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AbstractBACKGROUND: Inappropriate utilisation of biosolids may adversely impact agrosystem productivity. Here, we address the response of wheat (Triticum durum) to different doses (0, 40, 100, 200 and 300 t ha−1) of either municipal solid waste (MSW) compost or sewage sludge in a greenhouse pot experiment. Plant growth, heavy metal uptake, and antioxidant activity were considered.RESULTS: Biomass production of treated plants was significantly enhanced at 40 t ha−1 and 100 t ha−1 of MSW compost (+48% and +78% relative to the control, respectively). At the same doses of sewage sludge, the increase was only 18%. Higher doses of both biosolids restricted significantly the plant growth, in concomitance with the significant accumulation of heavy metals (Ni2+, Pb2+, Cu2+ and Zn2+), especially in leaves. Leaf activities of antioxidant enzymes (ascorbate peroxidase, glutathione reductase, catalase and superoxide dismutase) were unchanged at 40 t ha−1 MSW compost or sewage sludge, but were significantly stimulated at higher doses (200–300 t ha−1), together with higher leaf concentration of reduced glutathione.CONCLUSION: This preliminary study suggests that a MSW supply at moderate doses (100 t ha−1) could be highly beneficial for wheat productivity. Copyright © 2010 Society of Chemical Industry

Diesel engine exhausts from a common rail 3.0 L F1C diesel engine were analyzed at two different load conditions of the WLTC testing cycle downstream of both the diesel particulate filter (DPF) and selective catalytic reactor (SCR) to verify their effect on the characteristics of carbon particulate matter. An array of chemical, physical and spectroscopic techniques (gas chromatography coupled with mass spectrometry (GC-MS), mobility analyzer, UV-Visible absorption and fluorescence spectroscopy) was applied for characterizing polycyclic aromatic hydrocarbons (PAH), heavy aromatic compounds and soot, constituting the particulate matter (PM) sampled from the exhaust. The engine was operated in half load (HL) (188 Nm, representing the more common condition for engine in urban traffic) and full load (FL) (452 Nm, representing the best performance of the engine operation) conditions, at the same engine speed (2000 rpm). Soot formation was enhanced in HL condition, with respect to FL, but, just because of the much lower soot amount, the after-treatment systems in this last condition resulted to be less efficient in the soot abatement. Indeed, the abatement through DPF was about 40% lower in the FL condition with respect to HL condition, and any significant further concentration decrease was found after SCR, in both conditions. By contrast, PAH concentration after DPF abatement was found to be higher in the HL with respect to FL condition. A further PAH concentration decrease of about 30% was found after the SCR in the HL condition whereas in FL the reduction was only about 5-6%. Also the heavy aromatic compounds having molecular weight above the GC-MS detection limit (300 u), were mitigated by SCR. Therefore, SCR did not cause a further soot reduction, whereas it was effective in largely reducing PAH and heavy aromatics emissions, especially in the lower temperature condition featuring the half-load condition, when combustion efficiency is worse. Moreover, SCR system reduced the emission of small particles probably due to an enhanced agglomeration of particles, with beneficial effect on the harmfulness to human health.

In this paper some preliminary experimental results on a Zebra battery based propulsion system for urban bus applications are presented. The tests were carried out using a laboratory 1:1 scale test bench, composed by a 65 kW electric drive, specifically designed for urban bus applications, supplied by two 20 kWh Zebra batteries connected in parallel. The electric power train was tested on a laboratory bench, connected through a fixed ratio gear box to a 100 kW regenerative electric brake provided with speed and torque controls, in order to evaluate the propulsion system performance in steady state operative conditions. The obtained preliminary experimental results were utilized to implement a Matlab-Simulink model of urban bus, which might be powered by the same electric propulsion system studied. Thanks to this model it was possible to evaluate the dynamic behavior of the urban bus, working on standard driving cycles, taking into account the resistant forces represented by proper vehicle/road/aerodynamic parameters. An evaluation of the expected real vehicle driving range was also estimated in different road conditions.

Intention of this work is to investigate the opportunity and feasibility of energy efficient networking in Home and Building automation protocols. Wired HBAS have traditionally devoted a relatively little attention to this point, especially if compared to wireless networks. This paper will try to address the issue by evaluating the introduction of power state switching in a real scenario and proposing the concept of functional and spatial adjacency among packets.

Emergency building, devoted to give rapid and effective housing solutions to catastrophic and unexpected events, relies on the basic principles of construction rapidity and reversibility as well as the use of alternative energy sources. The growing need for environmental impact reduction in the building sector represents for temporary housing - especially under emergency conditions - a priority requisite, since, after given time lapses, areas occupied with emergency settlements will have to be recovered to their original use. In this case, the buildings' service life does not correspond to the life cycle of their materials and components; as a consequence, design activities will have to assure the dismantability and reusability of structures for further service cycles, making the whole process reversible: from construction to 'zero waste' de-construction. This paper aims at defining design criteria for low-impact emergency dwellings, assessing at the same time their applicability to corrugated steel pipes, obtained by assembling galvanized curved sheets - commonly used for underpasses and conduits - for which different use possibilities have been investigated. In this view, the research program has led to the definition of modular dwelling solutions. Then, technical feasibility studies have been carried out in collaboration with the industrial sector, taking advantage of consolidated production lines for innovative use purposes. Along the different research stages, a methodology has been defined for the assessment of the fundamental sustainability criteria through different simulation procedures; among these, the evaluation of the life-cycle environmental impacts with SimaPRO software and the 3D modelling for the maximization of the construction/environment integration - also in relation to the use of PV modules - have produced interesting results.

Landfill gas (LFG) tends to escape from the landfill surface even when LFG collecting systems are installed. Since LFG leaks are generally a noticeable percentage of the total production of LFG, the optimisation of the collection system is a fundamental step for both energy recovery and environmental impact mitigation. In this work, we suggest to take into account the results of direct measurements of gas fluxes at the air-cover interface to achieve this goal.During the last 5 years (2004-2009), 11 soil gas emission surveys have been carried out at the Municipal Solid Waste landfill of Legoli (Peccioli municipality, Pisa Province, Italy) by means of the accumulation chamber method. Direct and simultaneous measurements of CH(4) and CO(2) fluxes from the landfill cover (about 140,000 m(2)) have been performed to estimate the total output of both gases discharged into the atmosphere. Three different data processing have been applied and compared: Arithmetic mean of raw data (AMRD), sequential Gaussian conditional simulations (SGCS) and turning bands conditional simulations (TBCS). The total amount of LFG (captured and not captured) obtained from processing of direct measurements has been compared with the corresponding outcomes of three different numerical models (LandGEM, IPCC waste model and GasSim).Measured fluxes vary from undetectable values (<0.05 mol m(-2) day(-1) for CH(4) and <0.02 mol m(-2) day(-1) for CO(2)) to 246 mol m(-2) day(-1) for CH(4) and 275 mol m(-2) day(-1) for CO(2). The specific CH(4) and CO(2) fluxes (flux per surface unit) vary from 1.8 to 7.9 mol m(-2) day(-1) and from 2.4 to 7.8 mol m(-2) day(-1), respectively.The three different estimation methodologies (AMRD, SGCS and TBCS) used to evaluate the total output of diffused CO(2) and CH(4) fluxes from soil provide similar estimations, whereas there are some mismatches between these results and those of numerical LFG production models. Isoflux maps show a non-uniform spatial distribution, with high-flux zones not always corresponding with high-temperature areas shown by thermographic images.The average value estimated over the 5-year period for the Legoli landfill is 245 mol min(-1) for CH(4) and 379 mol min(-1) for CO(2), whereas the volume percentage of CH(4) in the total gas discharged into the atmosphere varies from 29% to 51%, with a mean value of 39%. The estimated yearly emissions from the landfill cover is about 1.29 x 10(8) mol annum(-1) (2,100 t year(-1)) of CH(4) and 1.99 x 10(8) mol annum(-1) (8,800 t year(-1)) of CO(2). Considering that the CH(4) global warming potential is 63 times greater than that of CO(2) (20 a time horizon, Lashof and Ahuja 1990), the emission of methane corresponds to 130,000 t annum(-1) of CO(2).The importance of these studies is to provide data for the worldwide inventory of CH(4) and CO(2) emissions from landfills, with the ultimate aim of determining the contribution of waste disposal to global warming. This kind of studies could be extended to other gas species, like the volatile organic compounds.

AbstractThe achievements of the last two decades in using solar energy for naturally ventilating and heating buildings of any size and scope across the world are remarkable, though comprising a niche market and being generally poorly known to this point. Air quality, thermal and hygrometric comfort, and reduced energy costs are some of the benefits provided by solar ventilated spaces. We identify the remaining hurdles to be addressed prior to forthcoming widespread adoption of this technology in the building environment across the world, well beyond the cold‐climate countries.

In themediumtolongterm,lowfossilfuelavailabilitywillmakeitnecessarytofindalternatives.Mass productionofbiofuelswillnotbeapracticalsolutionbecauseitrequiresstrongcompetitionforland that isusedforgrowingfood.Therefore,itwillbenecessarytorevisetheframeoftransportation energy sources.Thenumberofpurelight-andheavy-dutyelectricvehiclescouldincreaseinurban areas.Instead,itwillbehardtofindaviablealternativetotheinternalcombustionengineforextra- urban transportvehicles,thereforealternativesyntheticfuelscouldbeusedtocompensateforfossil fuel depletion.Asidefromasmallshareobtainablefrombiomass,mostsyntheticfuelsareexpectedto be obtainedfromcoal.Amongthese,syntheticnaturalgasrepresentsaverygoodsolution.Infact, syntheticnaturalgaswillbeadvantageouswithrespecttohydrogen,whoseon-boardstoragewillbean unsolvedprobleminthemediumterm,andwithrespecttosyntheticliquidfuels,whichrequiremore energy intheproductionphase.Moreover,thecarboncontentofliquidfuels,whichishigherthanthat of gaseousfuels,willberesponsibleforhigherCO2 emissionsfromvehicles.Currently,naturalgashas poor diffusioninthetransportsector,andthispaperhighlightsthemotivationsforfavouringapolicy aimedatincreasingtheshareofgaseousfuel-poweredvehicles.Inadditiontothelowenvironmental impact,syntheticnaturalgasalsooffersthepossibilityofoptimisingtheutilisationoffutureresources

A seawater spray scrubber was set up and tested with focus to desulfurization of marine engine exhaust gas. Experimental tests were carried out simulating typical exhaust conditions of a marine diesel engine burning heavy fuel oil and using real seawater. Different flue gas flow rates, seawater flow rates, and SO2 concentrations were tested. Liquid‐to‐gas ratios were in the range 1–10 × 10−3. A comparison between seawater and distilled water was also carried out to elucidate the effect of seawater alkalinity. In all conditions, the liquid phase was analyzed for alkalinity, pH, and sulfate content before and after the tests. Finally, the spray droplet size distribution was measured as a function of liquid flow rate.Experimental results indicated that seawater performed better than distilled water, by exploiting its inherent alkalinity. The desulfurization performance was improved by increasing the liquid flow rate and the gas residence time and by decreasing the SO2 concentration. SO2 capture efficiencies up to 93% were measured under the present operating conditions. The experimental data were further compared with calculations performed with an available model for SO2 absorption in fall‐down droplets within a simple plug‐flow reactor. Model calculations were carried out by using all parameters' values as measured in the present experimental campaign. Model results well fit the experimental data, even if a slight underestimation of the desulfurization efficiency is reported. The likely reasons are the assumed plug flow of gas as well as the neglected contribution to SO2 capture by water film falling at the wall. © 2012 American Institute of Chemical Engineers Environ Prog, 32: 1179–1186, 2013