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Solar Energy Materials and Solar Cells
Article . 2023 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Integration of rough RTP absorbers into CIGS-perovskite monolithic tandems by NiOx(:Cu)+SAM Hole-transporting Bi-layers

Authors: Ivona Kafedjiska; Guillermo A. Farias-Basulto; Pablo Reyes-Figueroa; Tobias Bertram; Amran Al-Ashouri; Christian A. Kaufmann; Robert Wenisch; +3 Authors

Integration of rough RTP absorbers into CIGS-perovskite monolithic tandems by NiOx(:Cu)+SAM Hole-transporting Bi-layers

Abstract

We investigate the performance of monolithic copper indium gallium selenide CIGS perovskite tandem solar cells with two different CIGS bottom device absorbers Cu In,Ga Se2 or Cu In,Ga S,Se 2 and with three different hole transporting layers HTLs NiOx SAM, NiOx Cu SAM and SAM alone. NiOx Cu is 2 wt copper doped nickel oxide and SAM is the MeO 2PACz [2 3,6 dimethoxy 9H carbazol 9 yl ethyl]phosphonic acid self assembled monolayer. The CIGSe is fabricated by physical vapor deposition PVD , has a Eg amp; 8764; 1.06eV, and a amp; 963;RMS,PVD amp; 8764; 65 nm, while the CIGSSe is fabricated by rapid thermal processing RTP , has a Eg amp; 8764; 1.01eV, and a amp; 963;RMS,RTP amp; 8764; 120 nm. While the current certified, 24.2 efficient, world record monolithic CIGSe perovskite tandem solar cell has previously been achieved with SAM as a stand alone HTL, this work investigates whether SAM can yield similarly high efficiencies also on industrially compatible, very rough RTP CIGSSe absorbers. We find that the devices with SAM as stand alone HTL suffer from severe FF and Voc losses and that NiOx Cu is needed to act as a shunt quenching layer below that SAM, ensuring conformal coverage of the rough bottom sub cell surface. Within this work the highest achieved in house measured PCEs for the RTP and PVD CIGS based tandems are 21.6 and 23.2 respectively, on a cell area of 1.08 cm2, both of which are obtained with NiOx Cu SAM as an HTL

Country
Germany
Keywords

Cu In,Ga S,Se 2 ; Metal halide perovskite ; Monolithic tandems ; Nickel oxide NiOx ; Hole transporting layers HTLs

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
17
Top 10%
Average
Top 10%
Green
Related to Research communities
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