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The influence of recycling non-condensable gases in the fractional catalytic pyrolysis of biomass
pmid: 22382295
In this study, the effect of recycling the non-condensable gases (NCG) in the catalytic pyrolysis of hybrid poplar using FCC catalyst was investigated. A 50mm bench scale fluidized bed reactor at 475°C with a weight hourly space velocity (WHSV) of 2h(-1) and a gas recycling capability was used for the studies. Model fluidizing gas mixtures of CO/N(2), CO(2)/N(2), CO/CO(2)/N(2) and H(2)/N(2) were used to determine their independent effects. Recycling of the NCG in the process was found to potentially increase the liquid yield and decrease char/coke yield. The model fluidizing gases increased the liquid yield and the CO(2)/N(2) fluidizing gas had the lowest char/coke yield. The (13)C-NMR analysis showed that recycling of NCG increases the aromatic fractions and decreases the methoxy, carboxylic and sugar fractions. Recycling of NCG increased the higher heating value and the pH of the bio-oil as well as decreased the viscosity and density.
- BASF (Germany) Germany
- Utah State University United States
- BASF (United States) United States
- Virginia Tech United States
Magnetic Resonance Spectroscopy, Recycling, Biomass, Gases, Catalysis
Magnetic Resonance Spectroscopy, Recycling, Biomass, Gases, Catalysis
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).62 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 10% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 10% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 10%
