• Energy Research

The effect of the combined application of nano-hydroxyapatite (NHAP) or nano-carbon black (NCB) on the phytoextraction of Pb by ryegrass was investigated as an enhanced remediation technique for soils by field-scale experiment. After the addition of 0.2% NHAP or NCB to the soil, temporal variation of the uptake of Pb in aboveground parts and roots were observed. Ryegrass shoot concentrations of Pb were lower with nano-materials application than without nano-materials for the first month. However, the shoot concentrations of Pb were significantly increased with nano-materials application, in particular NHAP groups. The ryegrass root concentrations of Pb were lower with nano-materials application for the first month. These results indicated that nano-materials had significant effects on stabilization of lead, especially at the beginning of the experiment. Along with the experimental proceeding, phytotoxicity was alleviated after the incorporation of nano-materials. The ryegrass biomass was significantly higher with nano-materials application. Consequently, the Pb phytoextraction potential of ryegrass significantly increased with nano-materials application compared to the gounps without nano-materials application. The total removal rates of soil Pb were higher after combined application of NHAP than NCB. NHAP is more suitable than NCB for in-situ remediation of Pb-contaminated soils. The ryegrass translocation factor exhibited a marked increase with time. It was thought that the major role of NHP and NBA might be to alleviate the Pb phytotoxicity and increase biomass of plants.

AbstractElevated carbon-dioxide concentration [eCO2] is a key climate change factor affecting plant growth and yield. Conventionally, crop modeling work has evaluated the effect of climatic parameters on crop growth, without considering CO2. It is conjectured that a novel multimodal ensemble approach may improve the accuracy of modelled responses to eCO2. To demonstrate the applicability of a multimodel ensemble of crop models to simulation of eCO2, APSIM, CropSyst, DSSAT, EPIC and STICS were calibrated to observed data for crop phenology, biomass and yield. Significant variability in simulated biomass production was shown among the models particularly at dryland sites (44%) compared to the irrigated site (22%). Increased yield was observed for all models with the highest average yield at dryland site by EPIC (49%) and lowest under irrigated conditions (17%) by APSIM and CropSyst. For the ensemble, maximum yield was 45% for the dryland site and a minimum 22% at the irrigated site. We concluded from our study that process-based crop models have variability in the simulation of crop response to [eCO2] with greater difference under water-stressed conditions. We recommend the use of ensembles to improve accuracy in modeled responses to [eCO2].

A field experiment was conducted during 1993–1995 to study the effect of industrial effluent on the initial growth of Azadirachta indica A. Juss. (Neem) in arid region. The effluent released from textile industry had high pH, EC, SAR and RSC. Various treatments were: irrigation with effluent only (W1), effluent mixed with canal water at 1:1 ratio (W2), gypsum‐treated effluent (W3), gypsum‐treated soil (W4) and wood ash‐treated soil (W5). W5 was the best treatment where neem attained 218 cm height, 118 cm crown diameter and 11.2 cm collar circumference at 28 months of age; followed by W1 treatment, where trees were on an average 186 cm tall and had 104 cm crown diameter and 9.4 cm collar circumference. Growth of the seedlings was the poorest in W2treatment. Increase in biomass accumulation over W2 treatment (1.89 kg tree−1) was 3.6 fold in W5, 2.1 fold in W1, 2.0 fold in W4 and 1.4 fold in W3 treatments. Though effluent application increased soil organic matter, electrical conductivity and in some cases pH also, but gypsum‐ and wood ash‐ treated soil ameliorated the pH by 0.25 units in comparison to the initial data. These results suggest that industrial wastewater can be effectively used to boost up establishment and growth of Neem (Azadirachta indica) in arid zone. Addition of wood ash improves the rate of growth. Irrigation with industrial effluent caused slight increase in electrical conductivity and decline in the soil pH. Santrauka Eksperimentas vyko 1993–1995 m. siekiant ištirti pramoninių nuotekų poveikį Azadirachta indica A. Juss. (Neem) sodinukų augimo pradžiai sausringuose regionuose. Tekstilės pramonės išleidžiamų nuotekų didelės pH rodiklio reikšmės, elektrinis laidumas, natrio adsorbcijos santykis ir natrio karbonato liekana. Tiriant taikyti įvairūs dirvožemio apdorojimo būdai: drėkinta tik nuotekomis (W1 ), nuotekos maišytos su kanalo vandeniu santykiu 1:1 (W2 ), nuotekos veiktos gipsu (W3 ), į dirvožemį dėta gipso (W4 ) ir dirvožemis tręštas medienos pelenais (W5 ). Efektyviausias buvo W5 apdorojimo būdas. 28 mėnesių augalai siekė 218 cm aukštį, jų vainiko skersmuo buvo 118 cm, žiedo perimetras – 11,2 cm. Stebint W1 apdorojimo tipą, medžiai buvo vidutiniškai 186 cm aukščio, vainikas – 104 cm skersmens, žiedai 9,4 cm perimetro. Blogiausiai sodinukai augo apdorojant W2 būdu. Nors naudojant nuotekas dirvožemio organinių medžiagų kiekis, elektrinis savitasis laidumas ir kai kuriais atvejais pH reikšmė padidėjo, tačiau gipsu ir medienos pelenais apdorotame dirvožemyje pH padidėjo per 0,25 vienetus, palyginti su pirminiais duomenimis. Šie rezultatai rodo, kad pramoninės nuotekos gali būti efektyviai naudojamos Neem (Azadirachta indica) želdinti ir auginti sausose teritorijose. Medienos pelenai pagerino augimo spartą. Drėkinimas pramoninėmis nuotekomis lėmė nežymų elektrinio savitojo laidumo augimą ir dirvožemio pH sumažėjimą. Резюме Экспериментальное поле возделывалось в 1993–1995 гг. с целью изучить воздействие промышленных стоков на начало роста Azadirachta indica A. Juss. (Neem) в засушливых районах. В стоках от производства текстиля высоко значение pH, электропроводимость, соотношение адсорбции натрия и остаток карбоната натрия. Применялись разные способы обработки почвы: орошение только стоками (W1 ); смесью стоков с водой из канала в соотношении 1:1 (W2 ); стоками, обработанными гипсом (W3 ); обработка почвы гипсом (W4 ) и удобрение древесной золой (W5 ). Наиболее эффективным способом оказалась обработка древесной золой. Высота растений в возрасте 28 месяцев составляла 218 см, венчик в поперечнике – 118 см, цветок – 11,2 см. После обработки почвы по типу W1 растения достигали 186 см в высоту, венчик в поперечнике – 104 см, цветок – 9,4 см. Наименее эффективным для растений способом оказалась обработка почвы по типу W2 . Несмотря на то, что при применении стоков количество органических веществ в почве, электропроводимость и в некоторых случаях значение pH увеличилось, однако при обработке почвы гипсом и древесной золой pH увеличилось более чем на 0,25 единиц по сравнению с начальными данными. Эти результаты показали, что промышленные стоки могут эффективно применяться для озеленения и выращивания Neem (Azadirachta indica) на засушливых территориях. Древесная зола ускоряла рост растений. Орошение промышленными стоками способствовало незначительному увеличению электропроводимости и уменьшению в почве pH.

<p>Historical weather data represent an extremely precious resource for agro-meteorology for studying evolutionary dynamics and for predictive purposes, to address agronomical and management choices, that have economic, social and environmental effect. The study of climatic variability and its consequences starts from the observation of variations over time and the identification of the causes, on the basis of historical series of meteorological observations. The availability of long-lasting, complete and accurate datasets is a fundamental requirement to predict and react to climate variability. Inter-annual climate changes deeply affect grapevine productive cycle determining direct impact on the onset and duration of phenological stages and, ultimately, on the grape harvest and yield. Indeed, climate variables, such as air temperature and precipitation, affect evapotranspiration rates, plant water requirements, and also the vine physiology. In this respect, the observed increase in the number of warm days poses a threat to grape quality as it creates a situation of imbalance at maturity, with respect to sugar content, acidity and phenolic and aromatic ripeness.</p><p>A study was conducted to investigate the relationships between climate variables and harvest onset dates to assess the responses of grapevine under a global warming scenario. The study was carried out in the “Monferrato” area, a rainfed hillslope vine-growing area of NW Italy. In particular, the onset dates of harvest of different local wine grape varieties grown in the Vezzolano Experimental Farm (CNR-IMAMOTER) and in surrounding vineyards (affiliated to the Terre dei Santi Cellars) were recorded from 1962 to 2019 and then related to historical series of climate data by means of regression analysis. The linear regression was performed based on the averages of maximum and minimum daily temperatures and sum of precipitation (1962–2019) calculated for growing and ripening season, together with a bioclimatic heat index for vineyards, the Huglin index. The climate data were obtained from two data series collected in the Experimental farm by a mechanical weather station (1962-2002) and a second series recorded (2002-2019) by an electro-mechanical station included in Piedmont Regional Agro-meteorological Network. Finally, a third long-term continuous series covering the period from 1962 to 2019, provided by Italian Meteorological Society was considered in the analysis.</p><p>The results of the study highlighted that inter-annual climate variability, with a general positive trend of temperature, significantly affects the ripening of grapes with a progressive anticipation of the harvest onset dates. In particular, all the considered variables excepted precipitation, resulted negatively correlated with the harvest onset date reaching a high level of significance (up to P< 0.001). Best results have been obtained for maximum temperature and Huglin index, especially by using the most complete dataset. The change ratios obtained using datasets including last 15 years were greater (in absolute terms) than results limited to the period 1962-2002, and also correlations have greater level of significance. The results indicated clearly the relationships between the temperature trend and the gradual anticipation of harvest and the importance of having long and continuous historical weather data series available.</p>

Using data from Eurobarometer 83.4, this study combines the two branches of research that address climate-related and biodiversity-related opinions and actions of individuals in the EU. The literature shows that the differences between climate-related and biodiversity-related policies correspond, at an individual level, to a person's basic attitudes towards environmental protection and towards nature protection, respectively. The contribution of this study is to demonstrate how these attitudes can influence behavior that has environmental repercussions for both issues, such as food consumption practices. The analysis focused on two Eurobarometer questions about buying local and seasonal food (to fight climate change) and about buying organic and local food (to protect biodiversity and nature). The results of two multinomial regression analyses, separately in Northwestern European countries and Eastern and Southern European countries, demonstrated that climate-related and biodiversity-related attitudes were, independent of each other, related to the adoption of these purchase behaviors. The results may support Europe's new Farm to Fork (F2F) strategy and indicate that improving food consumption practices can enable individuals to better play their part in fighting climate change and biodiversity loss simultaneously, which opens up interesting new perspectives for policymakers, businesses and consumers.

Land use changes from cropland to orchards in Eastern China have raised serious concerns about the regional nitrogen (N) cycle and greenhouse gas balance. We measured soil nitrous oxide (N2O) emissions and methane (CH4) uptake using manual static chambers in an apple orchard. The primary aims were to assess the effect of N fertilizer application on gas fluxes and quantify the site-specific N2O emission factor (EFd). Field experiments were arranged in a randomized block design with three N input rates (0, 800 and 2600/2000 kg N ha−1 year−1). We found that orchard soils were a negligible CH4 sink (−1.1 to −0.4 kg C ha−1 year−1). Annual N2O emissions responded positively to N input rates, ranging from 34.1 to 60.3 kg N ha−1 year−1. EFd ranged from 1.00% to 1.65% with a mean of 1.34%. The extremely large background emissions of N2O (34.1–34.3 kg N ha−1 year−1) most likely originated from nitrate accumulation in the soil profile because of historical overuse of N fertilizer. We conclude that (1) site-specific EFd is suitable for assessing regional direct N2O emissions from upland orchards; and (2) conventional fertilization regimes must be avoided, and reduced N input rates are recommended in the study region.

Ni3Mo3C was prepared by a modified organic colloid method and explored as anode catalyst for high-performance microbial fuel cell (MFC) based on Klebsiella pneumoniae (K. pneumoniae). The prepared sample was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), and Brunauer-Emmett-Teller (BET). The activity of the sample as anode catalyst for MFC based on K. pneumoniae was investigated by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and polarization curve measurement. The results show that the adding of nickel in Mo2C increases the BET surface area of Mo2C and improves the electrocatalytic activity of Mo2C towards the oxidation of microbial fermentation products. The power density of MFC with 3 mg cm(-2) Ni3Mo3C anode is far higher than that of the MFC with carbon felt as anode without any catalyst, which is 19 % higher than that of Mo2C anode and produced 62 % as much as that of Pt anode, indicating that Ni3Mo3C is comparative to noble metal platinum as anode electrocatalyst for MFCs by increasing the loading.