cQD are attracting significant interest as the key components for next-generation smart displays/lightings, photo detectors and image sensors, and solar cells. This is because they show excellent and unique physical properties such as i) high sensitivity and quantum efficiency, ii) excellent colour gamut with narrow emission (absorption) bandwidths, iii) colour tunability/band gap engineering through size control, iv) high photostability and v) high air stability as they are based on inorganic materials. Therefore, since the latest results on cQD LEDs and image sensors/photodetector have demonstrated the possibility of integration of cQD optoelectronics with current semiconducting technologies, the pace of research in the cQD area has been accelerated dramatically and an increasing number of research groups and companies are currently active in this area worldwide. The investigators expect that cQD LED will replace current technologies through: (1) Superior reliability of the inorganic structure in an almost air barrier free architecture w.r.t OLED (WVTR of 10-6 g/m2/day), (2) Lower power consumption and low product cost, 60 and 50 % less than current OLED, respectively, and (3) Colour purity of 110% or greater compared to typically 80% for OLED. This project will address will enhance the current state of the art to achieve cost reduction through using continuous, as opposed batch, cQD synthesis, mono layer resin free processing, all inorganic interface materials such as ETL (electron transport layer) and HTL (hole transport layer), device integration and packaging for EL cQD LED, with Cd-free cQDs for smart lighting and displays. The project proposed builds upon research established in the investigators' groups in Cambridge and Oxford. We are well equipped with facilities for pilot fabrication using technologies which will underpin the commercialisation of cQD LED based lighting/displays. The final deliverable will be energy efficient 4" active devices with predictable life times, and sustainable high brightness for flexible smart lighting. The elements of the smart light which will include colour hue and brightness control based on active matrix switching of pixels will also be applicable to displays, but without the same high pixel definition. We shall explore the design and synthesis of Cd-free cQDs with the core/shell structures using continuous flow production methods which can then be incorporated into active devices. Key to successfully implementing devices are the scalable production of high quality cQDs with specific surface passivation and functionalisation which limit the effects of impurities and defects and produce high quality thin films with well understood interfaces. In this project we will use scalable production techniques that can be transferred to in-line process for mass production. We shall focus on the manufacturing and processing aspects to create mono layer-controlled cQD films with entire close-packed and almost void free structure using dry-transfer printing methods. This will enhance efficiency and reliability of film for the desired mode of devices. Interface control based on a monolayer level layer-by-layer transfer process will be employed in order to obtain highly uniform monolayers which can be expanded to multilayer stacked film processing including interface layers. The interface materials for emissive cQD film with inorganic HTL and ETL layer for EL devices will also be designed and fabricated at the device integration step (WP 2-3). Driving electronics using TFTs will be designed for reliable and stable operation. Industrial partners in the supply chain for smart flexible lighting production, are: CDT Ltd for materials, lighting, metrology; CPI Ltd, Dupont-Teijin Films UK for flexible films for lighting; Emberion UK, Dyson, FlexEnable, Samsung UK for device processing, and system integration; Aixtron UK for TCF; Nanoco and Merck as materials suppliers and EAB members.

Graphene is ideal for opto-electronics due to its high carrier mobility at room temperature, electrically tuneable optical conductivity, and wavelength independent absorption. Graphene has opened a floodgate for many layered materials (LMs). For a given LM, the range of properties and applications can be tuned by varying the number of layers and their relative orientation. LM heterostructures (LMHs) with tailored properties can be created by stacking different layers. The number of bulk materials that can be exfoliated runs in the thousands, but few have been studied to date. The layered materials research foundry (LMRF) will develop a fully integrated LM-Silicon Photonics platform, serving 5G, 6G and quantum communications, facilitating new design concepts that unlock new performance levels. Graphene and the other non-graphene LMs are at two different stages of development. Graphene is more mature, and can now target functionalities beyond the state of the art in technologically relevant devices. In (opto-)electronics, photonics and sensors, graphene-based systems have already demonstrated extraordinary performance, with reduced power consumption, or photodetectors (PDs) with hyperspectral range for applications such as autonomous driving, where fast data exchange is a critical requisite for safe operation. Applications in light detection and ranging, security, ultrasensitive physical and chemical sensors for industrial, environmental and medical technologies are beginning to emerge and offer great promise. These technologies must be developed to achieve full industrial impact. The other non-graphene LMs are also at the centre of an ever increasing research effort as a new platform for quantum technology. They have already shown their potential, ranging from scalable components, such as quantum light sources, photon detectors and nanoscale sensors, to enabling new materials discovery within the broader field of quantum simulations. The challenge is understanding and tailoring the excitonic properties and the nature of the single photon emission process, as well as to make working integrated devices. Quantum emitters in LMs hold potential in terms of scalability, miniaturisation, integration with other systems and an extra quantum degree of freedom: the valley pseudospin. A major challenge is to go beyond lab demonstrators and show that LMs can achieve technological potential. The LMRF will accelerate this by enabling users to fabricate their devices in a scalable manner, with comparable technology to large-scale manufacturing foundries. This scalability is essential for LMs to become a disruptive technology. The vision is to combine the best of Silicon Photonics with LM-based optoelectronics, addressing key drawbacks of current platforms. ICT systems are the fastest growing consumers of electricity worldwide. Due to limitations set by current CMOS technology, energy efficiency reaches fundamental limits. LM-based optoelectronics builds on the optical/electronic integration ability of Silicon Photonics, which benefits product costs, but with modulator designs simpler than conventional Silicon Photonics at high data rates, giving lower power consumption.

Topic of Centre: This i4Nano CDT will accelerate the discovery cycle of functional nanotechnologies and materials, effectively bridging from ground-breaking fundamental science toward industrial device integration, and to drive technological innovation via an interdisciplinary approach. A key overarching theme is understanding and control of the nano-interfaces connecting complex architectures, which is essential for going beyond simple model systems and key to major advances in emerging scientific grand challenges across vital areas of Energy, Health, Manufacturing (particularly considering sustainability), ICT/Internet of things, and Quantum. We focus on the science of nano-interfaces across multiple time scales and material systems (organic-inorganic, bio-nonbio interfaces, gas-liquid-solid, crystalline-amorphous), to control nano-interfaces in a scalable manner across different size scales, and to integrate them into functional systems using engineering approaches, combining interfaces, integration, innovation, and interdisciplinarity (hence 'i4Nano'). The vast range of knowledge, tools and techniques necessary for this underpins the requirement for high-quality broad-based PhD training that effectively links scientific depth and application breadth. National Need: Most breakthrough nanoscience as well as successful translation to innovative technology relies on scientists bridging boundaries between disciplines, but this is hindered by the constrained subject focus of undergraduate courses across the UK. Our recent industry-academia nano-roadmapping event attended by numerous industrial partners strongly emphasised the need for broadly-trained interdisciplinary nanoscience acolytes who are highly valuable across their businesses, acting as transformers and integrators of new knowledge, crucial for the UK. They consistently emphasise there is a clear national need to produce this cadre of interdisciplinary nanoscientists to maintain the UK's international academic leadership, to feed entrepreneurial activity, and to capitalise industrially in the UK by driving innovations in health, energy, ICT and Quantum Technologies. Training Approach: The vision of this i4Nano CDT is to deliver bespoke training in key areas of nano to translate exploratory nanoscience into impactful technologies, and stimulate new interactions that support this vision. We have already demonstrated an ability to attract world-class postgraduates and build high-calibre cohorts of independent young Nano scientists through a distinctive PhD nursery in our current CDT, with cohorts co-housed and jointly mentored in the initial year of intense interdisciplinary training through formal courses, practicals and project work. This programme encourages young researchers to move outside their core disciplines, and is crucial for them to go beyond fragmented graduate training normally experienced. Interactions between cohorts from different years and different CDTs, as well as interactions with >200 other PhD researchers across Cambridge, widens their horizons, making them suited to breaking disciplinary barriers and building an integrated approach to research. The 1st year of this CDT course provides high-quality advanced-level training prior to final selection of preferred PhD research projects. Student progression will depend on passing examinable components assessed both by exams and coursework, providing a formal MRes qualification. Components of the first year training include lectures and practicals on key scientific topics, mini/midi projects, science communication and innovation/scale-up training, and also training for understanding societal and ethical dimensions of Nanoscience. Activities in the later years include conferences, pilot projects, further innovation and scale up training, leadership and team-building weekends, and ED&I and Responsible Innovation workshops