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Bifacial n-type silicon solar cells for upconversion applications

Abstract Upconversion of sub-band-gap photons has the potential to increase the efficiency of solar cells significantly, but requires modification of the solar cells. In this paper, we present a calculation framework to assess the efficiency of a combined bifacial silicon solar cell upconverter device, which is then used to optimize the solar cell׳s front and rear side anti-reflection coatings. Our calculations show that an upconverter can increase the efficiency of an optimized solar cell by 3.0% relative. Subsequently, planar bifacial n -type silicon solar cells were fabricated with optimized anti-reflection coatings. An upconversion layer – containing the upconverter phosphor β -NaY 0.8 Er 0.2 F 4 embedded in the polymer perfluorocyclobutyl – was attached to the rear side of the solar cells and an external quantum efficiency arising from the upconversion of sub-band-gap photons of 1.69% was measured under 1508 nm monochromatic excitation with an irradiance of 1091 W/m 2 . This corresponds to a value of 0.15 (W/cm 2 ) −1 when normalized to the irradiance, constituting a five-fold increase compared to the previously best published normalized values that were achieved without optimized solar cells.
- Heriot-Watt University United Kingdom
- University of Freiburg Germany
- Heriot-Watt University United Kingdom
- Fraunhofer Institute for Solar Energy Systems Germany
- Fraunhofer Society Germany
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