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Agritrop
Article . 2013
Data sources: Agritrop
Journal of Analytical and Applied Pyrolysis
Article . 2013 . Peer-reviewed
Data sources: Crossref
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Autothermal and allothermal pyrolysis in a continuous fixed bed reactor

Authors: Milhe, Mathieu; Van de Steene, Laurent; Haube, Michaël; Commandre, Jean-Michel; Fassinou, Wanignon Ferdinand; Flamant, Gilles;

Autothermal and allothermal pyrolysis in a continuous fixed bed reactor

Abstract

Abstract Pyrolysis plays a major role in the optimization of process efficiency and gas quality in two-stage gasifiers. We developed an original reactor at pilot scale to investigate continuous fixed bed pyrolysis, in either allothermal or autothermal operating mode using air injection. Instrumentation and analysis enabled thermal profiles to be established inside the bed along with fine measurement of yields, char composition, permanent gases, and compounds at the outlet of the pyrolysis reactor. Under oxidative conditions, fixed-bed pyrolysis led to smoldering and the stabilization of an ignition front between 10 and 20 cm below the bed surface. With oxidative pyrolysis, yields of organic condensates were lower than with allothermal pyrolysis, whereas the production of pyrolysis water and permanent gases increased considerably. The main conclusion is that during autothermal pyrolysis in fixed-bed conditions, the presence of oxygen promotes oxidation of volatile matter and cracking reactions, thereby increasing the production of pyrolysis water and permanent gases. We observed a significant increase in yields of CO2 and CO, while the yield of char remained comparable to that in allothermal experiments.

Country
France
Keywords

K50 - Technologie des produits forestiers, Plante ligneuse, Gazéification, P06 - Sources d'énergie renouvelable, Pinus pinaster, Biomasse, Production énergétique, Oxydation, Charbon de bois, Traitement thermique, Pyrolyse, Bioénergie, Rendement, agrovoc: agrovoc:c_34000, agrovoc: agrovoc:c_26837, agrovoc: agrovoc:c_24836, agrovoc: agrovoc:c_8488, agrovoc: agrovoc:c_5472, agrovoc: agrovoc:c_16526, agrovoc: agrovoc:c_26874, agrovoc: agrovoc:c_24947, agrovoc: agrovoc:c_926, agrovoc: agrovoc:c_5904, agrovoc: agrovoc:c_1503

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    66
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
66
Top 10%
Top 10%
Top 10%