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Thermochemical H2O and CO2 splitting redox cycles in a NiFe2O4 structured redox reactor: Design, development and experiments in a high flux solar simulator

Authors: Lorentzou, Souzana; Dimitrakis, Dimitrios; Zygogianni, Alexandra; Karagiannakis, George; Konstandopoulos, Athanasios;

Thermochemical H2O and CO2 splitting redox cycles in a NiFe2O4 structured redox reactor: Design, development and experiments in a high flux solar simulator

Abstract

Abstract A high flux solar simulator allows the lab-scale assessment of solar reactor concepts by irradiating a target with high flux thermal energy, similarly to reactors installed in concentrated solar radiation facilities such as central towers with a heliostat field. In the current study, the design and construction of a high flux solar simulator facility for near realistic solar experiments is presented. A simple, cavity-tubular thermochemical reactor is employed for the evaluation of the redox activity of structured monolithic bodies (foams and honeycombs) consisting entirely of NiFe2O4 w.r.t·H2O splitting, CO2 splitting and combined H2O-CO2 splitting reactions. Experiments under realistic conditions, i.e. a solar reactor under irradiation, were conducted to assess the solar fuels production capability, which was examined at the structure level and the reactor level. The best performing structure was the NiFe2O4 foam. Further multilevel research (structure, reactor as well as redox material), will improve product yield and reactor efficiency.

Keywords

Structured reactors, Redox thermochemical cycles, H2O-CO2 splitting, Solar fuels

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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