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Abstract Green analytical chemistry is primarily directed towards minimization of the amount of waste associated with either the sample preparation or analysis. Among different chromatographic methods, liquid chromatography is considered the least green, allowing for various possibilities for greening. Using green solvents such as ethanol or acetone in RP-HPLC, as an alternative to acetonitrile, is recently attracting an attention. Both ethanol and acetone are characterized with low toxicity, with certain drawbacks limiting their regular use in RP-HPLC. Ethanol has low eluotropic strength and causes high backpressures, while acetone shows high UV cut-off, making it unsuitable for UV/Vis detection. To overcome the existing problems, Corona Charged Aerosol Detector was employed for development of RP-HPLC methods for separation of risperidone and its structurally related impurities with either ethanol or acetone as organic modifier. The methods were optimized by experimental design methodology, while optimal conditions for separation were determined using Derringer's desirability function. Detailed assessment of 3D surface plots of Derringer's desirability function enabled selection of 0.6 mL min−1 flow rate and 20% (v/v) organic modifier content as optimal when using ethanol, while in case of acetone mobile phase flow rate was 0.8 mL min−1 and organic modifier content 17% (v/v). Methods were validated and their eco-friendly character was confirmed through Green Analytical Procedure Index (GAPI). Although both methods are ecologically acceptable, the main drawback is reflected in the fact that no recycling or another waste treatment method exist. In the end, acetone was prioritized over ethanol, due to lower health hazard and decreased amount of generated waste.

It has been suggested that the relationship between income and the associated environmental pressure in terms of derived materials inputs and pollution levels may take an inverted-U shape, indicating a 'delinking' of environmental pressure from economic growth in relation to rising per capita incomes. The likelihood of such a relationship being persistent is discussed in the context of a simple macro model of industrial metabolism, and the possibility of 'relinking' clearly emerges. Data on specific indicators of environmental pressure (i.e., the throughput of materials, energy and the volume of transport) in 19 countries have been used to investigate patterns of delinking. The results suggest that delinking may not be persistent; already some advanced economies may be entering a new period of relinking. The relationships between environmental pressure and welfare in the medium long term may be N-shaped rather than inverted-U-shaped.

This paper investigates the energy distribution and the waste heat energy characteristics of a compression ignition engine for micro-cogeneration applications, at different engine speeds and loads. The experimental activity was carried out on a three-cylinder, 1028 cc, common-rail engine. Tests were performed with diesel fuel and a 20% v/v biodiesel blend (B20). The quantity and the quality of the waste heat energy were studied through energy and exergy analyses, respectively. Combustion characteristics were investigated by means of indicating data. Gaseous emissions were measured and particles were characterized in terms of number and size at exhaust. It was found out that the addition of 20% v/v of RME to diesel fuel does not affect significantly the brake fuel conversion efficiency and the energetic flows. On the other hand, biodiesel blend allows to reduce the combustion noise and the pollutants emissions in most of the operating conditions. A proper phasing of the injection strategy for the biodiesel blend could further reduce the exhaust emissions, mainly at high engine speeds. The results presented in this paper could be useful for the development of diesel engine based micro-cogeneration systems working at different engine speeds and loads.

Policymakers at global level recognise that household biomass use in developing countries has significant health consequences. However, it is unclear how local-level health professionals perceive and respond to such health effects. This paper which is derived from the findings of a larger study on perceptions and responses to the harmful health effects of carrying heavy firewood loads and to smoke from cooking fires is based on a study conducted in South Africa among managers of health programmes and community nurses of Qaukeni and Mhlontlo municipalities in rural Eastern Cape. Interviews and participant observations were conducted in 2009 using ethnographic grounded theory approaches. In addition to a 10-month period of ethnographic fieldwork, ten programme managers and nurses in two villages were interviewed about health patterns in the villages that they serve, their perceptions of, and responses to the health effects of carrying heavy firewood loads, and inhalation of smoke from wood and dung cooking fires, their professional qualifications and experience, their own household energy use; and observations made as they served clinic clients. Results show that these programme managers and nurses perceive the health effects of carrying heavy loads of firewood and of cooking smoke as minor. Sometimes, nurses give women symptomatic relief for musculoskeletal pain resulting from carrying heavy loads. We posit that their perceptions are derived from customary neglect of work-related health and non-communicable diseases, cultural interpretations of womanhood, limited access to relevant information, and limited interactions between health and energy sector professionals. We conclude that culturally and gender-sensitive awareness programmes are needed for local-level health professionals to effectively address health effects of biomass collection and use. This paper provides new insights into overlooked differences between globally-driven initiatives to address health effects of biomass use and local perceptions.

Abstract The European Community is dedicating a growing effort towards the development of renewable energy resources market and in particular to bio-fuels. General public is now aware green biomass represents a local renewable resource, which is widely available on the territory and exploitable under environmentally sustainable criteria for an ecologically sound economic development. Generally, the problem is to evaluate where to concentrate the institutional action for the promotion of the renewable energy sector. The goal of this paper is to develop a methodology able to analyse the feasibility of the biomass energy chain. In particular, we have analysed two aspects: the availability of resources and the enterprise structures. While the first aspect is tied to the local situation (forest and agricultural areas), the second aspect has a general relevance for the Italian mountain context.

Fossil fuel thermal power plants constitute a large part of the Turkish electricity generation capacity. Turkish government has been developing several energy policy documents to evaluate how various renewable energy sources of the country can be utilized optimally in the generation of electricity within the next 30 years. This study considers three scenarios in the transition to renewable energy for Turkey; the business as usual (BAU), energy conservation (EC) and renewable energy (REN) scenarios. EC scenario considers the use of energy-efficient appliances and imposing a carbon tax, whereas REN scenario considers increasing the share of the renewable energy sources as much as possible in the power generation mix. These scenarios were evaluated in terms of cost and environmental impact. The LEAP (Long-range Energy Alternatives Planning Model) was used in the research. The REN scenario has been shown to be the optimal energy policy option for Turkey in terms of cost and environmental impact.

Electric vehicles (EVs) are considered a substitute for fossil-fueled vehicles due to rising fossil fuel prices and accompanying environmental concerns, and their use is predicted to increase dramatically shortly. However, the widespread use of EVs and their large-scale integration into the energy system will present several operational and technological hurdles. In the energy industry, an innovative solution known as the EVs smart parking lot (SPL) is introduced to handle EV charging and discharging electricity and energy supply challenges. This paper investigates social equity access and mobile charging stations (MCSs) for EVs, where the owner of MCSs is the EV parking lot. Accordingly, a new self-scheduling model for SPLs is presented in this paper that incorporates scheduling of the MCSs as temporary charging infrastructures while considering social equity access and optimizes SPL energy generation and storage schedule. The main objectives of this research are to (i) develop MCSs accessibility measures and quantify the equity impacts of MCSs locations by modeling prioritized demand based on several indices; (ii) determine the optimal set-points of SPL components (i.e., combined heat and power (CHP), photovoltaic system, electrical and heat-energy storage, and MCSs) to manage electrical peak demand and to maximize the economic benefits of SPLs. Results indicate that the proposed demand prioritization function model can meet the required EV charging demands for prioritized events, and the self-scheduling model for SPLs satisfies the charging demand of the EVs in the SPL location. Also, the social equity access to the EV charging stations is satisfied by analyzing the operation of MCSs around the prioritized demand of the prioritized events and social equity access indices.

The current fashion design, production, and consumption system, known as ‘fast fashion’, is characterized by the manufacturing of low-quality garments in a short period of time carried out in developing countries. In parallel with the deficits in social responsibility and human rights, the prevailing ‘take-make-dispose’ system in the fashion industry is one of the main causes of environmental pollution that concerns the climate change, scarcity of natural resources and health problems for the living beings. Due to these facts, discussions on Circular Design strategies – for waste reduction, components recycling, and materials reuse – became increasingly relevant throughout the globe. This paper’s aspiration is to outline a perspective towards a Circular Fashion. The concept of the Design for Sustainability requires a holistic view throughout de-signing strategies as well as the establishment of cyclical systems for the production site. Notwithstanding, the efficient integration of social and cultural dimensions are vital for Sustainable Fashion’s triumph. This work is supported by FEDER funds through the Competitiveness Factors Operational Programme - COMPETE and by national funds through FCT – Foundation for Science and Technology within the scope of the project POCI-01-0145-FEDER-007136. info:eu-repo/semantics/publishedVersion