This article presents a methodology to classify light-duty vehicles according to their environmental impacts. The classification is based on Life-Cycle Impact Assessment indicators and vehicle operation indicators, which are aggregated using a Multi-Criteria Decision Analysis (MCDA) method. In contrast with most literature combining Life-Cycle Assessment (LCA) and MCDA, vehicles are not compared directly; they are compared to pre-established profiles defining a set of classes. These profiles are established relatively to the impacts of the country's light-duty fleet. The ELECTRE TRI method is chosen for MCDA classification, thus avoiding complete substitutability among criteria and allowing for imprecision in the data. MCDA typically incorporates the subjective values of decision makers, namely through criteria weighting. To obtain conclusions that are not contingent on a given weight vector, we consider a space of weight vectors defined by constraints with a clear rationale and obtain all the possible results compatible with those constraints. The methodology is applied to classify six vehicles available in Portugal with different powertrains: Gasoline and Diesel Internal Combustion Engine Vehicles, Plug-in Hybrid Electric Vehicles (10 and 40-mile battery range) and Battery Electric Vehicle. The discussion suggests how this methodology might be useful for a decision-making entity that wishes to classify vehicles according to their environmental impacts.