The main objective of the project is development of complex transition metal oxides with perovskite-like structure having improved and controllable (multi)ferroic properties. The mentioned materials are manganites and ferrites with optimal composition having distinct magnetization, polarization, (magneto)transport properties or magnetoelectric coupling. The idea of the project is to utilize reduced structural stability of these oxides which increases their sensitivity to external stimuli. Improved functional properties of these oxides can be controlled via modification of the chemical bond character, structural parameters, stoichiometry, defects etc. The reduced stability is associated with the metastable structural state formed in the vicinity of the phase boundaries, while this state presumably consists of coexistent nanoscale regions of the adjacent structural phases. There are two ideas to create metastable state: the first one – to design ceramics via chemical substitution and post-synthesis treatment by high pressure and/or thermal cycling in gases to induce nanoscale regions, the second one assumes chemical routes synthesis of films and ceramics. Besides the fundamental interest of the phase transitions and related phenomena affecting properties of the oxides the applicants consider them to be effective materials for electronic applications (as sensors, magnetic memory elements, filters etc.). Research of these oxides requires consolidative efforts of specialists in different scientific areas - Materials Science, Theoretical Physics, Solid State Physics etc. as well as an access to unique equipment and facilities. Another important objective of the project is a formation of interdisciplinary network of teams and specialists with different scientific backgrounds which will ensure effective transfer of actual knowledge and skills. Development of the transition metal oxides with controllable properties has promising commercial opportunities for the involved SME.

The main objective of the proposal is the development of multi-purpose, multi-functional surfaces via environmentally friendly plasma electrolytic oxidation (PEO) treatments. In an intelligent way the weakness of the PEO process (the inherent porosity due to the discharges forming the coating is often responsible for poor properties) is used to functionalize the coating using the open pore structure as a reservoir for nanocontainer or to bring particles with certain functionalities deep into the coatings (fast pathways). The main targeted functionalities, are enhanced fault tolerance and active protection against corrosive damage as well as improved tribological behavior. Moreover, to extend this typical field of applications of PEO treatments and address additional industries and aspects (e.g. 3C, ecological), a set of less common functionalities, such as photocatalytic, magnetic, thermo- and electroconductivity will be added. This is challenging and goes far beyond the state-of-the-art introduction via post-treatments. To deal with such sensitive materials, changes in the power supply are required and this is addressed as one of the key points in frame of the project as well. The essential key of the project is the formation and development of an interdisciplinary R&D partnership, where participants from both academia (5) and private sector (4 SME) participate, promoting and sharing their ideas, expertise, techniques and methods to solve this demanding challenge. This partnership will be beneficial for all participants, since new PEO hardware, environmentally friendly processes and applications important for industry are developed, evaluated and promoted by the research institutions via presentations and publications of the obtained results. Laboratory based training and intersectional transfer of knowledge are the key aspects of the FUNCOAT project, so the partnership gathers the topmost competences to carry out the suggested research program.