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Faceted Branched Nickel Nanoparticles with Tunable Branch Length for High‐Activity Electrocatalytic Oxidation of Biomass

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type , Journal 13 Jul 2020 Australia, Australia, Australia, Germany Publisher:WileyJournal:Angewandte Chemie International Edition, volume 59, pages 15,487-15,491 (issn: 1433-7851, eissn: 1521-3773,

Copyright policy )Funded by:ARC | Australian Laureate Fello..., ARC | Discovery Projects - Gran..., ARC | Discovery Projects - Gran... +3 projects

Authors: Agus R. Poerwoprajitno; Lucy Gloag; John Watt; Steffen Cychy; Soshan Cheong; Priyank V. Kumar; Tania M. Benedetti; +9 Authors

doi: 10.1002/anie.202005489

pmid: 32449976

pmc: PMC7497201

handle: 1959.4/unsworks_82946 , 10072/412841

Faceted Branched Nickel Nanoparticles with Tunable Branch Length for High‐Activity Electrocatalytic Oxidation of Biomass

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Abstract

AbstractControlling the formation of nanosized branched nanoparticles with high uniformity is one of the major challenges in synthesizing nanocatalysts with improved activity and stability. Using a cubic‐core hexagonal‐branch mechanism to form highly monodisperse branched nanoparticles, we vary the length of the nickel branches. Lengthening the nickel branches, with their high coverage of active facets, is shown to improve activity for electrocatalytic oxidation of 5‐hydroxymethylfurfural (HMF), as an example for biomass conversion.

Countries

Australia, Australia, Australia, Germany

Related Organizations

UNSW Sydney
Australia
Griffith University
Australia
LWL-Universitätsklinik Hamm
Germany
Griffith University
Australia
Sandia National Laboratories
United States

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Keywords

Surface Properties, ddc:540, Metal Nanoparticles, Bioengineering, anzsrc-for: 34 Chemical Sciences, Catalysis, Nickel, Electrochemistry, Nanotechnology, branching mechanisms, electrocatalysis, nanoparticle synthesis, Furaldehyde, Biomass, Particle Size, anzsrc-for: 03 Chemical Sciences, HMF oxidation, Nanomaterials, Science & Technology, Multidisciplinary, 34 Chemical Sciences, 540, Communications, Chemistry, Chemical sciences, Physical Sciences, 7 Affordable and Clean Energy, branched nickel, Oxidation-Reduction

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