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The paper describes formation and spreading of dense shelf waters in the Adriatic Sea (North Adriatic Dense Water, NAdDW) during the winter of 2012 as a consequence of an intense and long cold air outbreak of northeasterly Bora winds. As a result, during February 2012 northern Adriatic Sea water temperature dropped to about 6 degrees C and density exceeded 1030 kg/m(3), most likely the maximum value since 1929. NAdDW dynamics has been investigated by means of a 3-D ocean-wave coupled model running on a high resolution and eddy-permitting grid. The numerical experiments have relied on the Coupled-Ocean-Atmosphere-Wave-Sediment-Transport (COAWST) system forced one-way with atmospheric forcings provided by the model COSMO-17. A suite of observational data has been used to characterize the Bora event and evaluate numerical model performance. At sub-basin scales, the newly formed waters flowing southerly have produced a water renewal of the northern Adriatic, as more than 50% of water volumes have left the basin. Dense waters volume transports, evaluated through different Adriatic cross-sections, have been modulated by tides (damped for the densest water masses) and reached about 1 Sv. The contribution of wave-induced forcings has been quantified and examined, indicating that these represent a major driving mechanism during NAdDW production and spreading phases. This work provides evidence that NAdDW is spread accordingly with two different mechanisms: at early stages of its formation, the wind-driven ocean circulation pushes newly formed waters to leave the northern basin with relatively high speeds (about 0.30 m/s). Later on, remaining NAdDW leaks slowly out (0.09 m/s as average) from the production site. Residence times of dense waters in the north, middle, and south Adriatic Sea are also documented. (C) 2014 Elsevier Ltd. All rights reserved.

In the present work, a novel hybrid solar-based smart building energy system is introduced and studied. The system comprises innovative photovoltaic-thermal-cooling (PVTC) panels integrated with hot and cold storages with two-way interaction with electricity, heat, and cooling networks (if any). The proposed system is compared with PV-based systems integrated with battery and heat pump for a case study complex building in Aarhus, Denmark. The comparison is conducted by evaluating the performance and economic indicators and investigating the effect of significant parameters on each scenario via a parametric study. Furthermore, the optimal operating conditions and sizing of the proposed system are determined using the genetic algorithm method considering initial cost and traded energy with local energy networks as the objective functions. The comparison results show that the proposed solution is the most cost-effective scenario with the lowest initial cost of about 457,000 $ and a payback period of 6.6 years. This is mainly due to the simultaneous interaction with electricity/heat/cooling networks as well as the elimination of the battery and the heat pump, which are offered by the proposed scenario. It is shown that, in comparison to PV panels, the PVTC can produce 328.7 MWh and 125.6 MWh extra heat and cooling annually. The scatter distribution of significant parameters shows that the panel area and heat storage capacity are not sensitive parameters, and keeping the cold storage capacity at the lower bound is a techno-economically better option.

Abstract Sustainability is an important and difficult consideration for the stakeholders/decision-makers when planning a biofuel supply network. In this paper, a Mixed-Integer Non-linear Programming (MINLP) model was developed with the aim to help the stakeholders/decision-maker to select the most sustainable design. In the proposed model, the emergy sustainability index of the whole biodiesel supply networks in a life cycle perspective is employed as the measure of the sustainability, and multiple feedstocks, multiple transport modes, multiple regions for biodiesel production and multiple distribution centers can be considered. After describing the process and mathematic framework of the model, an illustrative case was studied and demonstrated that the proposed methodology is feasible for finding the most sustainable design and planning of biodiesel supply chains.

Abstract This paper addresses the importance of the probabilistic analysis in determining the wave energy potential to support the design of electrical generators for wave energy conversion. The irregular activity of ocean waves induces variable frequencies and amplitudes of operation for point absorbers electrical generators, which may lead to the construction of inefficient electrical machines. Applying probabilistic models to describe the ocean wave's behavior allows the determination of the values most likely to be sampled for ocean-state parameters. Knowing these values, the most expected ocean wave potential can be determined and a proper device design can be performed. This work also refers to the importance of using the joint probability models instead of the marginal ones. Seven locations at the Portuguese coast are evaluated in order to determine their wave energy resource potential.

In the last years, the concept of “smart city” has been the subject of increasing attention in urban planning and governance due to the sustainability challenges and great technological advancements. Although the relevant literature highlights those smart cities can create a fertile environment to drive innovation from a technological, managerial and organizational, and policy point of view how smart cities function, in terms of their value chain and in light of sustainability and circularity is still an open question. Based on these considerations, this work aims to investigate how smart cities deliver value by combining environmental, societal, and financial priorities to re-imagine their core business models and shift the boundaries of urban competition in light of circular economy principles. To reach this goal, the tool Sustainable Business Model Innovation Canvas has been applied in the urban context with the aim to create and leverage an environmental and societal surplus in light of circularity in the smart city framework. Preliminary results shed light on new vistas on the future and new challenges of smart cities particularly relevant for facing the current complexity of the economy, social, and environmental changes.

In order to make adequate projections on the consequences of climate change stressors on marine organisms, it is important to know how impacts of these stressors are affected by the presence of other species. Here we assessed the direct effects of ocean warming (OW) and acidification (OA) along with non-consumptive effects (NCEs) of a predatory crab and/or a predatory snail on the habitat-forming mussel Perumytilus purpuratus. Mussels were exposed for 10-14 weeks to contrasting pCO2 (500 and 1400 μatm) and temperature (15 and 20 °C) levels, in the presence/absence of cues from one or two predator species. We compared mussel traits at sub-organismal (nutritional status, metabolic capacity-ATP production-, cell stress condition via HSP70 expression) and organismal (survival, oxygen consumption, growth, byssus biogenesis, clearance rates, aggregation) levels. OA increased the mussels' oxygen consumption; and OA combined with OW increased ATP demand and the use of carbohydrate reserves. Mussels at present-day pCO2 levels had the highest protein content. Under OW the predatory snail cues induced the highest cell stress condition on the mussels. Temperature, predator cues and the interaction between them affected mussel growth. Mussels grew larger at the control temperature (15 °C) when crab and snail cues were present. Mussel wet mass and calcification were affected by predator cues; with highest values recorded in crab cue presence (isolated or combined with snail cues). In the absence of predator cues in the trails, byssus biogenesis was affected by OA, OW and the OA × OW and OA × predator cues interactions. At present-day pCO2 levels, more byssus was recorded with snail than with crab cues. Clearance rates were affected by temperature, pCO2 and the interaction between them. The investigated stressors had no effects on mussel aggregation. We conclude that OA, OW and the NCEs may lead to neutral, positive or negative consequences for mussels.

Abstract This work reports a detailed experimental study that is aimed at investigating the Thermal Energy Storage (TES) performance of cementitious systems containing Microencapsulated Phase Change Materials (MPCMs). New spherical-shaped test specimens for TES measurements were produced following an innovative casting technique, developed at the Institut fur Werkstoffe im Bauwesen – TU Darmstadt. Three water-to-cement ratios and three MPCMs volume fractions, leading to a total of nine different mixtures, were investigated. The thermal experiments were accompanied by mechanical tests to observe the effect MPCMs have on the resulting strengths in both compression and bending. The analysis and discussion of the TES results are employed for calibrating an enthalpy-based model. The experimental data have been applied to evaluate the corresponding temperature-based material parameters like specific heat, conductivity, or more in general, the energy storage capacity of a system under transient heat conduction conditions.

AbstractThe implementation of a circular economy is a fundamental step to create a greater and more sustainable future for a better use of resources and energy. Wastes and in particular municipal solid waste represent an untapped source of carbon (and hydrogen) to produce a large range of chemicals from methane to alcohols (as methanol or ethanol) or urea. The waste to chemical process and related economics are assessed in this concept article to show the validity of such solution both from an economic point of view and from an environmental perspective considering the sensible reduction in greenhouse gas emissions with respect to conventional production from fossil fuels.