• Energy Research
• 2016-2025close
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Abstract Double and added double stage organic Rankine cycle systems are configured to recover exhaust gas waste heat of dual fuel engines. To evaluate the performance of the models proposed here, energy, exergy and economic analyses are performed. Several working fluids are evaluated for recommendation for double and added double stage organic Rankine cycle systems. In the double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in parallel. Working fluids R123, R141b, and R601 are used in cycle 1, and R245fa, R236ea, and R1233zd in cycle 2. In the double stage organic Rankine cycle, the working fluid combinations of R601-R1233zd, R601-R245fa and R123-R245fa show better performance when considering power, heat transfer area and payback period, which are 1760 kW, 2108.9 m2 and 4.21 year, respectively for R601-R245fa. In the added double stage organic Rankine cycle, cycle 1 and cycle 2 are connected in two stages and cycle 1 and cycle 3 in parallel. The net power of the working fluid combinations of R123-R245fa and R123-R1233zd are 1799 kW and 1782 kW, respectively, which are higher than those of the others. Further, for R123-R245fa, the heat transfer area and payback period are 3352 m2 and 6.20 year, respectively, which is better compared to those of other working fluid combinations.

Abstract Knocking combustion for spark-ignition engine is related to auto-ignition of a portion of the unburned fuel-air mixture. In this investigation, the detailed chemical kinetic mechanism was engaged to numerically study the auto-ignition characteristics of hydrogen-enriched methane under engine-relevant conditions. Compared with the experimental data, the USC Mech 2.0 mechanism obtained the closest agreement, and it was adopted in the sensitivity analysis, the rate of production (ROP) analysis and the reaction pathway analysis. Results showed that at high temperature and high pressure, the ignition delay times (IDs) of CH4/H2 fuel blends reduce significantly (by two orders of magnitude at most) with rising hydrogen fraction, but the decline rate is not so obvious (within 37.3%) at low temperature. The sensitivity analysis indicated that at high temperature the reaction (R1) and reactions (R2, R3) promote each other while at low temperature only the reaction (R3) unilaterally facilitates the reaction (R12). The ROP analysis implied that the decrease of IDs of methane by hydrogen addition is realized through increasing the H, O, and OH radical production. Interestingly, the IDs for CH4/H2 fuel blends show different trends at different temperature, which decrease (by 47.5% at most) at low temperature but increase (by 132.7% at most) at high temperature as the equivalence ratio rises. The sensitivity analysis showed that the ignition kinetics for CH4/H2 fuel blends more depend on the CH4 concentration at low temperature but oxygen concentration at high temperature. This investigation not only supplements the fundamental combustion studies of CH4/H2 fuel blends in elevated pressures, but also reveals the influence mechanism of hydrogen addition and equivalence ratio on the IDs of CH4/H2 fuel blends at high pressure. More importantly, it may offer fundamental insights for the control of knocking combustion of spark-ignition (SI) engine.

Abstract Thermal energy storage systems based on Phase change materials (PCM) are an attractive option to bridge the temporal and spatial gap between the energy demand and supply. But, these systems possess poor thermal conductivity causing reduced rate of heat transfer. The objective of the present study is to numerically analyze the melting process in an optimized finned latent heat storage system dispersed with varying volume fraction of Graphene nano plates (GNP). The individual effect of incorporating fins, GNP and a combination of both at different volume fraction has been studied. Effective thermal conductivity of nano-composite PCM has been theoretically evaluated including the effect of aspect ratio, interfacial thermal resistance, anisotropy, non-linear effects as well as concentration for the dispersed GNP. In this work, Dynamic differential scanning calorimetry tests are performed to evaluate the phase change temperature, latent heat and specific heat of the sugar alcohol (d- mannitol). Transient variation of liquid fraction, average temperature and radial/longitudinal temperature differentials are presented which would be useful for designing medium temperature (160–200 °C) storage systems for various applications. Fin height is varied to obtain an optimum fin size such that natural convection currents are not impeded. Various heat transfer models (including natural convection) are analysed using the actual plant data of a double effect solar absorption system at different arrangements of fins and GNP. Effect of Reynolds number and inlet temperature of HTF on the system performance have also been studied. A reduction of 68% in total melting time is observed in finned LHSS with 5% GNP as compared to a conventional system.

Abstract Heat pipes have been extensively applied in the domain of energy conversion and heat recovery application. A novel radial heat pipe with internally finned condenser has been proposed to recover waste heat from air conditioning units. Full mathematical description and computational fluid dynamics model were developed to predict the loop flow and thermal performance in a single radial heat pipe, respectively. The research focuses mainly on the effects of input power, filling ratio, pipe diameter, and velocity of the cooling water on the thermal performance and entropy generation rate of this novel heat pipe. Numerical results illustrate that average reductions in total thermal resistance with utilization of fins approximately achieved 8.69% and 14.78% for fins nf = 4 and nf = 8, respectively. Similarly, entropy generation rate shows an average decrease of 19.4% and 37.5% for identical operations. Additionally, the effect of internally finned condenser on the multiphase fluid flow has been comprehensively analyzed, including the break of the condensed film, generation of bubbles and nucleation boiling. The results further indicate that incorporation of internal fins has a significant influence on enhancing thermal homogenization and waste thermal recovery efficiency of a radial heat pipe. Case results agreed well with experimental data within average deviation being no more than 10%.

Abstract Distributed energy system becomes increasingly popular due to high efficiency and low pollution emissions. When it operates following the electricity load, thermal energy storage system can be used to accommodate surplus cooling and heating and improve the energy efficiency. This study investigates the energy and economic performance of thermal storage systems for surplus cooling and heating in distributed energy system, considering the impacts of climates, building combinations and cooling/heating supply systems. Results show that the thermal storage system can improve the primary energy efficiency and is more useful when residential buildings adopt centralized heating and decentralized cooling systems. By varying climates and building combinations, the thermal storage system can improve the primary energy efficiency by 0.28%–3.69%. The economic performance is not promising with a long payback period. The main reason is that the overall utilization rate of the surplus energy is low (less than 45%), especially when the cooling/heating load is low continually during spring and autumn. Additionally, the effect of static and dynamic thermal storage model is analyzed. Results show that the static model would over-estimate the performance of the thermal storage system significantly and the dynamic model is recommended.

Abstract Catalyst layer structural changes in polymer electrolyte membrane fuel cells have significant impact on the cell performance and durability. In this study, ex-situ experiments are designed to investigate the effect of humidity and/or thermal cycles on the structural changes of catalyst layers. The relative humidity and temperature are controlled by an environmental chamber and the catalyst layer structure is characterized by scanning electron microscopy and optical microscopy. The experimental results indicate that crack growth and development, catalyst agglomerate detachment, and surface bulges are the main structural changes of the catalyst layers. Applying relative humidity and thermal cycling simultaneously causes the most significant crack growth, while applying thermal cycling alone causes no appreciable changes. This indicates that the absolute humidity is the key parameter for the crack growth. Through cyclic voltammetry analysis, it is shown that the electrochemical active surface area decreases from 64.1 m2 g−1 to 49.1 m2 g−1 after 500 combined relative humidity and thermal cycles. Analyses of electrochemical impedance spectroscopy show that the charge transfer resistance and ohmic resistance increase significantly after 500 combined relative humidity and thermal cycles, causing the cell performance degradation.

Abstract A polymer-based flexible pulsating heat pipe (FPHP) as a flexible heat spreader was developed, and a series of experiments were conducted to evaluate the thermal performance and the long-term reliability of the FPHP. The FPHP consisted of a multilayer laminated film and a low-density polyethylene (LDPE) sheet. HFE-7000 was used as the working fluid, and the width, length, and thickness of the FPHP were 53.4 mm, 85.5 mm, and 1 mm, respectively. To minimize the permeation of non-condensable gases (NCGs) in a lateral direction, the heat-sealed flanges were covered with the indium coating. Owing to the indium-coated flanges, the long-term reliability of the FPHP drastically increased. The lifetime of the FPHP was defined to evaluate the long-term reliability. The FPHP had a lifetime of 18.2 days in the acceleration test environment, which was equivalent to 306 days in a standard atmosphere and 17 times longer than the previous polymer-based PHP. The FPHP had the thermal resistance of 2.41 K/W, which is 37% lower than that of the copper reference sample in a vertical orientation. Under bending conditions as well as in a horizontal orientation, the FPHP still operated well as a PHP, but the thermal resistance increased slightly. The fabrication method of the FPHP is effective in minimizing the permeation of NCGs in a lateral direction and can pave the way for fabricating a thin flexible heat spreader that has high flexibility, high thermal performance, and long-term reliability.