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New pyran-based dyes as efficient sensitizers of p-type dye-sensitized solar cells

handle: 11588/760016 , 11573/1108481 , 2318/1769421
Abstract The application of four pyran based dyes as sensitizers for p-type dye-sensitized solar cells (p-DSCs) is here proposed. The dyes differ for the nature of the electron acceptor group which functionalizes the pyran core. Such a structural variation significantly influences the optical properties of the dyes so that the new pyrans overall cover most of the visible spectrum. In some cases, the p-DSCs employing these pyran-based dyes display power conversion efficiency significantly higher than the device sensitized with sensitizer benchmark P1. The relevant photo-electrochemical activity of one of the reported dyes combined with its ability to absorb the visible radiation in the lower energy portion (λ > 500 nm) makes it a promising candidate to be used in a tandem DSC (t-DSC) with the photoanode sensitized by a dye typically absorbing the higher energy zone of the visible spectrum (λ
- University of Rome Tor Vergata Italy
- University of Turin Italy
- Sapienza University of Rome Italy
- Roma Tre University Italy
- University Federico II of Naples Italy
NiO sensitization, Pyran, IPCE, DSSC; Dyes; IPCE; NiO sensitization; Pyran, DSSC, dyes; pyran; nio sensitization; dssc; ipce, Dyes
NiO sensitization, Pyran, IPCE, DSSC; Dyes; IPCE; NiO sensitization; Pyran, DSSC, dyes; pyran; nio sensitization; dssc; ipce, Dyes
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).19 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 10% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 10%
