Stalagmites and other carbonates deposited in caves provide a potentially powerful record of past climate. Stalagmites have a wider geographical dispersion than lakes or ice cores and provide an ideal terrestrial complement to marine sediment cores. Stalagmites have additional advantages in that they can be very accurately and precisely dated, and that they suffer no sedimentary mixing so can provide very high resolution geochemical records. These advantages have led to a burgeoning interest in reconstruction of climate from stalagmites in the last decade - a trend that looks set to continue. There is, however, a big problem with such stalagmite paleoclimate research. This is that we cannot yet reliably turn geochemical measurements in stalagmites into quantitative information about the past climate. In some locations, stable-isotope data provides qualitative information about change, but we desperately need to develop better understanding of these and other geochemical proxies so we can reliably use them to reconstruct the past. The work proposed here will provide understanding of stalagmite paleoclimate proxies through a series of laboratory experiments mimicking the cave environment in which stalagmites grow. We have built a laboratory apparatus that allows super-saturated waters with high CO2 contents to drop onto glass-plates in closely controlled conditions and to degas to form calcite in a manner identical to that seen in the cave environment. We have demonstrated the success of this apparatus and used it to assess the role of temperature and drip-rate in controlling stalagmite geochemistry. Here we propose to replicate these experiments, and to go beyond them to also understand the role of variables such as pCO2, solution saturation, and humidity in controlling stalagmite geochemistry. We will characterize the samples grown in this way both for their chemistry and for their crystallographic features, and apply some simple models to develop a significantly better understanding of trace-metal and stable isotopes incorporation into stalagmites, under conditions of both thermodynamic equilibrium and kinetic fractionation. This work will have direct implications for the interpretation of existing and new stalagmite records, with perhaps the clearest reward coming in the interpretation of high-resolution climate records. We will also apply some new geochemical tools which have seen little previous application to the cave environment. The clumping of minor isotopes within molecules (such as the carbonate ion) has been shown to be temperature dependant, providing a potentially powerful paleothermometer in caves, but one that is unfortunately complicated by kinetic effects. Our laboratory samples will help, via a collaboration with Yale University, to understand the uses and pitfalls of this clumped-isotope paleothermometer. We will also measure some relatively unexplored isotope systems such as Ca, Li, Sr, and Mg isotopes to assess their use as paleoproxies. Finally, we will assess, by adding microbes to our experiments, the possibility that life plays a role in the precipitation and chemistry of stalagmites. Such cave carbonates are normally thought to grow inorganically, but very recent culturing and sequencing work has uncovered a diverse microbial assemblage on stalagmite surfaces, with some species known to have a role in carbonate precipitation in other environments. We will include microbial strains found in the natural cave environment in our experiments to assess the importance of life for growth of cave carbonates. In total, the outcome of these laboratory experiments will be a much improved understanding of the geochemistry of stalagmites, significantly advancing their usefulness as archives of past climate, and therefore providing new insights into the magnitude, timing, and processes of climate change on the continents.

SIEUSOIL will design, implement and test a shared China-EU Web Observatory platform that will provide Open Linked Data to monitor status and threats of soil and assist in decision making for sustainable support of agro-ecosystem functions, in view of the projected climate change. The Observatory platform will through customizable modules support the wise management of soil at field level and will provide showcase of good practices on soil management both for EU and China. The final target will be to support sustainable management of soil, increase land productivity sustainably, reduce crop yield variability across time and space, and support the policy formulation process. Innovative practices and tools will be tested in SIEUSOIL and their impact will be assessed for improved soil fertility and land suitability.

The Permo-Triassic mass extinction (PTME; c. 252 Ma) was the most catastrophic biotic event of the Phanerozoic with up to 96% of marine animals going extinct. This event was triggered by massive volcanic eruptions which led to a series of environmental cascades in the oceans, such as rapid and extreme greenhouse warming, ocean anoxia and ocean acidification. The PTME had long lasting effects on the evolution of life with current opinions stating that marine ecosystem recovery took anywhere between 5 to 50 million years. It has also been hypothesised that the PTME caused a permanent ecological regime shift in the world's oceans, marking the end of Palaeozoic benthic ecosystems largely made up of sessile suspension feeders and catalysing the "Mesozoic Marine Revolution", a predator-prey arms race which led to increasing levels of ecological complexity. However, previous attempts to quantify the speed and nature of the recovery interval from the PTME have relied upon indirect measures of ecosystem structure and complexity such as compilations of taxonomic vs functional diversity, qualitative interpretations of ecosystem recovery, and attempts at quantifying changes in life habit and evidence of predation intensity through time. However, to thoroughly test such hypotheses, analyses need to be conducted within a whole ecosystem framework which make use of community ecology methods in order to model ecosystem structural changes via trophic networks (i.e. food webs) through the recovery interval and beyond. This project will explore a novel approach to pushing the frontiers of palaeobiological research via interdisciplinary methods combining recent advances in ecological modelling with palaeontology. Specifically, we will test how marine ecosystems recovered from the PTME and whether this biotic crisis truly represented the beginning of the origins of modern marine ecosystem structure. We will use the rich marine fossil record from South China to model community structure across the PTME and long recovery interval through the Triassic whilst accounting for preservation bias in the fossil record. We will then use the Paleo Foodweb Inference Model to build food webs from ecological traits easily identifiable from the fossil record and then track community structure and function across the PTME and into the recovery interval in the Triassic. This analysis will provide the most precise analysis of how the largest mass extinction in Earth history altered marine ecosystem structure and whether this event heralded the onset of the Mesozoic Marine Revolution and the origins of modern marine ecosystem structure.

The rare earth elements (REE), and in particular neodymium and dysprosium, are essential for renewable energy devices such as wind turbines and the development of electric motors for transport. At present the REE are sourced from either low concentration weathered granitoid (ion adsorption clay) deposits, or from high concentration carbonatite-related deposits, especially the World's dominant REE mine in hard-rock, altered carbonatite at Bayan Obo, China. The one major mine operator outside of China is the Mount Weld weathered carbonatite, Australia. Weathered carbonatites such as Mount Weld are some of the world's richest REE deposits and several are subject to active exploration. As part of the NERC Global Partnerships Seedcorn fund project WREED, we have carried out preliminary investigations of weathering products on carbonatite hosted REE deposits. Three end member weathering products have been identified (1) carbonate mineral dissolution leaves behind primary REE minerals, forming residual deposits; (2) dissolution and reprecipitation of REE phosphates and fluorcarbonate minerals results in the formation of new hydrated REE-phosphate or -carbonate minerals producing supergene enrichment; and (3) the formation of clay and iron-manganese oxide caps (either from weathering of the deposit itself, or from soil transport from surrounding rocks) that may hold the REE adsorbed to mineral surfaces (c.f. the ion adsorption deposits). High grade, weathered carbonatite deposits typically consist of a range of soil and weathered horizons, that may be phosphate-rich due to dissolution and re-precipitation of apatite and monazite during the weathering process (Mount Weld, Australia), overlain by later sediments that may be REE enriched either by accumulation of residual minerals in lake sediments (Tomtor, Russia). The mineralogy of the ore zone is linked to, but distinct from, the unweathered carbonatite rock, and includes phosphates, crandallite-group minerals, carbonates and fluorcarbonates and oxides. In this study we will utilise bulk rock geochemistry, sequential leaching techniques, mineral chemistry and microbiology to investigate the processes producing different weathered REE deposit styles in carbonatites and their influence on the economic REE grade and environmental impact of deposits. Bulk rock geochemistry will be used to quantify element enrichments and depletions relative to bedrock, and to investigate the potential for ion adsorption style mineralisation in weathered carbonatites. Mineral chemical techniques will be used to investigate the timing of weathering, host minerals of the REE, potential beneficial or harmful changes in chemistry relative to primary minerals, and proxies for the environmental controls on weathering style. These data will be combined with existing records of surface morphology and weathering depth to produce overall genetic models linking climate, geomorphology and geochemistry that will allow prediction of the resource potential of the carbonatite weathered zone. The results will be communicated with industry and the public to raise awareness of the resource requirements of decarbonisation, and potential routes to increased extraction efficiency and reduced impact.

We propose a large-scale, multi-faceted, international programme of research on the functioning of the Earth system at a key juncture in its history - the Early Jurassic. At that time the planet was subject to distinctive tectonic, magmatic, and solar system orbital forcing, and fundamental aspects of the modern biosphere were becoming established in the aftermath of the end-Permian and end-Triassic mass extinctions. Breakup of the supercontinent Pangaea was accompanied by creation of seaways, emplacement of large igneous provinces, and occurrence of biogeochemical disturbances, including the largest magnitude perturbation of the carbon-cycle in the last 200 Myr, at the same time as oceans became oxygen deficient. Continued environmental perturbation played a role in the recovery from the end-Triassic mass extinction, in the rise of modern phytoplankton, in preventing recovery of the pre-existing marine fauna, and in catalysing a 'Mesozoic Marine Revolution'. However, existing knowledge is based on scattered and discontinuous stratigraphic datasets, meaning that correlation errors (i.e. mismatch between datasets from different locations) confound attempts to infer temporal trends and causal relationships, leaving us without a quantitative process-based understanding of Early Jurassic Earth system dynamics. This proposal aims to address this fundamental gap in knowledge via a combined observational and modelling approach, based on a stratigraphic 'master record' accurately pinned to a robust geological timescale, integrated with an accurate palaeoclimatic, palaeoceanographic and biogeochemical modelling framework. The project has already received $1.5M from the International Continental Drilling Programme towards drilling a deep borehole at Mochras, West Wales, to recover a new 1.3-km-long core, representing an exceptionally expanded and complete 27 My sedimentary archive of Early Jurassic Earth history. This core will allow investigation of the Earth system at a scale and resolution hitherto only attempted for the last 65 million years (i.e. archive sedimentation rate = 5 cm/ky or 20 y/mm). We will use the new record together with existing data and an integrative modelling approach to produce a step-change in understanding of Jurassic time scale and Earth system dynamics. In addition to order of magnitude improvements in timescale precision, we will: distinguish astronomically forced from non-astronomically forced changes in the palaeoenvironment; use coupled atmosphere-ocean general circulation models to understand controls on the climate system and ocean circulation regime; understand the history of relationships between astronomically forced cyclic variation in environmental parameters at timescales ranging from 20 kyr to 8 Myr, and link to specific aspects of forcing relating to solar energy received; use estimated rates and timing of environmental change to test postulated forcing mechanisms, especially from known geological events; constrain the sequence of triggers and feedbacks that control the initiation, evolution, and recovery from the carbon cycle perturbation events, and; use Earth system models to test hypotheses for the origins 'icehouse' conditions. Thirty six project partners from 13 countries substantially augment and extend the UK-based research.