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An Interlaboratory Study on the Stability of All‐Printable Hole Transport Material–Free Perovskite Solar Cells

Authors: John Chircop; Trystan Watson; Brian Azzopardi; Luigi Angelo Castriotta; Francesca De Rossi; Francesca De Rossi; David M. Tanenbaum; +13 Authors

An Interlaboratory Study on the Stability of All‐Printable Hole Transport Material–Free Perovskite Solar Cells

Abstract

Comparisons between different laboratories on long‐term stability analyses of perovskite solar cells (PSCs) is still lacking in the literature. This work presents the results of an interlaboratory study conducted between five laboratories from four countries. Carbon‐based PSCs are prepared by screen printing, encapsulated, and sent to different laboratories across Europe to assess their stability by the application of three ISOS aging protocols: (a) in the dark (ISOS‐D), (b) under simulated sunlight (ISOS‐L), and (c) outdoors (ISOS‐O). Over 1000 h stability is reported for devices in the dark, both at room temperature and at 65 °C. Under continuous illumination at open circuit, cells survive only for few hours, although they recover after being stored in the dark. Better stability is observed for cells biased at maximum power point under illumination. Finally, devices operate in outdoors for 30 days, with minor degradation, in two different locations (Barcelona, Spain and Paola, Malta). The findings demonstrate that open‐circuit conditions are too severe for stability assessment and that the diurnal variation of the photovoltaic parameters reveals performance to be strongly limited by the fill factor, in the central hours of the day, due to the high series resistance of the carbon electrode.

Countries
Spain, United Kingdom, Italy, Malta
Keywords

Interlaboratory studies, Perovskite solar cells, carbon, Direct energy conversion, 621, long-term stability, ISOS protocols, 530, interlaboratory studies, perovskite solar cells, Carbon, 620, Solar cells -- Materials, Settore ING-INF/01 - ELETTRONICA, Long-term stability, Photovoltaic cells -- Materials

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
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27
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11
4
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