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Alternative Thieno[3,2‐b][1]benzothiophene Isoindigo Polymers for Solar Cell Applications

Authors: Sergei Lopatin; Iain McCulloch; Iain McCulloch; Rawad K. Hallani; Hu Chen; Daniel Bryant; Lewis Cater; +3 Authors

Alternative Thieno[3,2‐b][1]benzothiophene Isoindigo Polymers for Solar Cell Applications

Abstract

AbstractThis work reports the synthesis, characterization, photophysical, and photovoltaic properties of five new thieno[3,2‐b][1]benzothiophene isoindigo (TBTI)‐containing low bandgap donor–acceptor conjugated polymers with a series of comonomers and different side chains. When TBTI is combined with different electron‐rich moieties, even small structural variations can have significant impact on thin film morphology of the polymer:phenyl C70 butyric acid methyl ester (PCBM) blends. More importantly, high‐resolution electron energy loss spectroscopy is used to investigate the phase‐separated bulk heterojunction domains, which can be accurately and precisely resolved, enabling an enhanced correlation between polymer chemical structure, photovoltaic device performance, and morphology.

Countries
Saudi Arabia, Saudi Arabia, Cyprus
Keywords

Indoles, Polymers, Conjugated Polymers, Electrons, Thiophenes, Electric Power Supplies, conjugated polymers, Solar Energy, Thieno-benzothiophene Isoindigo, Mechanical Engineering, Materials Engineering, Eels Mapping, Solar Cells, solar cells, Engineering and Technology, EELS mapping, thieno-benzothiophene isoindigo

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