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Renewable Energy
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High temperature corrosion behavior on molten nitrate salt-based nanofluids for CSP plants

Authors: Fernández, Angel G.; Muñoz-Sánchez, Belen; Nieto-Maestre, Javier; García-Romero, Ana;

High temperature corrosion behavior on molten nitrate salt-based nanofluids for CSP plants

Abstract

Abstract Recently, a number of theoretical and experimental studies have been performed to understand the effect of nanoparticles on thermal properties and heat transfer performance but there is a lack regarding their corrosion properties. In this work, an extended corrosion characterization (at central tower plant storage temperature (565 °C)) has been carried out in two different grades of solar salt (industrial and refined purity) doped with the addition of 1 wt% Al2O3 nanoparticles or 1 wt% SiO2 nanoparticles. Corrosion rates were determined in commercial stainless steel commonly used in CSP technology (347SS) by gravimetric tests, measuring the weight gain during 1000 h, identifying the corrosion products by Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD). The lowest corrosion rate (0.007 mm/year) was obtained in the refined solar salt with the addition of 1 wt% Al2O3 nanoparticles. A protective layer was formed in the steel-salt interphase, identified through XRD as Al2O3. Additionally, hematite (Fe2O3) and magnetite (Fe3O4) were obtained as unprotective corrosion products throughout the test carried out with or without nanoparticles. In addition, the presence of impurities on the salts generated some stable compounds, as magnesium ferrite (MgFe2O4).

Country
Spain
Keywords

Corrosion, Molten salts, Nanoparticles, Concentrated solar power

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    77
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    Top 1%
    influence
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
77
Top 1%
Top 10%
Top 1%
Green
hybrid