AbstractWe demonstrate the high concentration exfoliation of graphene nanosheets in dimethyl formamide (DMF) as a solvent from graphite powder. UV-Vis-NIR spectroscopy shows low power bath sonication yields less concentration of graphene nanosheets exfoliation, whereas the high power probe sonication yields high concentration graphene nanosheets exfoliation. The concentration of graphene nanosheets exfoliation depends on amount of energy supplied, and there exists a linear relationship between the concentration of graphene and energy supplied during sonication. TEM micrograph confirms the exfoliation of graphene nanosheets. AFM studies shows; high power sonication for longer time reveals graphene exfoliation with fewer graphene layers. The strategy of bath sonication followed by probe sonication of grapheme solution shows the stable suspension of graphene nanosheets even after one month.