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A Green Approach to Ethyl Acetate: Quantitative Conversion of Ethanol through Direct Dehydrogenation in a Pd–Ag Membrane Reactor

descriptionPublicationkeyboard_double_arrow_right Article , Journal 07 Nov 2012 Saudi Arabia Publisher:WileyJournal:Chemistry – A European Journal, volume 18, pages 15,940-15,943 (issn: 0947-6539, eissn: 1521-3765,

Authors: Zeng, Gaofeng; Chen, Tao; He, Lipeng; Pinnau, Ingo; Lai, Zhiping; Huang, Kuo-Wei;

doi: 10.1002/chem.201202005

pmid: 23136053

handle: 10754/562403

A Green Approach to Ethyl Acetate: Quantitative Conversion of Ethanol through Direct Dehydrogenation in a Pd–Ag Membrane Reactor

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Abstract

Pincers do the trick: The conversion of ethanol to ethyl acetate and hydrogen was achieved using a pincer-Ru catalyst in a Pd-Ag membrane reactor. Near quantitative conversions and yields could be achieved without the need for acid or base promoters or hydrogen acceptors (see scheme).

Country

Saudi Arabia

Related Organizations

King Abdullah University of Science and Technology
Saudi Arabia
King Abdullah University of Science and Technology
Saudi Arabia

Keywords

ethyl acetate, dehydrogenation, membrane reactor, ethanol, ruthenium

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	citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	34
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	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Top 10%