in the MRB watershed, only 33 were identified as having potential sites for hydropower development. These potential sub-basins hosted a total of 154 potential sites with an estimated monthly average power capacity of 5,551.35 MW for all 33 sub-basins. The estimated theoretical power capacity of 15,266.22 MW for all sites in the MRB is approximately equivalent to the Philippines’ total available power capacity in 2017 of 15,393 MW. These sites were classified into 16 mini-scale hydropower sites, 114 small-scale hydropower sites and 24 medium-scale hydropower sites based on the simulated river discharges and potential power capacities. Based on these results, hydropower development could be an alternative to strengthen the exploration of renewable energy resources and improve the energy situation in Mindanao; hydropower development could also have mitigation effects on frequent floods in flat, low-lying downstream areas.

Integrated multitrophic aquaculture (IMTA) is a versatile technology emerging as an ecological and sustainable solution for traditional monoculture aquacultures in terms of effluent treatment. Nevertheless, IMTA is still poorly applied in aquaculture industry due to, among other reasons, the lack of effective, low-investment and low-maintenance solutions. In this study, one has developed a practical and low maintenance IMTA-pilot system, settled in a semi-intensive coastal aquaculture. The optimisation and performance of the system was validated using Ulva spp., a macroalgae that naturally grows in the fishponds of the local aquaculture. Several cultivation experiments were performed at lab-scale and in the IMTA-pilot system, in static mode. The specific growth rate (SGR), yield, nutrient removal, N and C enrichment, protein and pigment content were monitored. Ulva spp. successfully thrived in effluent from the fish species sea bream (Sparus aurata) and sea bass (Dicentrarchus labrax) production tanks and significantly reduced inorganic nutrient load in the effluent, particularly, NH4+, PO43− and NO3−. The enrichment of nitrogen in Ulva spp.’s tissues indicated nitrogen assimilation by the algae, though, the cultivated Ulva spp. showed lower amounts of protein and pigments in comparison to the wild type. This study indicates that the designed IMTA-pilot system is an efficient solution for fish effluent treatment and Ulva spp., a suitable effluent remediator.