[EN] Fuel cell (FC) technology has been identified as a technically attractive solution to decarbonize the transportation sector, especially for heavy-duty vehicles. In this context, the industry and the scientific community are in need of advanced fuel cell systems (FCS) models that are able to replicate real-world operating conditions. Due to the scarcity of said models in the open literature, this study aimed to develop a comprehensive methodology to calibrate and validate multi-physics dynamic FCS models. Therefore, the key contribution of this paper is the detailed description of the calibration process for each component and the calibration order. The specific focus here was to accurately describe the behavior of the FC stack as well as the cathode, anode, and cooling circuits of the balance of plant. The model was calibrated with the aid of experimental data from a Toyota Mirai FC electric vehicle, which was predominantly retrieved from the vehicle¿s Controller Area Network (CAN) bus system thereby negating the need for major intrusion into the powertrain system. The validation process was deemed successful with the model being able to truthfully replicate the characteristics of the FC vehicle operated on the World-wide harmonized Light duty Test Cycle (WLTC) 3b and US06 driving cycle. The time-resolved physical parameters such as the cathode pressure, mass flow, or the FC stack temperature were captured with high fidelity, while the overall performance parameters such as the H2 consumption in the stack and the system, and the compressor energy consumption were predicted accurately with a deviation lower than 0.47%, 1.75% and 1.89% with respect to the experimental data, respectively.

This research is part of the project TED2021-131463B-I00 (DI-VERGENT) funded by MCIN/AEI/10.13039/501100011033 and the European Union "NextGenerationEU"/PRTR. It has also been partially funded by the Spanish Ministry of Science, Innovation, and University through the University Faculty Training (FPU) program (FPU19/00550) . Toby Rockstroh and Ram Vijayagopal acknowledge support through the US DOE Vehicle Technologies Program. Argonne National Laboratory is operated by UChicago Argonne, LLC under Contract no. DE-AC02-06CH11357. The US Government retains for itself, and others acting on its behalf, a paid-up non-exclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly, by or on behalf of the Government. The authors would like to express their gratitude to Kevin Stutenberg from Argonne National Laboratory for the informative discussions surrounding the experimental test campaign.