Abstract An electrochemical conversion technique has been developed to deposit selective black nickel coatings of solar absorptance 0.90–0.94 and thermal emittance (at 100°C) 0.08–0.15 on galvanized iron, zincated, and zinc electroplated aluminium surfaces. The effect of electrochemical conversion parameters on the microstructure, optical and thermal properties and durability of the coatings has been established.