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Environmental risks of farmed and barren alkaline coal ash landfills in Tuzla, Bosnia and Herzegovina

pmid: 17949870
The disposal of coal combustion residues (CCR) has led to a significant consumption of land in the West Balkan region. In Tuzla (Bosnia and Herzegovina) we studied previously soil-covered (farmed) and barren CCR landfills including management practises, field ageing of CCR and the transfer of trace elements into crops, wild plants and wastewaters. Soil tillage resulted in mixing of cover soil with CCR. Medicago sativa showed very low Cu:Mo ratios (1.25) which may cause hypocuprosis in ruminants. Total loads of inorganic pollutants in the CCR transport water, but not pH ( approximately 12), were below regulatory limits of most EU countries. Arsenic concentrations in CCR transport water were <2microgl(-1) whereas reductive conditions in an abandoned landfill significantly enhanced concentrations in leachates (44microgl(-1)). The opposite pattern was found for Cr likely due to large initial leaching of CrVI. Public use of landfills, including farming, should be based on a prior risk assessment due to the heterogeneity of CCR.
- University of Rijeka, Faculty of Physics Croatia
- Helmholtz Association of German Research Centres Germany
- University of Zagreb Croatia
- University of Natural Resources and Applied Life Sciences Nigeria
- Forest Research United Kingdom
Chromium, Risk, Industrial Waste, 550 - Earth sciences, Incineration, Arsenic, Time, Humans, Soil Pollutants, Environmental Restoration and Remediation, Bosnia and Herzegovina, Molybdenum, Agriculture, Hydrogen-Ion Concentration, Refuse Disposal, Coal, Adsorption, Environmental Pollution, Copper, Environmental Monitoring, Power Plants
Chromium, Risk, Industrial Waste, 550 - Earth sciences, Incineration, Arsenic, Time, Humans, Soil Pollutants, Environmental Restoration and Remediation, Bosnia and Herzegovina, Molybdenum, Agriculture, Hydrogen-Ion Concentration, Refuse Disposal, Coal, Adsorption, Environmental Pollution, Copper, Environmental Monitoring, Power Plants
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