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Revisiting the theory and usage of junction capacitance: Application to high efficiency amorphous/crystalline silicon heterojunction solar cells

Authors: Kleider, Jean-Paul; Alvarez, José; Brézard-Oudot, Aurore; Gueunier-Farret, Marie-Estelle; Maslova, Olga;

Revisiting the theory and usage of junction capacitance: Application to high efficiency amorphous/crystalline silicon heterojunction solar cells

Abstract

We briefly review the basic concepts of junction capacitance and the peculiarities related to amorphous semiconductors, paying tribute to Cohen and to his pioneering work. We extend the discussion to very high efficiency silicon heterojunction (SiHET) solar cells where both an amorphous semiconductor, namely hydrogenated amorphous silicon, and heterojunctions are present. By presenting both modeling and experimental results, we demonstrate that the conventional theory of junction capacitance based on the depletion approximation in the space charge region, cannot reproduce the capacitance data obtained on SiHET cells. The experimental temperature dependence is significantly stronger than that of the depletion-layer capacitance, while the bias dependence yields underestimated values of the diffusion potential, leading to strong errors if applied to the determination of band offsets using the procedure proposed precedingly in the literature. We demonstrate that this is not related to the amorphous nature of a-Si:H, but to the existence of a strongly inverted c-Si surface layer that requires minority carriers to be taken into account in the analysis of the junction capacitance.

Country
France
Keywords

[ SPI.MAT ] Engineering Sciences [physics]/Materials, [SPI.MAT] Engineering Sciences [physics]/Materials, [SPI.MAT]Engineering Sciences [physics]/Materials

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
24
Top 10%
Top 10%
Top 10%
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