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Solar Energy Materials and Solar Cells
Article . 2019 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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The importance of accurate determination of optical constants for the design of nanometallic light-trapping structures

Authors: Nicholas J. Ekins-Daukes; Nicholas J. Ekins-Daukes; Alexander Mellor; Phoebe Pearce;

The importance of accurate determination of optical constants for the design of nanometallic light-trapping structures

Abstract

Abstract The optical constants of many metals commonly used in solar cells, e.g. as contacts, rear side planar reflectors, or more complex nanopatterned light-trapping structures, can vary depending on deposition method, thickness and other factors, and as such are not documented consistently in the literature. In the case of nanometallic light-trapping structures specifically designed to improve absorption in a solar cell, the choice of optical constants used in simulations significantly affects the predicted enhancement, as well as the structure's optimal dimensions. The trade-off between coupling into guided modes in the photovoltaic material and the number of photons absorbed parasitically in the metal leads to small differences in the optical constants giving significantly different results for the quantum efficiency and photogenerated current. This work documents several optical constant sources for silver, aluminium, gold and titanium, and the effect this has on plasmon quality factors. The effect of choosing different optical constant sources on modelling outcomes is quantified by considering the optimization of a test structure comprising a grid of metal nanodisks on the front surface of a thinned-down GaAs cell. Finally, we define a new spectrally-integrated figure of merit for comparing the expected performance of metals in light-trapping structures based on their optical constants, which we name the spectral absorption enhancement factor (SAEF).

Country
United Kingdom
Related Organizations
Keywords

Technology, SOLAR-CELLS, Energy & Fuels, Surface plasnions, Materials Science, Materials Science, Multidisciplinary, Ultra-thin solar cells, FILMS, 530, 09 Engineering, Physics, Applied, Light-trapping, SCATTERING, Multidisciplinary, Science & Technology, 02 Physical Sciences, Energy, Physics, 620, PLASMONICS, Applied, Physical Sciences, Metallic gratings, RCWA, 03 Chemical Sciences

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    26
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
26
Top 10%
Average
Top 10%
Green