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Dynamics and useful heat of the discharge stage of adsorptive cycles for long term thermal storage

Authors: Palomba Valeria; Sapienza Alessio; Aristov Yuri;

Dynamics and useful heat of the discharge stage of adsorptive cycles for long term thermal storage

Abstract

Interest towards adsorption heat storage, especially for long-term (seasonal) applications, is growing. The previous studies have always treated the heat storage cycle as a fully temperature-initiated process, similarly to common adsorption cooling and heating cycles. However, in long term storage applications, the discharge stage of the cycle is initiated by a jump of pressure rather than by a traditional drop of temperature. This requires specific investigations on the useful heat recoverable as well as on the adsorption dynamics.In the present paper, an appropriate experimental methodology was applied for studying the heat discharge stage. Three well known adsorbents (Mitsubishi AQSOA FAM-Z02, silica Siogel and composite LiCl/silica) were experimentally tested in a lab-scale heat storage unit, evaluating the effect of cycle operating parameters. The results, elaborated in terms of useful heat recoverable from the charged adsorbent, highlighted that the evaporation temperature and the flow rate of heat transfer fluid have a great influence on the adsorption dynamics and the useful heat. For the silica gel and FAM Z02, the maximum heat storage capacity 450 kJ/kg is reached at the evaporation temperature of 25 degrees C. The composite performs better at low evaporation temperatures, allowing heat upgrade even at 5 degrees C. The flow rate of the heat transfer fluid has a more significant effect on FAM Z02 than on the other adsorbents, for which an optimal flow rate of 1.2 kg/min was found.

Country
Italy
Keywords

Useful heat, Adsorption dynamics, Heat rejection, Adsorption heat storage, Long term heat storage

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
28
Top 10%
Top 10%
Top 10%