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Integrated Solar Thermochemical Reaction System for Steam Methane Reforming

Authors: Paul H. Humble; Dustin D. Caldwell; Robert S. Wegeng; Robert A. Dagle; Ward E. TeGrotenhuis; Brad G. Fritz; Richard Zheng; +2 Authors

Integrated Solar Thermochemical Reaction System for Steam Methane Reforming

Abstract

AbstractSolar-aided upgrade of the energy content of fossil fuels, such as natural gas, can provide a near-term transition path towards a future solar-fuel economy and reduce carbon dioxide emission from fossil fuel consumption. Both steam and dry reforming a methane-containing fuel stream have been studied with concentrated solar power as the energy input to drive the highly endothermic reactions but the concept has not been demonstrated at a commercial scale. Under a current project with the U.S. Department of Energy, PNNL is developing an integrated solar thermochemical reaction system that combines solar concentrators with micro- and meso-channel reactors and heat exchangers to accomplish more than 20% solar augment of methane higher heating value. The objective of our three-year project is to develop and prepare for commercialization such solar reforming system with a high enough efficiency to serve as the frontend of a conventional natural gas (or biogas) combined cycle power plant, producing power with a levelized cost of electricity less than 6¢/kWh, without subsidies, by the year 2020. In this paper, we present results from the first year of our project that demonstrated a solar-to-chemical energy conversion efficiency as high as 69% with a prototype reaction system.

Keywords

Natural Gas, Microchannel Reaction, Methane Reforming, Steam Reforming, Concentrated Solar Power, Energy(all), Process Intensification

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