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Journal of Power Sources
Article . 2007 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Effect of structure on the storage characteristics of manganese oxide electrode materials

Authors: Marca M. Doeff; Yong Joon Park; Yong Joon Park;

Effect of structure on the storage characteristics of manganese oxide electrode materials

Abstract

Eleven types of manganese-containing electrode materialswere subjected to long-term storage at 55oC in 1M LiPF6 ethylenecarbonate/dimethyl carbonate (EC/DMC) solutions. The amount of manganesedissolution observed depended upon the sample surface area, the averageMn oxidation state, the structure, and substitution levels of themanganese oxide. In some cases, structural changes such as solvateformation were exacerbated by the high temperature storage, andcontributed to capacity fading upon cycling even in the absence ofsignificant Mn dissolution. The most stable materials appear to beTi-substituted tunnel structures and mixed metal layered oxides with Mnin the +4 oxidation state.

Country
United States
Keywords

Surface Area Manganese Oxides Cathode Materials Storage At 55Oc Manganesedissolution, Manganese, Energy storage, Storage, 25, Oxides, Manganese oxides cathode materials storage at 55oC manganese dissolution, Manganese Oxides, Electrodes, Manganese Oxides Cathode Materials Storage At 55Oc Manganesedissolution, Environmental Energy Technologies

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
16
Average
Top 10%
Average
Green
bronze
Related to Research communities
Energy Research