• Energy Research
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In a recent meeting of IEA's Annex 23, several members presented their conclusions on the modeling of phase change materials behavior in the context of building applications. These conclusions were in agreement with those of a vast review, involving the survey of more than 250 journal papers, undertaken earlier by the group of Ecole de technologie superieure. In brief, it can be stated that, at this point, the confidence in reviewed models is too low to use them to predict the future behavior of a building with confidence. Moreover, it was found that overall thermal behaviors of PCM are poorly known, which by itself creates an intrinsic unknown in any model. Models themselves are most of time suspicious as they are often not tested in a very stringent or exhaustive way. In addition, it also appears that modeling parameters are somewhat too simplified to realistically describe the complete physics needed to predict the real life performance of PCMs added to a building. As a result, steps are now taken to create standard model benchmarks that will improve the confidence of the users. Hopefully, following these efforts, confidence will increase and usage of PCM in buildings should be eased.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

Abstract Thermal properties of the different building envelopes, such as thermal transmittance in steady state, heat storage capacity and dynamic thermal responses, must be taken into account during the design phase of buildings. The evaluation and measurement of these parameters in multilayered samples are difficult because of the irregular morphology of the used materials and the difficulty in providing the well-controlled environment needed for the measurements. A new equipment has been designed to measure the thermal response and heat capacity of composite walls of different materials simulating real building envelopes. The equipment presented in this paper was used to test the improvement in the thermal response of a building envelope due to the incorporation of PCM. This study is focused on wood structural panels attached to a gypsum board, which is either impregnated or not with PCM. The four edges of the composite sample are properly insulated to ensure one-dimensional heat flow. The two faces of the sample are exposed to controlled environments heated and cooled by copper coils with thermo stated water supplied by water baths. The measured surface heat fluxes at both surfaces of the sample and temperature distribution in the sample provide accurate assessment to thermal mass and dynamic response of the composite wall, while the steady state measurements provide an accurate estimate of its effective thermal transmittance.

Building-integrated greenery (BIG) systems, which include green roofs and green facades, are well-established nature-based solutions (NBS) with proven scientific benefits. However, initial costs and economic apprehensions stemming from potential negative outcomes act as adoption barriers. Furthermore, the lack of standardized indicators and assessment methodologies for evaluating the city-level impacts of BIG systems presents challenges for investors and policy makers. This paper addresses these issues by presenting a comprehensive set of indicators derived from widely accepted frameworks, such as the Common International Classification of Ecosystem Services (CICES) and the NBS impact evaluation handbook. These indicators contribute to the creation of a ‘sustainability factor’, which facilitates cost–benefit analyses for BIG projects using locally sourced data. The practical application of this factor to a 3500 m2 green roof in Lleida, Catalonia (Spain) demonstrates that allocating space for urban horticultural production (i.e., food production), CO2 capture, and creating new recreational areas produces benefits that outweigh the costs by a factor value of nine during the operational phase of the green roof. This cost–benefit analysis provides critical insights for investment decisions and public policies, especially considering the significant benefits at the city level associated with the implementation of BIG systems.

The building and construction sector is a large contributor to anthropogenic greenhouse gas emissions and consumes vast natural resources. Improvements in this sector are of fundamental importance for national and global targets to combat climate change. In this context, vertical greenery systems (VGS) in buildings have become popular in urban areas to restore green space in cities and be an adaptation strategy for challenges such as climate change. However, only a small amount of knowledge is available on the different VGS environmental impacts. This paper discusses a comparative life cycle assessment (LCA) between a building with green walls, a building with green facades and a reference building without any greenery system in the continental Mediterranean climate. This life cycle assessment is carried according to ISO 14040/44 using ReCiPe and GWP indicators. Moreover, this study fills this gap by thoroughly tracking and quantifying all impacts in all phases of the building life cycle related to the manufacturing and construction stage, maintenance, use stage (operational energy use experimentally tested), and final disposal. The adopted functional unit is the square meter of the facade. Results showed that the operational stage had the highest impact contributing by up to 90% of the total environmental impacts during its 50 years life cycle. Moreover, when considering VGS, there is an annual reduction of about 1% in the environmental burdens. However, in summer, the reduction is almost 50%. Finally, if the use stage is excluded, the manufacturing and the maintenance stage are the most significant contributors, especially in the green wall system.

Phase change materials (PCM) are used in many industrial and residential applications for their advantageous characteristic of high capacity of latent thermal storage by means of an isothermal process. In this context, it is very useful to have predictive mathematical models for the analysis of the thermal performance and for the thermal design of these layers. In this work, an experimental validation of an analytical model that resolves the steady periodic heat transfer problem in a finite layer of PCM is presented. The experimental investigation was conducted employing a PCM with thermophysical and thermochemical behavior very close to those hypothesized in the formulation of the analytical model. For the evaluation of the thermophysical properties of the PCM sample used, an experimental procedure created by the authors was employed. In all tests realized in a sinusoidal and non-sinusoidal periodic regime, the comparison between the measured and calculated trends of the temperature at different sample heights and of the surface heat fluxes show an excellent agreement. Moreover, also having verified the analytical total stored energy, the analytical model constitutes a valid instrument for the evaluation of the latent and sensible contribution and the trend in time of the position of the bi-phase interface. Peer Reviewed

This paper presents a comprehensive review of all correlations and experimental studies available in the literature to determine the heat transfer coefficient of supercritical CO2 flowing in heat exchangers. The different applications in which it is used are also reviewed and discussed. The correlations obtained from extensive experimental measurements are presented for different geometries (horizontal, vertical and inclined tubes, closed-loop circular pipes, and mini-channels) and dimensions. The review shows that there is a lack of a unique universal correlation for each geometry, suggesting the need for more work in this area. The work partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER) and ENE2015-64117-C5-3-R (MINECO/FEDER)). The authors would like to thank the Catalan Government for the quality accreditation given to their research group (2014 SGR 123). This project has received funding from the European Commission Seventh Framework Programme (FP/2007-2013) under Grant agreement N°PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES), and the funds received by the Royal Society of New Zealand. Alvaro de Gracia would like to thank Ministerio de Economia y Competitividad de España for Grant Juan de la Cierva, FJCI-2014-19940.