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Thermal behaviour and kinetic study of the olive oil production chain residues and their mixtures during co-combustion

Authors: BURATTI, Cinzia; MOUSAVI, SORAYA SADAT; BARBANERA, MARCO; LASCARO, ELISA; COTANA, Franco; Bufacchi, M.;

Thermal behaviour and kinetic study of the olive oil production chain residues and their mixtures during co-combustion

Abstract

The kinetic behaviour of olive tree pruning (PR), two- (2PH) and three-phase (3PH) olive pomace and their blends was investigated under combustion condition using thermogravimetric analysis. PR was blended with 2PH and 3PH at different ratios (25:75, 50:50 and 75:25) and tested in the temperature range from ambient to 1000°C in order to evaluate the co-combustion behaviour. Results showed that the thermal degradation of all samples can be divided into three regions (drying, devolatilisation, char oxidation) with different combustion properties, depending on the percentage of PR. Significant interaction was detected between the fuels, and reactivity of 2PH and 3PH was improved upon blending with PR. The iso-conversional methods, Ozawa-Flynn-Wall and Vyazovkin, were employed for the kinetic analysis of the oxidation process. The results revealed that the activation energy of PR was higher than the one of 2PH and 3PH, and the minimum value was obtained for 25PR752PH sample.

Country
Italy
Keywords

Hot Temperature, Co-combustion; Kinetics; Non-isothermal; Olive pomace; Olive tree pruning; Bioengineering; Environmental Engineering; Waste Management and Disposal, Industrial Waste, Refuse Disposal, Kinetics, Olea, Thermogravimetry, Food-Processing Industry, Co-combustion; Kinetics; Non-isothermal; Olive pomace; Olive tree pruning, Olive Oil

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    29
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
29
Top 10%
Top 10%
Top 10%