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Effect of structure on the storage characteristics of manganese oxide electrode materials

Eleven types of manganese-containing electrode materialswere subjected to long-term storage at 55oC in 1M LiPF6 ethylenecarbonate/dimethyl carbonate (EC/DMC) solutions. The amount of manganesedissolution observed depended upon the sample surface area, the averageMn oxidation state, the structure, and substitution levels of themanganese oxide. In some cases, structural changes such as solvateformation were exacerbated by the high temperature storage, andcontributed to capacity fading upon cycling even in the absence ofsignificant Mn dissolution. The most stable materials appear to beTi-substituted tunnel structures and mixed metal layered oxides with Mnin the +4 oxidation state.
- University of California, Berkeley United States
- University of California System United States
- Kyonggi University Korea (Republic of)
- Kyonggi University Korea (Republic of)
- University of North Texas United States
Surface Area Manganese Oxides Cathode Materials Storage At 55Oc Manganesedissolution, Manganese, Energy storage, Storage, 25, Oxides, Manganese oxides cathode materials storage at 55oC manganese dissolution, Manganese Oxides, Electrodes, Manganese Oxides Cathode Materials Storage At 55Oc Manganesedissolution, Environmental Energy Technologies
Surface Area Manganese Oxides Cathode Materials Storage At 55Oc Manganesedissolution, Manganese, Energy storage, Storage, 25, Oxides, Manganese oxides cathode materials storage at 55oC manganese dissolution, Manganese Oxides, Electrodes, Manganese Oxides Cathode Materials Storage At 55Oc Manganesedissolution, Environmental Energy Technologies
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