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Renewable Energy
Article . 2025 . Peer-reviewed
License: CC BY
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Calibration methodology of static, dynamic and ageing parameters of an electrochemical model for a Li-ion cell based on an experimental approach

Authors: Francesco Mazzeo; Eduardo Graziano; Silvia Bodoardo; Davide Papurello;

Calibration methodology of static, dynamic and ageing parameters of an electrochemical model for a Li-ion cell based on an experimental approach

Abstract

This study presents a novel methodology for developing a digital twin of a lithium-ion coin cell battery (Graphite-NMC622), accurately replicating the average discharge behaviour of various laboratory-tested batteries and characterizing degradation phenomena through cyclic ageing experiments. Given the anticipated rise in electric vehicle adoption, this work is particularly relevant for addressing the growing demand for lithium-ion batteries. The experimental characterization identified the minimum requirements for battery modelling, with tests conducted up to a C/5 current. Degradation behaviours were analysed through cycle ageing tests at two State-Of-Charge (SOC) ranges (100 %–0 % and 90 %–10 %), establishing a robust foundation for modelling degradation trends. While further calendar ageing tests could enhance the degradation modelling, they would require extensive data and time. Despite these constraints, the virtual coin cell model developed using GT-AutoLion, an industry-standard CAE software, demonstrated excellent accuracy, achieving an RRMSE of less than 2.0 % and R2 greater than 0.95. This work is significant as it provides a reliable framework for battery modelling that can assist companies in optimizing battery design and performance.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
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