• Energy Research

To mitigate the temperature increase in urban environments and reduce its impact on energy consumption and the quality of the environment, urban retrofitting technologies have been developed and applied worldwide. High albedo in urban surfaces and additional vegetation are the most efficient strategies to accomplish these goals. The objective of this study is to estimate the weight of these strategies, both individually and integrated, on the cooling potential of two Latin American cities. To do this, 36 low and high urban density scenarios were simulated with the ENVI-Met software. The simulation models were calibrated using air temperature curves which were monitored during the summer periods from 2010 to 2013. A Principal Components Analysis was carried out to establish possible associations between the proposed mitigation strategies and then the weight of anthropogenic heat was evaluated according to the configuration. The results show that the integrated mitigation strategies in urban areas -i. e. increase vegetation and albedo on horizontal surfaces- has a great potential to mitigate urban warming, showing a more significant impact on low-density urban configuration. The contribution of anthropogenic heat mainly produced by motorized transport and air conditioning systems, is a crucial input data for the urban microclimate simulations. Its impact on the urban densification processes may cancel out the benefits derived by the application of the mitigation strategies considered.

Load forecasting is very important to manage the electrical power systems. Load forecasting can be analyzed in three different ways as short-term, medium-term and long-term. Long-term load forecasting (LTLF) is in need to plan and carry on future energy demand and investment such as size of energy plant. LTLF is affected by energy consumption, national incoming per year, rates of civilization, increasing population rates and moreover economical parameters. Some of the forecasting models use mathematical formulas and statistical models such as correlation and regression analysis. In this study, a new effective expert-supported dynamic programming algorithm (ESDP) has been improved. Additionally, adaptive neuro-fuzzy inference system (ANFIS) and mathematical modeling (MM) are used to forecast long term energy demand. ANFIS is one of the famous artificial intelligence and has widely used to solve forecasting problems in literature. In addition to numerical inputs, ANFIS has linguistics inputs. The results obtained from ESDP, ANFIS and MM are compared to show availability. In order to show error levels mean absolute percentage error (MAPE) and (MAE) are used. The obtained results show that the proposed algorithms are available.

AbstractThe ethylene glycol oxidation reaction on nickel and ruthenium modified palladium nanocatalysts was investigated with electrochemical, spectroelectrochemical, and chromatographic methods. These carbon‐supported materials, prepared by a revisited polyol approach, exhibited high activity towards the ethylene glycol electrooxidation in alkaline medium. Electrolysis coupled with high performance liquid chromatography/mass spectrometry (HPLC‐MS) and in situ Fourier transform infrared spectroscopy (FTIRS) measurements allowed us to determine the different compounds electrogenerated in the oxidative conversion of this two‐carbon molecule. High value‐added products such as oxalate, glyoxylate, and glycolate were identified in all electrolytic solutions, whereas glyoxylate was selectively formed at the Ru45@Pd55/C electrode surface. In situ FTIRS results also showed a decrease in the pH value in the thin layer near the electrode as a consequence of OH− consumption during the spectroelectrochemical experiments.

AbstractService unavailability of transmission lines, due to the direct and indirect lightning strikes, is evaluated as a challenging issue within electric companies. The lightning event can produce dangerous overvoltage, equipment failures, and power supply interruptions. Here, externally gapped line arresters (EGLAs) performances installed on a 63 kV transmission line are modelled using EMTP‐ATP to investigate their capability to withstand current and energy discharged by lightning strokes during back flashover phenomena. Frequency behaviour of the grounding system impedance, first and subsequent lightning current parameters effects on insulators back flashover and lightning flashover failure rate have been considered by Monte‐Carlo method. Then, extensive analysis has been carried out to study the absorbed energy of the EGLA and its expected life. The results show the dependency of failure rate and the EGLA expected life on the soil resistivity and lightning strike parameters. The selected EGLA must be provided sufficient lightning protection to the transmission line based on its absorbed energy capability, the soil and lightning parameters and be complied with the discharge energy capability requirement specified by the utility company.

Abstract The oxidation characteristics of several small methyl and ethyl esters with carbon number less than six were investigated in laminar flames. The kinetics of such fuels are subsets of those of larger alkyl esters that are constituents of practical biodiesel fuels. A total of seven fuels, namely methyl formate, methyl acetate, methyl propionate, methyl butanoate, ethyl formate, ethyl acetate, and ethyl propionate were considered. Experiments were conducted at atmospheric pressure, elevated reactant temperatures, and over a wide range of equivalence ratios. Laminar flame speeds were determined in the counterflow configuration in which flow velocities were measured using particle image velocimetry. Several detailed kinetic models were tested against the experimental data, and insight was provided into the high-temperature combustion kinetics of the aforementioned fuels. Based on comparisons between experimental and computed results it became apparent that the chemistry of alkyl-ester combustion chemistry is evolving and much needs to be done in order to derive improved rate constants for a wide range of elementary steps.

Abstract In this work addition of ethanol to high viscosity jatropha methyl ester (JME) through port injection is investigated in order to determine its effect fuel viscosity reduction on diesel engine performance. In addition to viscosity alteration, the impact of ethanol addition on combustion characteristics such as combustion duration, ignition delay and emissions levels from diesel engines fuelled with blends of ethanol, diesel and JME is studied in particular. It is found that blending of oxygenated fuels with diesel modifies the chemical structure and physical properties which again alter the engine operating conditions, combustion parameters and emissions levels. However, the injection of only 5% ethanol through port injection allows for a total of 25% blending of biofuels into diesel yet keeping the fuel characteristics close to that of conventional diesel. However, both experimental and numerical results show that ethanol addition in JME blended diesel results in a slight increase in fuel consumption and thermal efficiency for the same power outputs as that of conventional diesel fuel. Also, the combustion characteristics with ethanol addition include improved maximum in-cylinder peak pressure, cumulative heat release (CHR) rate of heat release (ROHR), in-cylinder peak temperature and combustion duration. Regarding emission characteristics the experimental results show significant reduction in smoke, carbon monoxide (CO) and total hydrocarbon (THC) emissions with extended oxygen mass percentage in the fuel at higher engine loads. However, oxides of nitrogen (NOx) emissions are found to increase at high loads although the common tradeoff between smoke and NOx is found to be more prominent for the oxygenated fuels.

White sweet clover found voluntarily growing on a deep bed of soft coal fly ash was found to contain high concentrations of a number of elements including selenium, bromine, and molybdenum, rubidium, strontium, and others. The clover was harvested and fed as 23.5% of a dry pelleted ration to lambs and pregnant goats for up to 173 days. High concentrations of selenium were found in 11 tissues, blood, goats' milk, and excreta of lambs, goats, and newborn kids. Molybdenum in liver, strontium in bone, and bromine and rubidium in animal tissues were also elevated over those in the corresponding tissues of animals fed an identical ration containing control clover grown on soil. No gross or histologic lesions were present in any of the animals.

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