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Bioresource Technology
Article . 2009 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Production of biodiesel from acid waste lard

Authors: Joana M. Dias; Maria C. M. Alvim Ferraz; Manuel F. Almeida;

Production of biodiesel from acid waste lard

Abstract

The objective of the present work was: (i) to enable biodiesel production from acid waste lard; (ii) to study the esterification reaction as possible pre-treatment at different temperatures, catalyst amount and reaction times; (iii) to evaluate biodiesel quality according to EN 14214 after basic transesterification of the pre-treated fat; and (iv) to predict the impact of using such waste as raw material in mixture with soybean oil. Temperature and catalyst amount were the most important reaction conditions which mostly affected biodiesel quality, namely viscosity and purity. The selected pre-treatment conditions were 65 degrees C, 2.0 wt% H(2)SO(4) and 5 h, which allowed obtaining a product with a viscosity of 4.81 mm(2) s(-1) and a purity of 99.6 wt%. The proposed pre-treatment was effective to enable acid wastes as single raw materials for biodiesel production with acceptable quality; however, low yields were obtained (65 wt%). Alkali transesterification of a mixture of waste lard and soybean oil resulted in a product with a purity of 99.8 wt% and a yield of 77.8 wt%, showing that blending might be an interesting alternative to recycle such wastes. Also, because in addition to using conventional and relatively economical processes, some biodiesel properties depending on the raw material composition (such as the iodine value) might even be improved.

Country
Portugal
Related Organizations
Keywords

:Environmental engineering [Engineering and technology], Chromatography, Gas, Bioelectric Energy Sources, Catalysis, Waste Products, Esterification, Viscosity, Temperature, Esters, Engenharia química, Engenharia do ambiente, Dietary Fats, :Engenharia do ambiente [Ciências da engenharia e tecnologias], Soybean Oil, Acids, Chemical engineering, Environmental engineering

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    140
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
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    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
140
Top 1%
Top 10%
Top 10%