In the 20th century, the development of silicon-based electronics revolutionised the world, becoming the most pervasive technology behind modern-day life. In the 21st century, it is envisaged that technology will move to the use of light (photons) together with, or in place of, electrons, providing a dramatic increase in the speed and quantity of information processing whilst also reducing the energy required to do so. Making this transition to an all optical 'photonic' technology has proved to be a complex task, as the material of choice for electronics, silicon, is limited in its ability to control light. In the search for alternative materials, a class of glasses called amorphous chalcogenides (a-ChGs) have shown remarkable promise, to the point where they have been referred to as the 'optical equivalent of silicon'. Chalcogenides are materials which contain one or more of the elements sulfur, selenium or tellurium as a major constituent. These materials are already widely used in applications such as photovoltaics, memory (e.g. DVDs), advanced optical devices (e.g. lasers), and in some thermoelectric generation systems. It is accepted that the move to all-optical technologies will require an intermediate stage where information processing is undertaken using a hybrid 'optoelectronic' system. This provides a strong and compelling argument for the development of a-ChGs, as they can be deposited on Si to form a hybrid approach en-route to their use as an all-optical platform. Whilst the optical properties of a-ChGs may be controlled and modified it has proved to be extremely difficult to modify their electronic properties during the material preparation, which has typically involved melting at high temperatures. Any impurities that are added to these materials in order to change the electronic behaviour are ineffective under these conditions due to the ability of the ChG material to reorder itself when melted, and so negate the desired doping effect. We have successfully pioneered a method to modify their properties by introducing dopants into a-ChGs below their melting temperature, thus not allowing the material to reorder, using ion-implantation. This method of doping allows precise control of the type of impurity introduced and is widely used in silicon technologies. As a result of this work, we have demonstrated the ability to reverse the majority charge carrier type from holes (p-type) to electrons (n-type) in a spatially localised way. This step-changing achievement enabled us to demonstrate the fabrication of optically active pn-junctions in a-ChGs, which will act as the enabling catalyst for the development of future photonic technologies. In this project we will seek to develop a full understanding of the process of carrier-type reversal on the atomic scale, and use this information to optimize it, and the materials that are to be modified, so as to add further functionality. We will also develop the required advanced engineering methods which relate to the control and activation of dopants introduced using ion-implantation into a-ChGs. Together, these will enable the demonstration of a series of optoelectronic devices demonstrating the key functionalities required to build an integrated optoelectronic technology. This programme will consolidate the position of the UK as the world leader in the field of non-equilibrium doping of chalcogenides. We will, in this way, champion these materials in the world's transition to beyond CMOS technology and therefore directly contribute to the continuing growth of the knowledge economy. We will train the next generation of scientists and engineers in state-of-the-art techniques to ensure that the UK maintains the expertise base required for this purpose, aim to ensure that the impact of this work is maximised and accelerated where possible, and communicate the results widely, including to all stakeholders in this research.

The recording of high resolution spectral images and non-invasive monitoring of wall paintings in grotto sites, tombs and buildings are particularly important since these paintings are extremely vulnerable. The remoteness of some of the sites, the inaccessible height of some of the paintings and the difficulty in controlling the environment they are in, all contribute to their vulnerability. Imaging of wall paintings at high resolution currently requires either scaffolding or some heavy and cumbersome mechanical structure to lift the camera to the upper parts of a wall or ceiling. The aim of the proposed project is to develop a portable imaging system that is light-weight and flexible for in situ high resolution, accurate colour and spectral imaging in the visible/near infrared (400-1000nm) and short-wave infrared (900nm-1700nm), including fluorescence imaging of wall paintings and other large paintings from ground level. The system would provide the means of non-invasive monitoring of the conditions of the paintings, revealing past intervention, studying painting techniques and identifying pigments and disseminating the 3D colour images to the general public. The portability of the system means that it can be taken to remote sites to image paintings in situ without the need for scaffolding or other cumbersome mechanical structures and that it can also be used to image large museum paintings and painted objects in situ at high resolution.

A Centre for Innovative Manufacture in Laser-based Production Processes is proposed. This Centre will exploit the unique capabilities of laser light to develop new laser-based manufacturing processes, at both micro and macro levels, supported by new laser source, process monitoring and system technologies. The past 25 years has seen industrial lasers replace many 'conventional' tools in diverse areas of manufacture, enabling increased productivity, functionality and quality, where for example laser processing (cut/join/drill/mark) has revolutionised automotive, aerospace and electronics production. However the penetration of laser technology into some areas such as welding and machining has been less than might have been anticipated. But recently there has been a significant 'step change-opportunity' to take laser-based processing to a new level of industrial impact, brought about by major advances in laser technology in two key areas: (i) A new generation of ultra-high quality and reliability lasers based around solid state technology (laser diode and optical fibre) has evolved from developments in the telecoms sector. These lasers are leading to systems with very high levels of spatial and temporal controllability. This control, combined with advanced in-process measurement techniques, is revolutionising the science and understanding of laser material interactions. The result of this is that major improvements are being made in existing laser based processes and that new revolutionary processes are becoming viable, e.g. joining of dissimilar materials. (ii) A new generation of high average power laser technologies is becoming available, offering controllable trains of ultrashort (picosecond and femtosecond) pulses, with wavelengths selectable across the optical spectrum, from the infrared through to the ultra-violet. Such technology opens the door to a whole range of new laser-based production processes, where thermal effects no longer dominate, and which may replace less efficient 'conventional' processes in some current major production applications. These new developments are being rapidly exploited in other high-value manufacturing based economies such as Germany and the US. We argue that for the UK industry to take maximum advantage of these major advances in both laser material processing and machine technology there is an urgent requirement for an EPSRC Centre for Innovative Manufacturing in Laser-based Production Processes. This will be achieved by bringing together a multi-disciplinary team of leading UK researchers and key industry partners with the goal of exploiting 'tailored laser light'. Together with our industrial partners, we have identified 2 key research themes. Theme A focuses on Laser Precision Structuring, i.e. micro-machining processes, whilst Theme B is focused on joining and additive processes. Spanning these themes are the laser based manufacturing research challenges which fall into categories of Laser Based Production Process Research and Laser Based Machine Technologies, underpinned by monitoring and control together with material science. Research will extend from the basic science of material behaviour modelling and laser-material interaction processes to manufacturing feasibility studies with industry. The Centre will also assume an important national role. The Centre Outreach programme will aim to catalyse and drive the growth of a more effective and coherent UK LIM community as a strong industry/academia partnership able to represent itself effectively to influence UK/EU policy and investment strategy, to promote research excellence, and growth in industrial take-up of laser-based technology, expand UK national knowledge transfer and marketing events and improve the coordination and quality of education/training provision.

Manufacturing with lasers has advanced from the purely science fiction ideas of the 1950's and 60's to be a real world, critical step, in the manufacture of an enormous range of products. Over the years a range of new techniques and processes have been developed in research labs and companies across the world. One of the more important of these has been the development of beam-shaping technology. Laser processing of material is driven by transfer of energy from the laser beam into the material, and can be a mixture of thermal, photo-chemical and optical non-linear effects. By changing the shape of a laser beam where it impacts a material it is possible to mould how and where energy is transferred. This then allows for more precise control of the laser-material interaction and hence of the manufacturing process itself. This has led to improvements in the way cutting, welding and similar processes work with improvements in quality and efficiency. However these beam-shaping technologies are limited. They only shape in two dimensions, i.e. in a single focal plane. This is not a big problem for "surface processes" as the plane at which the laser beam is formed into the right shape can be made, with some care in focussing the beam, to be the surface of the material. However for materials with an irregular shape, imprecise thicknesses, or that are at least partially transparent to the laser, this is a challenge. It is also a challenge when trying to take advantage of the range of exciting new technologies based on non-linear phenomena. Non-linear laser processes typically limit the laser material interaction to only those regions of the laser beam where there is an extremely high intensity i.e. at the focus. By moving the focus inside the material it then possible to manufacture from the inside out. However, because the light interacts with the material not just on the surface but throughout the focal volume two dimensional beam shaping is insufficient; full 3D control is instead required. Within this research project we will take advantage of the wave-nature of light. Through careful shaping of a glass optic it is possible to bend different parts of a laser beam to overlap in a controlled manner. As the beams overlap they will interfere creating regions of high and low energy. Though careful calculation it is possible to manipulate this with each optic designed to give a precise interference pattern which results in a specific energy distribution; to shape the beam in three dimensions. By shaping the laser beam throughout the focal region it will be possible to open entirely new methods of manufacture from more effective means to cut toughened glass (like mobile phones or iPads), dice and drill semiconductors (for computer chips), make precision medical devices, and create new and much more effective surgical procedures. The potential applications are truly enormous, transformative and will change how and what we can manufacture.

This platform grant will underpin integrated photonics research in advanced laser sources, photonic circuits, and sensors, at the Optoelectronics Research Centre (ORC) at the University of Southampton, leveraging the recent investment of >£100M in the new Mountbatten Fabrication Complex. Photonic materials and device research has been the key driver of many disruptive advances in telecommunications, healthcare, data storage, display and manufacturing, and this platform grant will provide the group with the horizon and stability to build upon its international standing to explore new high-risk, high-reward research avenues. Integrated photonic materials and devices of the future will play a huge role in the next generation of cheaper, faster, greener, disposable, miniaturised and more versatile systems based on silica and silicon, glasses, crystal and polymer hosts, in both channel and planar geometries. The broad range of expertise within our group and our access to the unequalled brand-new planar fabrication facilities will allow us to fully explore this diverse research area. Impact will be realised through applications in compact kW-class waveguide lasers (new manufacturing techniques), pollution sensors (monitoring climate change), optical amplifiers and switches (high-speed data control), early threat detection devices (homeland security), and fast universally accessible disease screening (point-of-care medical diagnostics). Applications for the photonic materials, processes and devices developed during this platform grant will play a key role in fields of interest to society, Industry as well as university-based research and development, and will be pursued in collaboration with both existing and newly-identified partners during the programme.