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Applied Energy
Article . 2021 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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Techno-economic comparison of 100% renewable urea production processes

Authors: Zhang, Hanfei; Wang, Ligang; Van herle, Jan; Maréchal, François; Desideri, Umberto;

Techno-economic comparison of 100% renewable urea production processes

Abstract

Abstract Urea is widely used in agriculture, industry, and food, while it is also a potential fuel. Large-scale urea production relies on fossil fuels, thus there is a strong need for green urea given the increasing penetration of renewable energy sources. A potential alternative is biomass-to-urea; however, it cannot fully convert the biomass carbon into urea. To achieve full carbon conversion, innovative integrated biomass- and power-to-urea processes are designed conceptually. The two green urea production processes are evaluated techno-economically and compared with state-of-the-art methane-to-urea. The results show that the methane-to-urea achieves a system efficiency of 58% (LHV), while biomass-to-urea only has 39% (LHV) with unconverted biomass carbon of up to 60%. The integrated power- and biomass-to-urea has outstanding heat integration performance which fixes all biomass carbon into urea, with an efficiency enhanced up to 53%. Due to the electricity demand, the levelized cost of the urea of integrated biomass- and power-to-urea is 15 – 38 and 58 – 87% points higher than those of the biomass-to-urea and methane-to-urea for the scale of 10 – 60 MWth urea production. The available annual hours and electricity price of renewable electricity have a significant impact on the levelized cost of the urea. When the available annual hours decrease from 7200 to 3600 with an electricity price of 73 $/MWh, the levelized cost of urea increases on average by 13% from 51 $/GJ with the plant capacity being 10 – 60 MWth urea. However, when electricity price is reduced from 73 $/MWh to 35 $/MWh with available annual hours of 3600, the levelized cost decreases on average by 15% from 59 $/GJ with the same plant capacity.

Countries
Switzerland, Italy
Keywords

solid-oxide electrolyzer, power-to-urea, design, gasification, renewable urea, power, electrolysis, cost, Renewable urea; Methane-to-urea; Biomass-to-urea; Power-to-urea; Power-to-hydrogen; Solid-oxide electrolyzer, biomass, ammonia production, biomass-to-urea, systems, power-to-hydrogen, optimization, methane-to-urea, performance

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    52
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
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    Top 10%
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
52
Top 10%
Top 10%
Top 1%