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In the present work, a novel hybrid solar-based smart building energy system is introduced and studied. The system comprises innovative photovoltaic-thermal-cooling (PVTC) panels integrated with hot and cold storages with two-way interaction with electricity, heat, and cooling networks (if any). The proposed system is compared with PV-based systems integrated with battery and heat pump for a case study complex building in Aarhus, Denmark. The comparison is conducted by evaluating the performance and economic indicators and investigating the effect of significant parameters on each scenario via a parametric study. Furthermore, the optimal operating conditions and sizing of the proposed system are determined using the genetic algorithm method considering initial cost and traded energy with local energy networks as the objective functions. The comparison results show that the proposed solution is the most cost-effective scenario with the lowest initial cost of about 457,000 $ and a payback period of 6.6 years. This is mainly due to the simultaneous interaction with electricity/heat/cooling networks as well as the elimination of the battery and the heat pump, which are offered by the proposed scenario. It is shown that, in comparison to PV panels, the PVTC can produce 328.7 MWh and 125.6 MWh extra heat and cooling annually. The scatter distribution of significant parameters shows that the panel area and heat storage capacity are not sensitive parameters, and keeping the cold storage capacity at the lower bound is a techno-economically better option.

In the last years, the concept of “smart city” has been the subject of increasing attention in urban planning and governance due to the sustainability challenges and great technological advancements. Although the relevant literature highlights those smart cities can create a fertile environment to drive innovation from a technological, managerial and organizational, and policy point of view how smart cities function, in terms of their value chain and in light of sustainability and circularity is still an open question. Based on these considerations, this work aims to investigate how smart cities deliver value by combining environmental, societal, and financial priorities to re-imagine their core business models and shift the boundaries of urban competition in light of circular economy principles. To reach this goal, the tool Sustainable Business Model Innovation Canvas has been applied in the urban context with the aim to create and leverage an environmental and societal surplus in light of circularity in the smart city framework. Preliminary results shed light on new vistas on the future and new challenges of smart cities particularly relevant for facing the current complexity of the economy, social, and environmental changes.

In order to make adequate projections on the consequences of climate change stressors on marine organisms, it is important to know how impacts of these stressors are affected by the presence of other species. Here we assessed the direct effects of ocean warming (OW) and acidification (OA) along with non-consumptive effects (NCEs) of a predatory crab and/or a predatory snail on the habitat-forming mussel Perumytilus purpuratus. Mussels were exposed for 10-14 weeks to contrasting pCO2 (500 and 1400 μatm) and temperature (15 and 20 °C) levels, in the presence/absence of cues from one or two predator species. We compared mussel traits at sub-organismal (nutritional status, metabolic capacity-ATP production-, cell stress condition via HSP70 expression) and organismal (survival, oxygen consumption, growth, byssus biogenesis, clearance rates, aggregation) levels. OA increased the mussels' oxygen consumption; and OA combined with OW increased ATP demand and the use of carbohydrate reserves. Mussels at present-day pCO2 levels had the highest protein content. Under OW the predatory snail cues induced the highest cell stress condition on the mussels. Temperature, predator cues and the interaction between them affected mussel growth. Mussels grew larger at the control temperature (15 °C) when crab and snail cues were present. Mussel wet mass and calcification were affected by predator cues; with highest values recorded in crab cue presence (isolated or combined with snail cues). In the absence of predator cues in the trails, byssus biogenesis was affected by OA, OW and the OA × OW and OA × predator cues interactions. At present-day pCO2 levels, more byssus was recorded with snail than with crab cues. Clearance rates were affected by temperature, pCO2 and the interaction between them. The investigated stressors had no effects on mussel aggregation. We conclude that OA, OW and the NCEs may lead to neutral, positive or negative consequences for mussels.

Abstract This work reports a detailed experimental study that is aimed at investigating the Thermal Energy Storage (TES) performance of cementitious systems containing Microencapsulated Phase Change Materials (MPCMs). New spherical-shaped test specimens for TES measurements were produced following an innovative casting technique, developed at the Institut fur Werkstoffe im Bauwesen – TU Darmstadt. Three water-to-cement ratios and three MPCMs volume fractions, leading to a total of nine different mixtures, were investigated. The thermal experiments were accompanied by mechanical tests to observe the effect MPCMs have on the resulting strengths in both compression and bending. The analysis and discussion of the TES results are employed for calibrating an enthalpy-based model. The experimental data have been applied to evaluate the corresponding temperature-based material parameters like specific heat, conductivity, or more in general, the energy storage capacity of a system under transient heat conduction conditions.

AbstractThe implementation of a circular economy is a fundamental step to create a greater and more sustainable future for a better use of resources and energy. Wastes and in particular municipal solid waste represent an untapped source of carbon (and hydrogen) to produce a large range of chemicals from methane to alcohols (as methanol or ethanol) or urea. The waste to chemical process and related economics are assessed in this concept article to show the validity of such solution both from an economic point of view and from an environmental perspective considering the sensible reduction in greenhouse gas emissions with respect to conventional production from fossil fuels.

Bioenergy crops are well known for their ability to reduce greenhouse gas emissions and increase the soil carbon stock. Although such crops are often held to be in competition with food crops and thus raise the question of current and future food security, at the same time mitigation measures are required to tackle climate change and sustain local farming communities and crop production. However, in some cases the actions envisaged for specific pedo-climatic conditions are not always economically sustainable by farmers. In this frame, energy crops with high environmental adaptability and yields, such as giant reed (Arundo donax L.), may represent an opportunity to improve farm incomes, making marginal areas not suitable for food production once again productive. In so doing, three of the 17 Sustainable Development Goals (SDGs) of the United Nations would be met, namely SDG 2 on food security and sustainable agriculture, SDG 7 on reliable, sustainable and modern energy, and SDG 13 on action to combat climate change and its impacts. In this work, the response of giant reed in the marginal areas of an agricultural district of southern Italy (Destra Sele) and expected farm incomes under climate change (2021-2050) are evaluated. The normalized water productivity index of giant reed was determined (WP; 30.1gm-2) by means of a SWAP agro-hydrological model, calibrated and validated on two years of a long-term field experiment. The model was used to estimate giant reed response (biomass yield) in marginal areas under climate change, and economic evaluation was performed to determine expected farm incomes (woodchips and chopped forage). The results show that woodchip production represents the most profitable option for farmers, yielding a gross margin 50% lower than ordinary high-input maize cultivation across the study area.

Abstract A key challenge for efficient thermal management of civil buildings is the development of shape-stabilized phase change materials (PCM) for thermal energy storage and release. Nevertheless, some issues related to the disposal of such devices are arising as they are generally not biodegradable and recyclable. In this work, we developed two new renewable and biodegradable thermal energy storage composites obtained from renewable resources. These are based on the use of bio-derived alcohol as PCM and on porous biogenic structures, namely cuttlebone and pomelo peel, as shape stabilizers, which are currently waste materials. The results point out that both cuttlebone and pomelo peel can spontaneously absorb huge amounts of the considered PCM and retain it in the liquid state. The thermal energy storage capacity of the composites is about 70% that of neat PCM, whereas the volumetric efficiency (i.e., the ratio between the thermal energy storage capacity of the composite and the neat PCM in J cm−3) approaches 90% and 70% in cuttlebone and pomelo peel composites, respectively. The properties appear stable over at least 100 melting/solidification cycles.

Changes in the main weather features are becoming perceivable in Italy. In the last years, the average temperature and the intensity of rainstorms are increasing. Such phenomena could lead to changes in the earth-atmosphere interaction. Accounting for the high vulnerability of the Italian territory, an obvious consequence would concern the effects on the hydro-geological hazards, including landslides and floods. As a matter of fact, the higher frequency of high magnitude flood and landslide events represent an alarm bell. It is necessary to explore with all available instruments the consequences of the potential climate changes. Since quantitative predictions are not possible, the only way to run is depicting rational scenarios for the most vulnerable contexts adopting a multidisciplinary approach. Based on projections of potential climate changes in the 21st century, the report examines their potential impact in the context of the Italian peninsula. After a general overview about typical slope responses to weather changes, some quantitative scenarios have been depicted for representative geomorphological contexts. The last part of the paper examines changes in the expected risk, based on the characteristics of the Italian territory and its vulnerability, looking at the initiatives to undertake for its mitigation.