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Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions

pmid: 24472746
Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions
To investigate the kinetic characteristics of coking coal mixed with biomass during pyrolysis, thermogravimetric (TG) and thermo-balance reactor (TBR) analyses were conducted under non-isothermal and isothermal condition. Yellow poplar as a biomass (B) was mixed with weak coking coal (WC) and hard coking coal (HC), respectively. The calculated activation energies of WC/B blends were higher than those of HC/B blends under non-isothermal and isothermal conditions. The coal/biomass blends show increased reactivity and decreased activation energy with increasing biomass blend ratio, regardless of the coking properties of the coal. The different char structures of the WC/B and HC/B blends were analyzed by BET and SEM.
- Korea Institute of Energy Research Korea (Republic of)
- Pohang Iron and Steel (South Korea) Korea (Republic of)
- Kier Group United Kingdom
- Pohang Iron and Steel (South Korea) Korea (Republic of)
- Kier Group United Kingdom
Hot Temperature, Liriodendron, Kinetics, Coal, Biofuels, Thermogravimetry, Microscopy, Electron, Scanning, Biomass, Coke, Porosity
Hot Temperature, Liriodendron, Kinetics, Coal, Biofuels, Thermogravimetry, Microscopy, Electron, Scanning, Biomass, Coke, Porosity
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