Significant reduction of greenhouse gas emissions (GHG) has become the utmost endeavour to achieve net-zero emissions by 2050. In the UK, domestic heating itself is responsible for 17% of the total GHG emissions, this is comparable to the contribution of all petrol and diesel cars (BEIS, January 2022). Therefore, the decarbonization of domestic heat is a big challenge. A sustainable route to reduce GHG is to replace natural gas (NG) with hydrogen (H2) since the combustion of H2 does not produce CO2. However, the challenge for H2 combustion is that its combustion characteristics substantially differ from NG (methane, CH4), e.g., its use affects combustion stability, heat release and NOx emission, and increases the combustion rate due to a higher H2 flame temperature. Various technological challenges are also associated with using pure H2 such as its production, safety, quick charge capability and low density, which limits its storage capabilities. At this transitional stage, a practical option is the use of higher H2 enriched fuel (i.e., more than 20% blend with NG), which would be a promising solution to lower the CO2 emission compared with other fossil fuels. However, the impacts of higher H2 enriched fuels on the widely used condensing heating boilers are not extensively studied and fully understood. The H2 enrichment leads to higher flame radicals such as OH*, CN*, CH* and C2*, higher combustion temperature and flame destabilisation, thus triggering higher NOx formation. The flame radicals are closely related to the combustion structure, temperature, heat release and pollution emissions. Moreover, domestic condensing boilers use premixed cylindrical/surface burners, and these burners produce an array of flames. It is extremely difficult to measure flame radical information in different depths of the array of flames using existing measurement systems. The development of an intelligent instrumentation system has, therefore, become indispensable to assess and monitor the flame radical emissions and NOx formation process at different depths of flames, thus facilitating an in-depth understanding of the combustion process of different H2/CH4 blends. This project will develop and implement a new instrumentation system based on multi-spectral light field imaging to assess and monitor the flame radicals and temperatures with different H2/CH4 blends in domestic boilers. Light field image formation and depth reconstruction models will be developed to generate flame radical images at different depths for different spectral bands. The developed system will provide distinctive capabilities for characterising and quantifying the radical information and temperature profiles of a flame in a single exposure, simultaneously. The proposed project will also develop an intelligent data-driven model based on machine learning to predict NOx emission, thus, facilitating the improvement of domestic boiler performance. The relationships between flame radical characteristics and NOx emission will be established by conducting a series of experiments initially on a lab-scale test rig and then on commercial domestic boilers under different H2/CH4 blends and boiler settings. The prototype system will also be tested on a gas turbine test rig to evaluate its wider applicability. Experiments will be conducted to investigate the characteristics of CO2, H2 and ammonia (NH3) blend combustion, thus providing an in-depth understanding of stability regions and NOx emission with different proportions of CO2/H2/NH3 in the blend. The outcomes of this research will provide in-depth knowledge of the combustion characteristics of H2 blends, understanding of the boiler efficiency and pollutant formation process of domestic boilers. Once the system is developed, it will be used for the design of domestic boilers, and the engineering insights produced during the project could be used to develop a portable diagnostic tool for routine monitoring of blended-fuel boilers.

The motivation for this proposal is that the global reliance on fossil fuels is set to increase with the rapid growth of Asian economies and major discoveries of shale gas in developed nations. The strategic vision of the IDC is to develop a world-leading Centre for Industrial Doctoral Training focussed on delivering research leaders and next-generation innovators with broad economic, societal and contextual awareness, having strong technical skills and capable of operating in multi-disciplinary teams covering a range of knowledge transfer, deployment and policy roles. They will be able to analyse the overall economic context of projects and be aware of their social and ethical implications. These skills will enable them to contribute to stimulating UK-based industry to develop next-generation technologies to reduce greenhouse gas emissions from fossil fuels and ultimately improve the UK's position globally through increased jobs and exports. The Centre will involve over 50 recognised academics in carbon capture & storage (CCS) and cleaner fossil energy to provide comprehensive supervisory capacity across the theme for 70 doctoral students. It will provide an innovative training programme co-created in collaboration with our industrial partners to meet their advanced skills needs. The industrial letters of support demonstrate a strong need for the proposed Centre in terms of research to be conducted and PhDs that will be produced, with 10 new companies willing to join the proposed Centre including EDF Energy, Siemens, BOC Linde and Caterpillar, together with software companies, such as ANSYS, involved with power plant and CCS simulation. We maintain strong support from our current partners that include Doosan Babcock, Alstom Power, Air Products, the Energy Technologies Institute (ETI), Tata Steel, SSE, RWE npower, Johnson Matthey, E.ON, CPL Industries, Clean Coal Ltd and Innospec, together with the Biomass & Fossil Fuels Research Alliance (BF2RA), a grouping of companies across the power sector. Further, we have engaged SMEs, including CMCL Innovation, 2Co Energy, PSE and C-Capture, that have recently received Department of Energy and Climate Change (DECC)/Technology Strategy Board (TSB)/ETI/EC support for CCS projects. The active involvement companies have in the research projects, make an IDC the most effective form of CDT to directly contribute to the UK maintaining a strong R&D base across the fossil energy power and allied sectors and to meet the aims of the DECC CCS Roadmap in enabling industry to define projects fitting their R&D priorities. The major technical challenges over the next 10-20 years identified by our industrial partners are: (i) implementing new, more flexible and efficient fossil fuel power plant to meet peak demand as recognised by electricity market reform incentives in the Energy Bill, with efficiency improvements involving materials challenges and maximising biomass use in coal-fired plant; (ii) deploying CCS at commercial scale for near-zero emission power plant and developing cost reduction technologies which involves improving first-generation solvent-based capture processes, developing next-generation capture processes, and understanding the impact of impurities on CO2 transport and storage; (iimaximising the potential of unconventional gas, including shale gas, 'tight' gas and syngas produced from underground coal gasification; and (iii) developing technologies for vastly reduced CO2 emissions in other industrial sectors: iron and steel making, cement, refineries, domestic fuels and small-scale diesel power generatort and These challenges match closely those defined in EPSRC's Priority Area of 'CCS and cleaner fossil energy'. Further, they cover biomass firing in conventional plant defined in the Bioenergy Priority Area, where specific issues concern erosion, corrosion, slagging, fouling and overall supply chain economics.

Our infrastructure is central to the economic prosperity of the nation and to the flourishing of a stable, yet dynamic, civil society. Its interconnected strands - the energy, transportation, water, sanitation and communication networks that provide access to services and markets and which underpin the securities of daily life - must be not only affordable and reliable but also resilient against threats such as technological uncertainty, environmental causes, economic and political change, and demographic and societal change unfolding in an increasingly uncertain world. FIBE2 CDT will lead a paradigm shift in the approach to infrastructure resilience through the creation of an inspirational doctoral training programme for talented cohorts from diverse academic and social backgrounds to conduct world-class, cutting-edge and industry-relevant research. Our goal is to develop the infrastructure professionals of the future, equipped with a versatile and cross-disciplinary skillset to meet the most complex emerging challenges, harness the full value of existing infrastructure and contribute effectively to better infrastructure decision-making in the UK. The programme's technical focus will exploit high-level interconnected research themes in advanced infrastructure materials, rethinking design & construction, digitised civil engineering, whole-life performance, built environment and global challenges, along high-level crosscutting themes in emerging technologies, performance to data to knowledge, research across scales, and risk and uncertainty. In FIBE2 CDT we offer a radical rethink to deliver innovation for the cross-disciplinary and interconnected challenges in resilient infrastructure. Our 1+3 MRes/PhD programme proposes a new approach to infrastructure research where students from different disciplines proactively forge new training and research collaborations. FIBE2 is inspired by the paradigm of a 3D 'T' shaped engineer embodying a combination of depth and breadth of knowledge, augmented by our new thinking around cross-disciplinary training and research. High level Infrastructure Engineering concepts will be interlinked and related to the detailed technical fundamentals that underpin them in bespoke core and elective modules. Cohort-based learning will bridge across the wider environmental, societal, economic, business and policy issues within the even broader context of ethics, responsible innovation and ED&I. These depth and breadth elements are interwoven and brought together through problem-based challenges using large-scale cross-disciplinary infrastructure projects. Individual student plans will be carefully crafted to harmonise the specificity of PhD research with the need for expansive understanding of threats and opportunities. The development of Resilient FIBE2 CDT students with strong personal, technical and professional resilience attributes is integral to the FIBE2 approach to training and research. The FIBE2 PhD projects will build upon Cambridge's internationally leading research, investment and funding in the diverse areas related to infrastructure and resilience. Our major strategic initiatives include >£60M funding from EPSRC and industry. Our engagements in UKCRIC, CDBB, Alan Turing and Henry Royce Institutes and our world class graduate training programmes provide an inspirational environment for the proposed CDT. The FIBE2 vision has been co-created with our 27 strategic industry partners from across all infrastructure sectors and nine international academic centre partners across the world, who have pledged over £12M. We will work together to deliver the FIBE2 CDT objectives and add new dimensions to our students' experience. The lasting impact of FIBE2 will be embodied in our students acting as role models to inspire future generations of infrastructure engineers and rising to lead the profession through all the technological and societal challenges facing UK infrastructure.

EPSRC Centre for Doctoral Training in Resilient Decarbonised Fuel Energy Systems Led by the University of Nottingham, with Sheffield and Cardiff SUMMARY This Centre is designed to support the UK energy sector at a time of fundamental change. The UK needs a knowledgeable but flexible workforce to deliver against this uncertain future. Our vision is to develop a world-leading CDT, delivering research leaders with broad economic, societal and contextual awareness, having excellent technical skills and capable of operating in multi-disciplinary teams covering a range of roles. The Centre builds on a heritage of two successful predecessor CDTs but adds significant new capabilities to meet research needs which are now fundamentally different. Over 80% of our graduates to date have entered high-quality jobs in energy-related industry or academe, showing a demand for the highly trained yet flexible graduates we produce. National Need for a Centre The need for a Centre is demonstrated by both industry pull and by government strategic thinking. More than forty industrial and government organisations have been consulted in the shaping and preparation of this proposal. The bid is strongly aligned with EPSRC's Priority Area 5 (Energy Resilience through Security, Integration, Demand Management and Decarbonisation) and government policy. Working with our partners, we have identified the following priority research themes. They have a unifying vision of re-purposing and re-using existing energy infrastructure to deliver rapid and cost-effective decarbonisation. 1. Allowing the re-use and development of existing processes to generate energy and co-products from low-carbon biomass and waste fuels, and to maximise the social, environmental and economic benefits for the UK from this transition 2. Decreasing CO2 emissions from industrial processes by implementation of CCUS, integrating with heat networks where appropriate. 3. Assessing options for the decarbonisation of natural gas users (as fuel or feedstock) in the power generation, industry and domestic heating system through a combination of hydrogen enhancement and/or CO2 capture. Also critical in this theme is the development of technologies that enable the sustainable supply of carbon-lean H2 and the adoption of H2 or H2 enriched fuel/feedstock in various applications. 4. Automating existing electricity, gas and other vector infrastructure (including existing and new methods of energy storage) based on advanced control technologies, data-mining and development of novel instrumentation, ensuring a smarter, more flexible energy system at lower cost. Training Our current Centre operates a training programme branded 'exemplary' by our external examiner and our intention is to use this as solid basis for further improvements which will include a new technical core module, a module on risk management and enhanced training in inclusivity and responsible research. Equality, Diversity and Inclusion Our current statistics on gender balance and disability are better than the EPSRC mean. We will seek to further improve this record. We are also keen to demonstrate ED&I within the Centre staff and our team also reflects a diversity in gender, ethnicity and experience. Management and Governance Our PI has joined us after a career conducting and managing energy research for a major energy company and led development of technologies from benchtop to full-scale implementation. He sharpens our industrial focus and enhances an already excellent team with a track record of research delivery. One Co-I chairs the UoN Ethics Committee, ensuring that Responsible Innovation remains a priority. Value for Money Because most of the Centre infrastructure and organisation is already in place, start-up costs for the new centre will be minimal giving the benefit of giving a new, highly refreshed technical capability but with a very low organisational on-cost.