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ABSTRACT The progression of the organic loading rate (OLR) up to a certain limit increases biogas production. The limit and operation range vary according to the configuration of the reactor and are associated with other variables that generate different results with respect to biogas yield (BY) and biogas productiveness (BP). The aim of this study was to investigate the effect of the OLR on the BY and BP from swine manure in continuous stirred tank reactors (CSTRs) and upflow anaerobic sludge blanket reactors (UASBs). In the assay with the CSTR, the best operational condition was at an OLR of 0.7 gVS add L−1 reactor d−1 and a hydraulic retention time (HRT) of 18 days. At this operational condition, 0.8 LN biogas gVS add−1 of BY and 0.6 LN biogas L−1 reactor d−1 of BP were obtained. In the assay with the UASB, the best operational condition was at an OLR of 2.2 gVS add L−1 reactor d−1 and an HRT of two days, and 0.7 LN biogas gvs add−1 of BY and 1.6 LN biogas L−1 reactor d−1 of BP were obtained. The results demonstrate the effects of OLR changes on the biogas production in the CSTR and UASB, avoiding the underutilization or overloading of such equipment and enabling collaboration in projects for power generation from biogas in swine farms.

{"references": ["UNSD Demographic Statistics, available at http://data.un.org", "The World Bank GDP data, available at https://data.worldbank.org/", "UNFCCC: Greenhouse Gas Inventory Data, available at https://unfccc.int/process/transparency-and-reporting/greenhouse-gas-data/what-is-greenhouse-gas-data"]} Dataset containing all greenhouse gas emissions data submitted by countries under climate change convention (including CRF data) as published by the UNFCCC secretariat at 2021-12-03. The dataset is also available via datalad. To obtain the dataset with datalad, see the instructions at https://github.com/mikapfl/unfccc_di_data .

This climate change impact data (future scenarios on temperature-induced GDP losses) and climate change mitigation cost data (REMIND model scenarios) is published under doi: 10.5281/zenodo.3541809 and used in this paper: Ueckerdt F, Frieler K, Lange S, Wenz L, Luderer G, Levermann A (2018) The economically optimal warming limit of the planet. Earth System Dynamics. https://doi.org/10.5194/esd-10-741-2019 Below the individual file contents are explained. For further questions feel free to write to Falko Ueckerdt (ueckerdt@pik-potsdam.de). Climate change impact data File 1: Data_rel-GDPpercapita-changes_withCC_per-country_all-RCP_all-SSP_4GCM.csv Content: Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, RCP (and a zero-emissions scenario), SSP and 4 GCMs (spanning a broad range of climate sensitivity). Negative (positive) values indicate losses (gains) due to climate change. For figure 1a of the paper, this data was aggregated for all countries. File 2: Data_rel-GDPpercapita-changes_withCC_per-country_all-SSP_4GCM_interpolated-for-REMIND-scenarios.csv Content: Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, SSP and 4 GCMs (spanning a broad range of climate sensitivity). The RCP (and a zero-emissions scenario) are interpolated to the temperature pathways of the ten REMIND model scenarios used for climate change mitigation costs. Hereby the set of scenarios for climate impacts and climate change mitigation are consistent and can be combined to total costs of climate change (for a broad range of mitigation action). File 3: Data_rel-GDPpercapita-changes_withCC_per-country_SSP2_12GCM_interpolated-for-REMIND-scenarios.csv Content: Same as file 2, but only for the SSP2 (chosen default scenario for the study) and for all 12 GCMs. Data of relative change in absolute GDP/CAP levels (compared to the baseline path of the respective SSP in the SSP database) for each country, SSP-2 and 12 GCMs (spanning a broad range of climate sensitivity). The RCP (and a zero-emissions scenario) are interpolated to the temperature pathways of the ten REMIND model scenarios used for climate change mitigation costs. Hereby the set of scenarios for climate impacts and climate change mitigation are consistent and can be combined to total costs of climate change (for a broad range of mitigation action). In addition, reference GDP and population data (without climate change) for each country until 2100 was downloaded from the SSP database, release Version 1.0 (March 2013, https://tntcat.iiasa.ac.at/SspDb/, last accessed 15Nov 2019). Climate change mitigation cost data The scenario design and runs used in this paper have first been conducted in [1] and later also used in [2]. File 4: REMIND_scenario_results_economic_data.csv File 5: REMIND_scenarios_climate_data.csv Content: A broad range of climate change mitigation scenarios of the REMIND model. File 4 contains the economic data of e.g. GDP and macro-economic consumption for each of the countries and world regions, as well as GHG emissions from various economic sectors. File 5 contains the global climate-related data, e.g. forcing, concentration, temperature. In the scenario description “FFrunxxx” (column 2), the code “xxx” specifies the scenario as follows. See [1] for a detailed discussion of the scenarios. The first dimension specifies the climate policy regime (delayed action, baseline scenarios): 1xx: climate action from 2010 5xx: climate action from 2015 2xx climate action from 2020 (used in this study) 3xx climate action from 2030 4x1 weak policy baseline (before Paris agreement) The second dimension specifies the technology portfolio and assumptions: x1x Full technology portfolio (used in this study) x2x noCCS: unavailability of CCS x3x lowEI: lower energy intensity, with final energy demand per economic output decreasing faster than historically observed x4x NucPO: phase out of investments into nuclear energy x5x Limited SW: penetration of solar and wind power limited x6x Limited Bio: reduced bioenergy potential p.a. (100 EJ compared to 300 EJ in all other cases) x6x noBECCS: unavailability of CCS in combination with bioenergy The third dimension specifies the climate change mitigation ambition level, i.e. the height of a global CO2 tax in 2020 (which increases with 5% p.a.). xx1 0$/tCO2 (baseline) xx2 10$/tCO2 xx3 30$/tCO2 xx4 50$/tCO2 xx5 100$/tCO2 xx6 200$/tCO2 xx7 500$/tCO2 xx8 40$/tCO2 xx9 20$/tCO2 xx0 5$/tCO2 For figure 1b of the paper, this data was aggregated for all countries and regions. Relative changes of GDP are calculated relative to the baseline (4x1 with zero carbon price). [1] Luderer, G., Pietzcker, R. C., Bertram, C., Kriegler, E., Meinshausen, M. and Edenhofer, O.: Economic mitigation challenges: how further delay closes the door for achieving climate targets, Environmental Research Letters, 8(3), 034033, doi:10.1088/1748-9326/8/3/034033, 2013a. [2] Rogelj, J., Luderer, G., Pietzcker, R. C., Kriegler, E., Schaeffer, M., Krey, V. and Riahi, K.: Energy system transformations for limiting end-of-century warming to below 1.5 °C, Nature Climate Change, 5(6), 519–527, doi:10.1038/nclimate2572, 2015.

Biodiesel, known as a mixture of fatty acid ethyl/methyl esters, is seen as an alternative, ecofriendly, biodegradable and renewable non-fossil fuel. The use of heterogeneous catalysts for biodiesel synthesis can solve several problems associated with the homogeneous alkaline catalyzed-transesterification. Therefore, this work reports the evaluation of the commercial resin Amberlyst A26OH, a strong anion exchange resin, as a heterogeneous catalyst for the batch transesterification of refined palm olein with ethanol. It was studied the effects of the main operational parameters, considering the molar ratio of the reaction mixture (MRRM), namely the molar ratio of ethanol to olein taking into account only the ethanol added to the reaction system, and the total molar ratio (TMR), in this case considering also the amount of ethanol carried by the resin after its pretreatment. It was determined an optimal range of operational conditions by response surface methodology, guaranteeing conversion to ethyl esters higher than 96% with a catalyst amount corresponding to a range from 10.4 to 11.4% of the oil quantity, a temperature within the range of 55 to 60 ºC and a MRRM within the range from 3.5:1 to 6.0:1.

Project: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets - These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6). CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ). The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. Summary: These data include the subset used by IPCC AR6 WGI authors of the datasets originally published in ESGF for 'CMIP6.ScenarioMIP.MIROC.MIROC6.ssp119' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'. The MIROC6 climate model, released in 2017, includes the following components: aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T85; 256 x 128 longitude/latitude; 81 levels; top level 0.004 hPa), land: MATSIRO6.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), seaIce: COCO4.9. The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, land: 250 km, ocean: 100 km, seaIce: 100 km.

These are two sets of data that I collected in 2018 and 2019 in Germany. They assess basic psychological need satisfaction, various indicators of pro-environmentalism, and self-protective strategies people commonly use when facing the threat of climate change. The corresponding study (Wullenkord, submitted) investigated relations between basic psychological need satisfaction and climate-relevant defensive self-protection.

Fluorescence spectroscopy via confocal laser scanning microscopy (CLSM) was used to analyze ancient sedimentary organic matter, including Tasmanites microfossils in Devonian shale and Gloecapsomorpha prisca (G. prisca) in Ordovician kukersite from North American basins. We examined fluorescence emission as a function of excitation laser wavelength, sample orientation, and with respect to location within individual organic entities and along organic matter chemical transects. Results from spectral scans of the same field of view in Tasmanites with different laser lines showed progressive red-shift in emission maxima with longer excitation wavelengths. This result indicates steady-state Tasmanites fluorescence emission is an overlapping combination of emission from multiple distinct fluorophore functions. Stokes shift decreased with increasing excitation wavelength, further suggesting the presence of multiple fluorophore functions with different S1 -> S0 transition energies. This observation also indicates that at longer excitation wavelengths, less absorbed light energy is dissipated via collisional transfer than at shorter excitation wavelengths and may suggest fewer polar functions are preferentially absorbing. Confirming earlier results, emission spectra observed from high fluorescence intensity regions (fold apices) in individual Tasmanites are blue-shifted relative to emission from other locations in the same microfossil. We suggest high intensity emission is from photoselective alignment of polarized excitation with the fluorophore absorption and emission transition moment. The blue shift observed in regions of high intensity emission may be due to relative absence of polar species, e.g., bridging ether or ester functions, although this could not be confirmed with preliminary time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis. Tasmanites occurring in consolidated sediments are flattened from original spherical morphology and, in optical microscopy, this burial deformation results in generally parallel extinction (strain-influenced) and positive elongation. The deformation also induces fluorescence anisotropy observed as variations in emission wavelength when samples are measured parallel to bedding, whereas this effect is absent in bedding-normal view. Evaluation of fluorescence emission on compositional transects from G. prisca-rich source layers into adjacent reservoir layers indicates decrease in fluorescence intensity and spectral red-shift (increase in full-width half-maximum with increasing red portion of the half-width). These results may suggest an increase in fluorescence quenching across the source-to-reservoir transition zone, consistent with an increase in aromaticity following petroleum expulsion and migration. These observations are supported by increasing reflectance values measured across similar micro-scale transects. Our results highlight the applicability of CLSM as a broad and under-utilized approach for the characterization of sedimentary organic matter and are discussed with perspective toward petroleum processes and thermal indices research.

Abstract Activated carbon is commonly used as a material for contaminant-adsorption processes in aqueous systems. However, its use is more restricted to charcoal than to coal, for the most part, in view of the fact of the higher cost (~ 40%) if the mineral is a fossil fuel which needs to be extracted from the earth by mining. For this reason, the peach stone that comes from alimentary industrial tailings can be a good choice for the separation of pollutants from aqueous suspensions and other soluble substances. The purpose of this research was the development of a low-cost filter, using stones to remove atrazine from water. Appraisal and characterization studies were performed along with batch experiments to investigate dosing effects of the activated carbon, atrazine concentration, contact time, and adsorption pH on removal procedures. From the results of the experiment, an excellent removal of the analyte in question was observed under conditions that can be considered as close as possible to the environment, such as pH = 6.5, room temperature and 10 minutes of agitation time, always choosing the best alternative with the lowest cost of energy and time. Batch system application has been recommended as versatile for utilization in seasonal problems such as pesticide contamination.