Abstract Pyrolysis is currently being considered as an alternative method of treating sewage sludge. It yields residual oils and gases, which can be used as fuels, and a solid which can either be burned or physically activated with air or CO 2 . The aim of this work was to study the influence of different pyrolysis conditions (e.g. temperature and heating rate) on the reactivity in air and in CO 2 of carbonaceous materials obtained from these types of residues. An anaerobic sewage sludge produced in a Spanish urban waste water treatment plant, containing 5 wt.% moisture after air-drying, was pyrolyzed in an electrical laboratory furnace under different pyrolysis conditions. Non-isothermal reactivities (up to 1100°C) in air and in CO 2 of the carbonaceous materials obtained after pyrolysis were performed in a thermobalance. The TG and DTG curves obtained from these experiments are discussed.