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Enhancement of aromatics production via cellulose fast pyrolysis over Ru modified hierarchical zeolites

Abstract In the present study, Ru modified hierarchical zeolites xRu-MZSM were developed for cellulose fast pyrolysis. Comprehensive catalyst characterizations including XRD, XPS, N2 adsorption-desorption, Py-IR and so on, were performed to unveil the essential structural properties. The chemical modification and Ru decoration remarkably regulated the distribution of Bronsted/Lewis acid sites. The presence of RuOx species would supply abundant strong Lewis acid sites for participating catalytic cracking, dehydration, decarbonylation, decarboxylation, cyclization, aromatization, etc., in cooperation with Bronsted acid sites. In-situ generated active Ru0 centers during cellulose pyrolysis might facilitate the proceeding of deoxygenation, hydride transfer, and dehydrogenation. Among the as-prepared catalysts screened, 2Ru-MZSM was much more efficient in aromatics production from cellulose fast pyrolysis compared to parent ZSM, wherein the total aromatics yield achieved 16.8% at temperature of 650 °C and heating rate of 10 °C/ms with corresponding E value as low as 23.40 kJ/mol. Also, plausible reaction mechanism for xRu-MZSM involved cellulose fast pyrolysis was proposed in detail.
- Chinese Academy of Sciences China (People's Republic of)
- Chinese Academy of Sciences China (People's Republic of)
- Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) China (People's Republic of)
- Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) China (People's Republic of)
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