Chromium(III)-trisoxalate, a versatile building block for luminescent materials
Copyright policy )Chromium(III)-trisoxalate, a versatile building block for luminescent materials
Abstract Chromium(III)-trisoxalate, [Cr(ox) 3 ] 3− (ox=C 2 O 4 2− ), incorporated into polymeric networks of composition [NaCr(ox) 3 ][M II (bpy) 3 ] and [NaCr(ox) 3 ][M III (bpy) 3 ]ClO 4 (ox=C 2 O 4 2− , bpy=2,2′-bipyridine, M II =Zn, Fe, Ru; M III =Rh, Cr), results in interesting features ranging from phonon-assisted and resonant energy migration within the R 1 line the 2 E state to persistent spectral side-hole burning via the latter, and manifestations of specific nearest-neighbour π – π interactions between bipyridine and oxalate.
- University of Geneva Switzerland
Energy migration, info:eu-repo/classification/ddc/540, Spectral diffusion, Persistent spectral hole burning, Chromium(III)-tris-oxalate, Fluorescence line narrowing, ddc: ddc:540
Energy migration, info:eu-repo/classification/ddc/540, Spectral diffusion, Persistent spectral hole burning, Chromium(III)-tris-oxalate, Fluorescence line narrowing, ddc: ddc:540
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