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Article . 1991 . Peer-reviewed
License: Elsevier TDM
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Formation of NOx in fluidized bed combustion of model mixtures of liquid organic compounds containing nitrogen

Authors: Miloslav Hartman; Karel Svoboda;

Formation of NOx in fluidized bed combustion of model mixtures of liquid organic compounds containing nitrogen

Abstract

Abstract Model liquid mixtures of organic compounds containing nitrogen were burned in a laboratory fluidized bed reactor at temperatures ranging from 700 to 900 °C and oxygen concentrations ranging from 2 to 15 vol%. The model solutions included binary mixtures of toluene with pyridine, quinoline, aniline, 1-aminonaphthalene, nitrobenzene and benzonitrile. Several ternary mixtures containing propanol, ethanol, pyridine, thiophene, toluene and urea were also employed. The nitrogen concentrations in the model mixtures varied within the range 0.5–5 wt%. The results showed that the dependence of the NO x emissions on temperature was influenced by the gas phase oxygen concentration. The conversion of the fuel nitrogen to NO x was less dependent on nitrogen compound type than on other factors. The conversions to NO x increased with increasing air excess for combustion and with decreasing organic nitrogen concentrations. Only a weak influence of SO 2 and in situ desulphurization on NO x emissions in the fluidized bed was observed. Addition of water, propanol or ethanol to a model burned mixture caused a significant reduction of NO x emissions.

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    19
    popularity
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    influence
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Found an issue? Give us feedback
citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
19
Average
Top 10%
Average