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Experimental analysis of performance degradation of micro-tubular solid oxide fuel cells fed by different fuel mixtures

handle: 11588/386739
Abstract This paper analyzes the thermodynamic and electrochemical dynamic performance of an anode supported micro-tubular solid oxide fuel cell (SOFC) fed by different types of fuel. The micro-tubular SOFC used is anode supported, consisting of a NiO and Gd 0.2 Ce 0.8 O 2− x (GDC) cermet anode, thin GDC electrolyte, and a La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3− y (LSCF) and GDC cermet cathode. The fabrication of the cells under investigation is briefly summarized, with emphasis on the innovations with respect to traditional techniques. Such micro-tubular cells were tested using a Test Stand consisting of: a vertical tubular furnace, an electrical load, a galvanostast, a bubbler, gas pipelines, temperature, pressure and flow meters. The tests on the micro-SOFC were performed using H 2 , CO, CH 4 and H 2 O in different combinations at 550 °C, to determine the cell polarization curves under several load cycles. Long-term experimental tests were also performed in order to assess degradation of the electrochemical performance of the cell. Results of the tests were analyzed aiming at determining the sources of the cell performance degradation. Authors concluded that the cell under investigation is particularly sensitive to the carbon deposition which significantly reduces cell performance, after few cycles, when fed by light hydrocarbons. A significant performance degradation is also detected when hydrogen is used as fuel. In this case, the authors ascribe the degradation to the micro-cracks, the change in materials crystalline structure and problems with electrical connections.
- Colorado School of Mines United States
- Colorado School of Mines United States
- University Federico II of Naples Italy
- Pohang University of Science and Technology Korea (Republic of)
- Pohang University of Science and Technology Korea (Republic of)
FABRICATION, SYNTHESIS GAS, MOLYBDENUM, CATALYSTS, OXIDATION, 620, Fuel mixtures, Degradation, CONVERSION, METHANE, SOFCS, Micro-tubular, Carbon deposition, SOFC, ANODE, INTERMEDIATE-TEMPERATURE
FABRICATION, SYNTHESIS GAS, MOLYBDENUM, CATALYSTS, OXIDATION, 620, Fuel mixtures, Degradation, CONVERSION, METHANE, SOFCS, Micro-tubular, Carbon deposition, SOFC, ANODE, INTERMEDIATE-TEMPERATURE
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