Perovskite Solar Cells with Carbon‐Based Electrodes – Quantification of Losses and Strategies to Overcome Them
Copyright policy )Perovskite Solar Cells with Carbon‐Based Electrodes – Quantification of Losses and Strategies to Overcome Them
AbstractCarbon‐based electrodes represent a promising approach to improve stability and up‐scalability of perovskite photovoltaics. The temperature at which these contacts are processed defines the absorber grain size of the perovskite solar cell: in cells with low‐temperature carbon‐based electrodes (L‐CPSCs), layer‐by‐layer deposition is possible, allowing perovskite crystals to be large (>100 nm), while in cells with high‐temperature carbon‐based contacts (H‐CPSCs), crystals are constrained to 10–20 nm in size. To enhance the power conversion efficiency of these devices, the main loss mechanisms are identified for both systems. Measurements of charge carrier lifetime, quasi‐Fermi level splitting (QFLS) and light‐intensity‐dependent behavior, supported by numerical simulations, clearly demonstrate that H‐CPSCs strongly suffer from non‐radiative losses in the perovskite absorber, primarily due to numerous grain boundaries. In contrast, large crystals of L‐CPSCs provide a long carrier lifetime (1.8 µs) and exceptionally high QFLS of 1.21 eV for an absorber bandgap of 1.6 eV. These favorable characteristics explain the remarkable open‐circuit voltage of over 1.1 V in hole‐selective layer‐free L‐CPSCs. However, the low photon absorption and poor charge transport in these cells limit their potential. Finally, effective strategies are provided to reduce non‐radiative losses in H‐CPSCs, transport losses in L‐CPSCs, and to improve photon management in both cell types.
- École Polytechnique Fédérale de Lausanne EPFL Switzerland
- University of Cambridge United Kingdom
- University of Freiburg Germany
- THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE United Kingdom
- Fraunhofer Institute for Solar Energy Systems Germany
Electrode, design, Grain boundary, Physical Chemistry, Engineering, Band gap, Materials Chemistry, Carbon fibers, Applications of Quantum Dots in Nanotechnology, Perovskite (structure), Microstructure, Photovoltaic system, Fysikalisk kemi, Ecology, carbon-based electrodes, Physics, 522, Composite number, Open-circuit voltage, Grain size, htl-free, Chemistry, Absorption (acoustics), Physical chemistry, Solar Cell Efficiency, Physical Sciences, impact, Energy conversion efficiency, films, performance, Composite material, Thin-Film Solar Cells, Perovskite Solar Cell Technology, Materials Science, Photovoltaic Cells, perovskites, Energy Engineering, Charge carrier, HTL-free, Quantum mechanics, Chemical engineering, FOS: Electrical engineering, electronic engineering, information engineering, Electrical and Electronic Engineering, Optoelectronics, Biology, FOS: Chemical engineering, hole-conductor-free, Solar cell, temperature, Voltage, methylammonium lead iodide, Perovskite solar cell, Materials science, recombination, Solar Cells, Energiteknik, Thin-Film Solar Cell Technology, Photovoltaics, photovoltaics, FOS: Biological sciences, grain-size, Perovskite Solar Cells
Electrode, design, Grain boundary, Physical Chemistry, Engineering, Band gap, Materials Chemistry, Carbon fibers, Applications of Quantum Dots in Nanotechnology, Perovskite (structure), Microstructure, Photovoltaic system, Fysikalisk kemi, Ecology, carbon-based electrodes, Physics, 522, Composite number, Open-circuit voltage, Grain size, htl-free, Chemistry, Absorption (acoustics), Physical chemistry, Solar Cell Efficiency, Physical Sciences, impact, Energy conversion efficiency, films, performance, Composite material, Thin-Film Solar Cells, Perovskite Solar Cell Technology, Materials Science, Photovoltaic Cells, perovskites, Energy Engineering, Charge carrier, HTL-free, Quantum mechanics, Chemical engineering, FOS: Electrical engineering, electronic engineering, information engineering, Electrical and Electronic Engineering, Optoelectronics, Biology, FOS: Chemical engineering, hole-conductor-free, Solar cell, temperature, Voltage, methylammonium lead iodide, Perovskite solar cell, Materials science, recombination, Solar Cells, Energiteknik, Thin-Film Solar Cell Technology, Photovoltaics, photovoltaics, FOS: Biological sciences, grain-size, Perovskite Solar Cells
